Download citation
Download citation
link to html
The title compound, [Co(C22H26N6O2)]ClO4, was prepared from di­formyl­oxanilide, cobalt(II) perchlorate and 1,3-propane­di­amine. The crystal structure contains a complex cobalt(III) cation and a perchlorate anion. Cobalt is coordinated by six N atoms from the anilide ligand in chelating mode, forming a distorted octahedral geometry. Inter-cation hydrogen bonds are present in the crystal structure.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804009894/na6309sup1.cif
Contains datablocks I, 021004c

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536804009894/na6309Isup2.hkl
Contains datablock I

CCDC reference: 242025

Key indicators

  • Single-crystal X-ray study
  • T = 293 K
  • Mean [sigma](C-C) = 0.007 Å
  • R factor = 0.054
  • wR factor = 0.118
  • Data-to-parameter ratio = 15.0

checkCIF/PLATON results

No syntax errors found



Alert level C PLAT125_ALERT_4_C No _symmetry_space_group_name_Hall Given ....... ? PLAT244_ALERT_4_C Low Solvent U(eq) as Compared to Neighbors .... Cl1 PLAT341_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 7 PLAT416_ALERT_2_C Short Intra D-H..H-D H1C .. H6B .. 1.91 Ang. PLAT420_ALERT_2_C D-H Without Acceptor N6 - H6C ... ? PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... # 2 N3 -CO1 -N1 -C1 10.30 1.40 1.555 1.555 1.555 1.555 PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... # 8 N5 -CO1 -N2 -C4 40.00 4.00 1.555 1.555 1.555 1.555 PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... # 13 N5 -CO1 -N2 -C3 -138.00 4.00 1.555 1.555 1.555 1.555 PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... # 19 N1 -CO1 -N3 -C11 35.50 1.40 1.555 1.555 1.555 1.555 PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... # 24 N1 -CO1 -N3 -C10 -107.10 1.20 1.555 1.555 1.555 1.555 PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... # 30 N6 -CO1 -N4 -C12 75.00 4.00 1.555 1.555 1.555 1.555 PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... # 35 N6 -CO1 -N4 -C13 -79.00 4.00 1.555 1.555 1.555 1.555 PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... # 38 N2 -CO1 -N5 -C19 117.00 4.00 1.555 1.555 1.555 1.555 PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... # 43 N2 -CO1 -N5 -C20 -61.00 4.00 1.555 1.555 1.555 1.555 PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... # 46 N4 -CO1 -N6 -C22 -9.00 4.00 1.555 1.555 1.555 1.555
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 15 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 2 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 12 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Bruker, 1999); cell refinement: SMART; data reduction: SAINT (Bruker, 1999); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1999); software used to prepare material for publication: SHELXTL and WinGX (Farrugia, 1999).

{2,2'-Bis[(3-aminopropyl)iminomethyl]oxalanilide}cobalt(III) perchlorate top
Crystal data top
[Co(C22H26N6O2)]ClO4F(000) = 1168
Mr = 564.87Dx = 1.575 Mg m3
Monoclinic, P21/cMo Kα radiation, λ = 0.71073 Å
a = 9.728 (3) ÅCell parameters from 897 reflections
b = 17.232 (5) Åθ = 2.2–23.3°
c = 14.953 (5) ŵ = 0.89 mm1
β = 108.076 (6)°T = 293 K
V = 2382.8 (13) Å3Block, red
Z = 40.32 × 0.24 × 0.20 mm
Data collection top
Bruker SMART CCD area-detector
diffractometer
4873 independent reflections
Radiation source: fine-focus sealed tube2884 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.064
φ and ω scansθmax = 26.4°, θmin = 1.9°
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)
h = 1210
Tmin = 0.743, Tmax = 0.838k = 2115
11184 measured reflectionsl = 618
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.054Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.118H-atom parameters constrained
S = 0.99 w = 1/[σ2(Fo2) + (0.0383P)2 + 1.7668P]
where P = (Fo2 + 2Fc2)/3
4873 reflections(Δ/σ)max = 0.001
325 parametersΔρmax = 0.44 e Å3
0 restraintsΔρmin = 0.37 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) =

are estimated using the full covariance matrix. The cell e.s.d.'s are = taken into account individually in the estimation of e.s.d.'s in distances, = angles and torsion angles; correlations between e.s.d.'s in cell parameters are = only used when they are defined by crystal symmetry. An approximate = (isotropic)

treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. = planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Co10.66589 (6)0.24282 (3)0.43119 (3)0.02315 (16)
N10.7581 (4)0.31526 (19)0.5372 (2)0.0319 (9)
H1C0.70990.31010.57950.038*
H1D0.84850.29770.56520.038*
N20.5211 (4)0.32033 (18)0.3674 (2)0.0281 (8)
N30.5768 (3)0.18241 (18)0.31901 (19)0.0215 (7)
N40.7968 (3)0.27092 (18)0.3645 (2)0.0238 (7)
N50.8067 (4)0.16354 (19)0.4906 (2)0.0303 (8)
N60.5305 (4)0.2094 (2)0.5023 (2)0.0336 (9)
H6B0.55440.23730.55580.040*
H6C0.44140.22490.46800.040*
O10.5623 (3)0.18653 (17)0.16234 (17)0.0351 (7)
O20.8417 (3)0.24942 (18)0.22368 (17)0.0427 (8)
C10.7696 (5)0.3989 (3)0.5214 (3)0.0415 (12)
H1A0.83590.40730.48550.050*
H1B0.80840.42500.58150.050*
C20.6254 (5)0.4325 (3)0.4695 (3)0.0503 (13)
H2A0.63480.48850.46740.060*
H2B0.55880.42130.50450.060*
C30.5608 (5)0.4028 (2)0.3702 (3)0.0454 (12)
H3A0.47540.43310.33870.054*
H3B0.63010.41000.33620.054*
C40.3907 (5)0.3023 (3)0.3202 (3)0.0329 (10)
H4A0.32670.34300.29740.040*
C50.3339 (4)0.2239 (2)0.2991 (3)0.0297 (10)
C60.1867 (5)0.2087 (3)0.2773 (3)0.0408 (11)
H6A0.12330.24880.27850.049*
C70.1346 (5)0.1350 (3)0.2541 (3)0.0478 (13)
H7A0.03650.12470.24140.057*
C80.2288 (5)0.0763 (3)0.2497 (3)0.0486 (13)
H8A0.19290.02650.23280.058*
C90.3747 (5)0.0898 (3)0.2697 (3)0.0375 (11)
H9A0.43670.04980.26560.045*
C100.4281 (4)0.1637 (2)0.2960 (3)0.0269 (9)
C110.6249 (4)0.1999 (2)0.2469 (3)0.0234 (9)
C120.7676 (4)0.2430 (2)0.2765 (2)0.0263 (9)
C130.9420 (4)0.2897 (2)0.4139 (3)0.0280 (10)
C141.0138 (5)0.3520 (3)0.3911 (3)0.0348 (10)
H14A0.96700.38320.34000.042*
C151.1545 (5)0.3681 (3)0.4437 (3)0.0468 (13)
H15A1.20120.41090.42850.056*
C161.2262 (5)0.3217 (3)0.5182 (3)0.0508 (14)
H16A1.32040.33370.55410.061*
C171.1587 (5)0.2579 (3)0.5394 (3)0.0481 (13)
H17A1.20900.22530.58810.058*
C181.0142 (4)0.2410 (3)0.4884 (3)0.0331 (10)
C190.9430 (5)0.1732 (3)0.5103 (3)0.0392 (12)
H19A1.00200.13290.54170.047*
C200.7544 (5)0.0870 (2)0.5107 (3)0.0454 (13)
H20A0.83670.05380.53940.055*
H20B0.69820.06310.45190.055*
C210.6620 (6)0.0928 (3)0.5753 (3)0.0536 (14)
H21A0.64900.04120.59750.064*
H21B0.71270.12380.62970.064*
C220.5170 (6)0.1280 (3)0.5292 (3)0.0487 (13)
H22A0.46680.09820.47360.058*
H22B0.46000.12600.57210.058*
Cl10.16886 (15)0.48693 (7)0.19923 (8)0.0503 (3)
O30.2606 (6)0.4485 (3)0.1572 (3)0.1112 (18)
O40.0761 (7)0.4325 (3)0.2161 (4)0.153 (3)
O50.0913 (6)0.5437 (3)0.1394 (4)0.129 (2)
O60.2499 (6)0.5156 (3)0.2859 (4)0.148 (2)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Co10.0281 (3)0.0271 (3)0.0151 (2)0.0020 (3)0.00779 (19)0.0011 (2)
N10.041 (2)0.035 (2)0.0220 (17)0.0013 (17)0.0128 (16)0.0039 (16)
N20.030 (2)0.024 (2)0.0303 (18)0.0021 (16)0.0087 (16)0.0010 (16)
N30.0225 (18)0.0282 (19)0.0137 (15)0.0005 (14)0.0057 (13)0.0003 (14)
N40.0238 (18)0.032 (2)0.0152 (15)0.0016 (14)0.0056 (13)0.0010 (14)
N50.039 (2)0.030 (2)0.0202 (17)0.0051 (17)0.0055 (16)0.0015 (15)
N60.041 (2)0.039 (2)0.0242 (17)0.0026 (17)0.0158 (16)0.0005 (16)
O10.0306 (17)0.054 (2)0.0179 (14)0.0055 (14)0.0037 (12)0.0005 (13)
O20.0360 (17)0.073 (2)0.0243 (14)0.0154 (17)0.0164 (13)0.0075 (16)
C10.047 (3)0.033 (3)0.040 (3)0.001 (2)0.009 (2)0.010 (2)
C20.051 (3)0.031 (3)0.065 (3)0.001 (2)0.012 (3)0.014 (2)
C30.041 (3)0.026 (3)0.062 (3)0.003 (2)0.006 (2)0.008 (2)
C40.032 (3)0.037 (3)0.029 (2)0.007 (2)0.0076 (19)0.003 (2)
C50.029 (2)0.034 (3)0.026 (2)0.005 (2)0.0072 (18)0.0005 (18)
C60.033 (3)0.052 (3)0.036 (3)0.001 (2)0.010 (2)0.001 (2)
C70.026 (3)0.067 (4)0.049 (3)0.014 (3)0.011 (2)0.002 (3)
C80.045 (3)0.046 (3)0.052 (3)0.020 (3)0.010 (2)0.005 (3)
C90.044 (3)0.032 (3)0.035 (2)0.000 (2)0.010 (2)0.002 (2)
C100.030 (2)0.034 (3)0.019 (2)0.004 (2)0.0093 (17)0.0019 (18)
C110.025 (2)0.023 (2)0.022 (2)0.0053 (17)0.0066 (17)0.0018 (17)
C120.024 (2)0.034 (3)0.0180 (18)0.0029 (19)0.0030 (15)0.0037 (19)
C130.024 (2)0.038 (3)0.021 (2)0.0019 (19)0.0069 (17)0.0051 (18)
C140.034 (3)0.039 (3)0.031 (2)0.004 (2)0.011 (2)0.005 (2)
C150.034 (3)0.060 (3)0.046 (3)0.013 (2)0.013 (2)0.020 (3)
C160.026 (3)0.072 (4)0.047 (3)0.008 (3)0.000 (2)0.020 (3)
C170.035 (3)0.070 (4)0.031 (2)0.010 (3)0.0016 (19)0.011 (3)
C180.027 (2)0.043 (3)0.026 (2)0.004 (2)0.0037 (17)0.004 (2)
C190.043 (3)0.044 (3)0.023 (2)0.016 (2)0.000 (2)0.002 (2)
C200.064 (4)0.024 (3)0.045 (3)0.006 (2)0.013 (3)0.011 (2)
C210.085 (4)0.036 (3)0.042 (3)0.004 (3)0.022 (3)0.016 (2)
C220.070 (4)0.043 (3)0.042 (3)0.011 (3)0.031 (3)0.004 (2)
Cl10.0573 (8)0.0458 (8)0.0444 (7)0.0006 (7)0.0108 (6)0.0083 (6)
O30.165 (5)0.102 (4)0.080 (3)0.075 (3)0.057 (3)0.022 (3)
O40.171 (6)0.161 (5)0.128 (5)0.085 (5)0.048 (4)0.047 (4)
O50.136 (5)0.139 (4)0.145 (4)0.092 (4)0.090 (4)0.102 (4)
O60.128 (5)0.172 (5)0.114 (4)0.001 (4)0.003 (4)0.090 (4)
Geometric parameters (Å, º) top
Co1—N41.908 (3)C6—C71.371 (6)
Co1—N31.936 (3)C6—H6A0.9300
Co1—N51.944 (3)C7—C81.381 (7)
Co1—N21.961 (3)C7—H7A0.9300
Co1—N11.999 (3)C8—C91.377 (6)
Co1—N62.016 (3)C8—H8A0.9300
N1—C11.471 (5)C9—C101.386 (6)
N1—H1C0.9000C9—H9A0.9300
N1—H1D0.9000C11—C121.515 (5)
N2—C41.284 (5)C13—C141.379 (6)
N2—C31.470 (5)C13—C181.397 (5)
N3—C111.337 (4)C14—C151.378 (6)
N3—C101.416 (5)C14—H14A0.9300
N4—C121.346 (4)C15—C161.373 (7)
N4—C131.413 (5)C15—H15A0.9300
N5—C191.276 (5)C16—C171.368 (7)
N5—C201.478 (5)C16—H16A0.9300
N6—C221.476 (5)C17—C181.405 (6)
N6—H6B0.9000C17—H17A0.9300
N6—H6C0.9000C18—C191.448 (6)
O1—C111.242 (4)C19—H19A0.9300
O2—C121.229 (4)C20—C211.513 (6)
C1—C21.494 (6)C20—H20A0.9700
C1—H1A0.9700C20—H20B0.9700
C1—H1B0.9700C21—C221.494 (7)
C2—C31.512 (6)C21—H21A0.9700
C2—H2A0.9700C21—H21B0.9700
C2—H2B0.9700C22—H22A0.9700
C3—H3A0.9700C22—H22B0.9700
C3—H3B0.9700Cl1—O41.378 (5)
C4—C51.456 (6)Cl1—O51.381 (4)
C4—H4A0.9300Cl1—O61.383 (4)
C5—C61.391 (6)Cl1—O31.406 (4)
C5—C101.394 (6)
N4—Co1—N382.87 (13)C5—C6—H6A119.8
N4—Co1—N585.82 (14)C6—C7—C8119.5 (4)
N3—Co1—N594.64 (13)C6—C7—H7A120.3
N4—Co1—N293.90 (13)C8—C7—H7A120.3
N3—Co1—N283.31 (13)C9—C8—C7121.3 (5)
N5—Co1—N2177.95 (14)C9—C8—H8A119.3
N4—Co1—N192.74 (13)C7—C8—H8A119.3
N3—Co1—N1173.48 (13)C8—C9—C10119.2 (4)
N5—Co1—N189.82 (14)C8—C9—H9A120.4
N2—Co1—N192.22 (14)C10—C9—H9A120.4
N4—Co1—N6178.00 (14)C9—C10—C5120.1 (4)
N3—Co1—N696.49 (13)C9—C10—N3122.8 (4)
N5—Co1—N692.35 (15)C5—C10—N3117.1 (4)
N2—Co1—N687.90 (14)O1—C11—N3126.6 (4)
N1—Co1—N688.05 (14)O1—C11—C12120.2 (3)
C1—N1—Co1121.5 (2)N3—C11—C12113.1 (3)
C1—N1—H1C107.0O2—C12—N4127.5 (4)
Co1—N1—H1C107.0O2—C12—C11121.6 (3)
C1—N1—H1D107.0N4—C12—C11111.0 (3)
Co1—N1—H1D107.0C14—C13—C18119.7 (4)
H1C—N1—H1D106.7C14—C13—N4123.3 (4)
C4—N2—C3117.1 (3)C18—C13—N4116.9 (4)
C4—N2—Co1122.7 (3)C15—C14—C13120.4 (4)
C3—N2—Co1120.1 (3)C15—C14—H14A119.8
C11—N3—C10116.2 (3)C13—C14—H14A119.8
C11—N3—Co1113.8 (3)C16—C15—C14120.6 (5)
C10—N3—Co1118.8 (2)C16—C15—H15A119.7
C12—N4—C13117.8 (3)C14—C15—H15A119.7
C12—N4—Co1116.6 (3)C17—C16—C15119.8 (4)
C13—N4—Co1120.4 (2)C17—C16—H16A120.1
C19—N5—C20117.9 (4)C15—C16—H16A120.1
C19—N5—Co1123.3 (3)C16—C17—C18120.8 (4)
C20—N5—Co1118.8 (3)C16—C17—H17A119.6
C22—N6—Co1122.9 (3)C18—C17—H17A119.6
C22—N6—H6B106.6C13—C18—C17118.6 (4)
Co1—N6—H6B106.6C13—C18—C19120.5 (4)
C22—N6—H6C106.6C17—C18—C19120.8 (4)
Co1—N6—H6C106.6N5—C19—C18126.1 (4)
H6B—N6—H6C106.6N5—C19—H19A117.0
N1—C1—C2111.0 (4)C18—C19—H19A117.0
N1—C1—H1A109.4N5—C20—C21112.4 (4)
C2—C1—H1A109.4N5—C20—H20A109.1
N1—C1—H1B109.4C21—C20—H20A109.1
C2—C1—H1B109.4N5—C20—H20B109.1
H1A—C1—H1B108.0C21—C20—H20B109.1
C1—C2—C3114.6 (4)H20A—C20—H20B107.9
C1—C2—H2A108.6C22—C21—C20113.3 (4)
C3—C2—H2A108.6C22—C21—H21A108.9
C1—C2—H2B108.6C20—C21—H21A108.9
C3—C2—H2B108.6C22—C21—H21B108.9
H2A—C2—H2B107.6C20—C21—H21B108.9
N2—C3—C2112.4 (4)H21A—C21—H21B107.7
N2—C3—H3A109.1N6—C22—C21111.1 (4)
C2—C3—H3A109.1N6—C22—H22A109.4
N2—C3—H3B109.1C21—C22—H22A109.4
C2—C3—H3B109.1N6—C22—H22B109.4
H3A—C3—H3B107.9C21—C22—H22B109.4
N2—C4—C5126.0 (4)H22A—C22—H22B108.0
N2—C4—H4A117.0O4—Cl1—O5110.1 (4)
C5—C4—H4A117.0O4—Cl1—O6106.7 (4)
C6—C5—C10119.4 (4)O5—Cl1—O6113.0 (4)
C6—C5—C4121.3 (4)O4—Cl1—O3107.7 (4)
C10—C5—C4119.2 (4)O5—Cl1—O3109.8 (3)
C7—C6—C5120.5 (4)O6—Cl1—O3109.3 (4)
C7—C6—H6A119.8
N4—Co1—N1—C157.8 (3)C3—N2—C4—C5172.3 (4)
N3—Co1—N1—C110.3 (14)Co1—N2—C4—C56.1 (6)
N5—Co1—N1—C1143.6 (3)N2—C4—C5—C6157.5 (4)
N2—Co1—N1—C136.3 (3)N2—C4—C5—C1025.8 (6)
N6—Co1—N1—C1124.1 (3)C10—C5—C6—C70.8 (6)
N4—Co1—N2—C4121.9 (3)C4—C5—C6—C7177.5 (4)
N3—Co1—N2—C439.6 (3)C5—C6—C7—C81.9 (7)
N5—Co1—N2—C440 (4)C6—C7—C8—C91.1 (7)
N1—Co1—N2—C4145.2 (3)C7—C8—C9—C100.9 (7)
N6—Co1—N2—C457.2 (3)C8—C9—C10—C52.0 (6)
N4—Co1—N2—C356.5 (3)C8—C9—C10—N3179.2 (4)
N3—Co1—N2—C3138.8 (3)C6—C5—C10—C91.2 (6)
N5—Co1—N2—C3138 (4)C4—C5—C10—C9175.5 (4)
N1—Co1—N2—C336.4 (3)C6—C5—C10—N3179.9 (3)
N6—Co1—N2—C3124.4 (3)C4—C5—C10—N33.3 (5)
N4—Co1—N3—C1112.4 (3)C11—N3—C10—C984.8 (5)
N5—Co1—N3—C1197.6 (3)Co1—N3—C10—C9133.5 (3)
N2—Co1—N3—C1182.4 (3)C11—N3—C10—C594.0 (4)
N1—Co1—N3—C1135.5 (14)Co1—N3—C10—C547.7 (4)
N6—Co1—N3—C11169.5 (3)C10—N3—C11—O115.6 (6)
N4—Co1—N3—C10155.0 (3)Co1—N3—C11—O1159.2 (3)
N5—Co1—N3—C10119.8 (3)C10—N3—C11—C12161.7 (3)
N2—Co1—N3—C1060.2 (3)Co1—N3—C11—C1218.1 (4)
N1—Co1—N3—C10107.1 (12)C13—N4—C12—O220.1 (6)
N6—Co1—N3—C1026.9 (3)Co1—N4—C12—O2174.8 (3)
N3—Co1—N4—C123.4 (3)C13—N4—C12—C11159.7 (3)
N5—Co1—N4—C1298.6 (3)Co1—N4—C12—C115.1 (4)
N2—Co1—N4—C1279.3 (3)O1—C11—C12—O217.8 (6)
N1—Co1—N4—C12171.7 (3)N3—C11—C12—O2164.7 (4)
N6—Co1—N4—C1275 (4)O1—C11—C12—N4162.4 (3)
N3—Co1—N4—C13150.6 (3)N3—C11—C12—N415.2 (5)
N5—Co1—N4—C1355.3 (3)C12—N4—C13—C1470.1 (5)
N2—Co1—N4—C13126.7 (3)Co1—N4—C13—C14136.2 (3)
N1—Co1—N4—C1334.3 (3)C12—N4—C13—C18108.9 (4)
N6—Co1—N4—C1379 (4)Co1—N4—C13—C1844.8 (4)
N4—Co1—N5—C1934.6 (3)C18—C13—C14—C152.5 (6)
N3—Co1—N5—C19117.1 (3)N4—C13—C14—C15178.5 (4)
N2—Co1—N5—C19117 (4)C13—C14—C15—C161.3 (7)
N1—Co1—N5—C1958.2 (3)C14—C15—C16—C171.4 (7)
N6—Co1—N5—C19146.2 (3)C15—C16—C17—C182.9 (7)
N4—Co1—N5—C20142.7 (3)C14—C13—C18—C171.0 (6)
N3—Co1—N5—C2060.3 (3)N4—C13—C18—C17179.9 (4)
N2—Co1—N5—C2061 (4)C14—C13—C18—C19176.8 (4)
N1—Co1—N5—C20124.5 (3)N4—C13—C18—C192.2 (5)
N6—Co1—N5—C2036.5 (3)C16—C17—C18—C131.7 (6)
N4—Co1—N6—C229 (4)C16—C17—C18—C19179.5 (4)
N3—Co1—N6—C2262.1 (3)C20—N5—C19—C18174.1 (4)
N5—Co1—N6—C2232.8 (3)Co1—N5—C19—C183.2 (6)
N2—Co1—N6—C22145.1 (3)C13—C18—C19—N524.4 (6)
N1—Co1—N6—C22122.6 (3)C17—C18—C19—N5157.7 (4)
Co1—N1—C1—C253.4 (5)C19—N5—C20—C21123.0 (4)
N1—C1—C2—C365.5 (5)Co1—N5—C20—C2159.5 (4)
C4—N2—C3—C2126.3 (4)N5—C20—C21—C2271.4 (5)
Co1—N2—C3—C255.2 (5)Co1—N6—C22—C2148.9 (5)
C1—C2—C3—N267.4 (5)C20—C21—C22—N664.1 (5)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
N1—H1C···O1i0.902.173.057 (5)168
N1—H1C···O2i0.902.372.876 (4)115
N6—H6B···O1i0.902.052.929 (4)166
N1—H1D···O2i0.902.522.876 (4)104
C1—H1B···O6ii0.972.453.294 (8)145
C14—H14A···O4iii0.932.553.182 (8)126
C16—H16A···O1iv0.932.433.314 (5)158
Symmetry codes: (i) x, y+1/2, z+1/2; (ii) x+1, y+1, z+1; (iii) x+1, y, z; (iv) x+1, y+1/2, z+1/2.
 

Follow Acta Cryst. E
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds