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Acta Cryst. (2004). E60, o1078-o1080  [ doi:10.1107/S1600536804012073 ]

2,2'-{(Z)-Ethane-1,2-diylbis[(Z)-o-phenylenenitrilomethylidyne]}diphenol (EIEP)

S. M. M. Sony, P. Charles, M. N. Ponnuswamy and H. S. Yathirajan

Abstract: The salicylideneaniline moiety in the centrosymmetric title compound, C28H24N2O2, is a phenol-imine tautomer which is non-planar and photochromic. A strong intramolecular hydrogen-bonding interaction, which is a common feature in related imine-phenol compounds, stabilizes the molecular structure. The [pi] system in the salicylideneaniline moiety interacts with symmetry-related [pi] systems through face-to-face [pi]-[pi] interactions and C-H...[pi] interactions, to stabilize the molecules in the crystal structure.

Online 29 May 2004


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