Acta Cryst. (2004). E60, m1051-m1052  [ doi:10.1107/S1600536804015697 ]

A second C-centered monoclinic polymorph of poly[[aquamanganese(II)]-di--(4-pyridylthioacetato)-⁶O,O':N,N:O,O']

Y.-Q. Huang, H. Zhang, J.-G. Chen and S. W. Ng

Abstract: The water-coordinated Mn atom in the title compound, [Mn(C₇H₆NO₂S)₂(H₂O)]_n is chelated by two carboxylate groups; it is also linked to the N atoms of two other carboxylate anions in a pentagonal bipyramidal environment. The compound adopts a chain architecture. The Mn and the water O atom lie on a twofold rotation axis.

Online 9 July 2004

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