Acta Cryst. (2004). E60, m842-m844  [ doi:10.1107/S1600536804011924 ]

Aqua(2,2'-diamino-4,4'-bi-1,3-thiazole-²N,N')(oxydiacetato-³O,O',O'')cobalt(II) dihydrate

Y.-H. Shen, J.-G. Liu and D.-J. Xu

Abstract: The title compound, [Co(C₄H₄O₅)(C₆H₆N₄S₂)(H₂O)]·2H₂O, contains one Co^II complex and two water molecules in the asymmetric unit. The tridentate oxydiacetate dianion meridionally chelates a Co atom, and both five-membered chelate rings assume an envelope conformation. Diaminobithiazole chelates the Co atom, in a planar configuration. Parallel thiazole rings of neighboring complex molecules are separated by 3.504 (5) Å, suggesting the existence of - stacking interactions.

Online 22 May 2004

Copyright © International Union of Crystallography
IUCr Webmaster