Acta Cryst. (2004). E60, m662-m663  [ doi:10.1107/S1600536804009602 ]

Hydrogen bonding in thiacrown complexes: chlorobis(nicotinamide-N)(1,4,7-trithiacyclononane-³S)ruthenium(II) hexafluorophosphate monohydrate

H. Adams, N. Shan and J. Thomas

Abstract: The title complex, [RuClL₂([9]-ane-S₃)]PF₆·H₂O [where L is nicotinamide, C₇H₆N₂O) and [9]-ane-S₃ is 1,4,7-trithiacyclononane (C₆H₁₂S₃)], was isolated as a hexafluorophosphate salt from water-ethanol. The structure confirms that the amide moieties are available for possible mutual hydrogen-bond interactions. However, from aqueous solvents, these sites are involved in networks of interactions with water molecules.

Online 30 April 2004

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