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Acta Cryst. (2004). E60, m927-m929  [ doi:10.1107/S1600536804013637 ]

Di-[mu]-thiocyanato-bis{[1,1'-bis(diphenylphosphino)ferrocene-[kappa]2P,P']copper(I)} dichloromethane disolvate

D. Li, Y.-F. Luo, T. Wu and S. W. Ng

Abstract: The 1,1'-bis(diphenylphosphino)ferrocene ligand chelates to the CuI atom forming the centrosymmetric title dimer [Cu2(NCS)2(C34H28P2)2]·2CH2Cl2. The thiocyanate ions bridge the Cu atoms, which show tetrahedral coordination. The solvent molecules are disordered over twofold rotation axes.

Online 12 June 2004


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