Acta Cryst. (2004). E60, m606-m608  [ doi:10.1107/S1600536804008839 ]

Ethanol(ethoxy)[3-methoxysalicylaldehyde (4-methoxybenzoyl)hydrazonato-³O,N,O']oxovanadium(V)

L.-H. Huo, S. Gao, J.-W. Liu, H. Zhao and S. W. Ng

Abstract: The six-coordinated V^V atom in the title complex, [VOL(OCH₂CH₃)(CH₃CH₂OH)] [H₂L = 3-methoxysalicylaldehyde (4-methoxybenzoyl)hydrazone] or [VO(C₂H₅O)(C₁₆H₁₄N₂O₄)(C₂H₆O)], displays a distorted octahedral VO(ONO)(O)(O) coordination. The equatorial plane is defined by one N and two O atoms of the tridentate hydrazone ligand and the ethoxy O atom, while the axial oxo group is trans to the ethanol O atom. Adjacent molecules are linked by intermolecular hydrogen bonds into a chain structure along the c axis.

Copyright © International Union of Crystallography
IUCr Webmaster