Acta Cryst. (2004). E60, m805-m807  [ doi:10.1107/S1600536804011791 ]

[N,N'-Bis(salicylidene)-1,3-propanediaminato](methanol)(thiocyanato)nickel(II)

Z.-L. You, H.-L. Zhu and W.-S. Liu

Abstract: The title compound, [Ni(C₁₇H₁₇N₂O₂)(NCS)(CH₄O)], is a mononuclear nickel(II) complex. The Ni^II atom has a slightly distorted octahedral geometry, coordinated by two N and two O atoms of the Schiff base ligand, and one terminal N atom from a thiocyanate anion, together with a methanol molecule. In the crystal structure, the complex forms centrosymmetric O-HO hydrogen-bonded dimers. The symmetry-related dimers are linked by weak O-HS hydrogen bonds to form layers parallel to the bc plane.

Online 22 May 2004

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