cis,cis,cis-Aqua­bis­[bis­(di­phenyl­phosphino)­methane-κ²P,P′]­chloro­ruthenium(II) hexa­fluoro­phosphate methanol 1.73-solvate

The title compound, [RuCl(C₂₅H₂₂P₂)₂(H₂O)]PF₆·1.73CH₄O, contains a pseudo-octahedral ruthenium complex cation with two bidentate diphosphine ligands and cis-disposed chloro and aqua ligands, together with a disordered hexa­fluoro­phosphate anion and disordered methanol solvent mol­ecules. Identification as an aqua­ruthenium(II) complex rather than a hydroxo­ruthenium(III) complex was confirmed by cyclic voltammetry.

Key indicators

• Single-crystal X-ray study
• T = 200 K
• Mean [sigma](C-C) = 0.007 Å
• H-atom completeness 84%
• Disorder in solvent or counterion
• R factor = 0.032
• wR factor = 0.036
• Data-to-parameter ratio = 13.4

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings    Differ ....          ?
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT068_ALERT_1_C Reported F000 Differs from Calcd (or Missing)...          ?
PLAT125_ALERT_4_C No _symmetry_space_group_name_Hall Given .......          ?
PLAT141_ALERT_4_C su on a - Axis Small or Missing (x 100000) .....         20 Ang.
PLAT143_ALERT_4_C su on c - Axis Small or Missing (x 100000) .....         20 Ang.
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.12 Ratio
PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors ....        C10
PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors ....        C47
PLAT244_ALERT_4_C Low Solvent  U(eq) as Compared to Neighbors ....         P5
PLAT302_ALERT_4_C Anion/Solvent Disorder .........................      44.00 Perc.
PLAT309_ALERT_2_C Single Bonded Oxygen (C-O .GT. 1.3 Ang) ........         O2
PLAT309_ALERT_2_C Single Bonded Oxygen (C-O .GT. 1.3 Ang) ........         O3
PLAT309_ALERT_2_C Single Bonded Oxygen (C-O .GT. 1.3 Ang) ........        O21
PLAT431_ALERT_2_C Short Inter HL..A Contact  F3     ..  O3      ..       2.96 Ang.
PLAT431_ALERT_2_C Short Inter HL..A Contact  F21    ..  O21     ..       2.92 Ang.
PLAT731_ALERT_1_C Bond    Calc  2.4655(19), Rep   2.4656(8) ......       2.38 su-Rat
              RU1  -CL1     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc  2.3028(17), Rep   2.3028(8) ......       2.12 su-Rat
              RU1  -P2      1.555   1.555

Alert level G
FORMU01_ALERT_2_G  There is a discrepancy between the atom counts in the
            _chemical_formula_sum and the formula from the _atom_site* data.
            Atom count from _chemical_formula_sum:C51.73 H52.92 Cl1 F6 O2.73 P5 Ru
            Atom count from the _atom_site data:  C51.73 H44 Cl1 F6 O2.73 P5 Ru1
CELLZ01_ALERT_1_G Difference between formula and atom_site contents detected.
CELLZ01_ALERT_1_G WARNING: H atoms missing from atom site list. Is this intentional?
           From the CIF: _cell_formula_units_Z    4
           From the CIF: _chemical_formula_sum  C51.73 H52.92 Cl1 F6 O2.73 P5 Ru1
           TEST: Compare cell contents of formula and atom_site data

           atom    Z*formula  cif sites diff
           C        206.92    206.92    0.00
           H        211.68    176.00   35.68
           Cl         4.00      4.00    0.00
           F         24.00     24.00    0.00
           O         10.92     10.92    0.00
           P         20.00     20.00    0.00
           Ru         4.00      4.00    0.00
REFLT03_ALERT_4_G Please check that the estimate of the number of Friedel pairs is
            correct. If it is not, please give the correct count in the
            _publ_section_exptl_refinement section of the submitted CIF.
           From the CIF: _diffrn_reflns_theta_max           27.49
           From the CIF: _reflns_number_total              11446
           Count of symmetry unique reflns         5827
           Completeness (_total/calc)            196.43%
           TEST3: Check Friedels for noncentro structure
           Estimate of Friedel pairs measured      5619
           Fraction of Friedel pairs measured     0.964
           Are heavy atom types Z>Si present          yes

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
  18 ALERT level C = Check and explain
   4 ALERT level G = General alerts; check

   7 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   9 ALERT type 2 Indicator that the structure model may be wrong or deficient
   0 ALERT type 3 Indicator that the structure quality may be low
   6 ALERT type 4 Improvement, methodology, query or suggestion

---

Computing details

Data collection: COLLECT (Nonius, 1997); cell refinement: DENZO/SCALEPACK; data reduction: DENZO/SCALEPACK (Otwinowski & Minor, 1997); program(s) used to solve structure: SIR92 (Altomare et al., 1994); program(s) used to refine structure: CRYSTALS (Watkin et al., 2001); molecular graphics: ORTEPII (Johnson, 1976) in TEXSAN (MSC, 1992–1997); software used to prepare material for publication: CRYSTALS.

(I)

Crystal data

[RuCl(C25H22P2)2(H2O)]PF6·1.73CH4O	F(000) = 2300.6
Mr = 1123.67	Dx = 1.474 Mg m^−3
Monoclinic, Cc	Mo Kα radiation, λ = 0.71073 Å
a = 20.4427 (2) Å	Cell parameters from 50753 reflections
b = 12.7593 (2) Å	θ = 3–27°
c = 21.0262 (2) Å	µ = 0.58 mm^−1
β = 112.6186 (7)°	T = 200 K
V = 5062.53 (11) Å^3	Block, green
Z = 4	0.30 × 0.26 × 0.17 mm

Data collection

Nonius KappaCCD diffractometer	8523 reflections with I > 3σ(I)
Graphite monochromator	Rint = 0.05
φ and ω scans	θmax = 27.5°, θmin = 4.1°
Absorption correction: integration [Coppens (1970); implemented in maXus (Mackay et al., 2000)]	h = −26→26
Tmin = 0.883, Tmax = 0.957	k = −16→16
50753 measured reflections	l = −27→27
11446 independent reflections

Refinement

Refinement on F	Hydrogen site location: inferred from neighbouring sites
Least-squares matrix: full	H-atom parameters constrained
R[F^2 > 2σ(F^2)] = 0.032	Chebychev polynomial with 5 parameters: 0.771, 0.341, 0.66, 0.079, 0.197 (Carruthers & Watkin, 1979)
wR(F^2) = 0.036	(Δ/σ)max = 0.019
S = 1.05	Δρmax = 0.69 e Å^−3
8523 reflections	Δρmin = −1.37 e Å^−3
637 parameters	Absolute structure: Flack (1983), 5819 Friedel pairs
Primary atom site location: structure-invariant direct methods	Absolute structure parameter: −0.02 (2)

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ru1	0.26440 (5)	0.75092 (2)	0.63884 (5)	0.0310
Cl1	0.13507 (7)	0.75323 (9)	0.60706 (7)	0.0466
P1	0.25279 (7)	0.71516 (9)	0.52558 (6)	0.0354
P2	0.37561 (6)	0.73290 (7)	0.63668 (6)	0.0307
P3	0.29001 (6)	0.80203 (8)	0.75502 (6)	0.0324
P4	0.27368 (7)	0.93153 (7)	0.64608 (6)	0.0344
P5	0.42852 (7)	0.1815 (1)	0.88069 (7)	0.0498
F1	0.45721 (19)	0.0809 (3)	0.8562 (2)	0.0943
F2	0.3510 (2)	0.1443 (6)	0.8376 (4)	0.1177	0.730 (5)
F3	0.4303 (3)	0.2351 (4)	0.8130 (3)	0.1061	0.730 (5)
F4	0.3976 (2)	0.2802 (3)	0.9041 (3)	0.1116
F5	0.5076 (2)	0.2195 (4)	0.9201 (3)	0.0861	0.730 (5)
F6	0.4270 (5)	0.1296 (6)	0.9464 (3)	0.1401	0.730 (5)
F21	0.3759 (12)	0.2151 (15)	0.8096 (9)	0.121 (6)*	0.270 (5)
F31	0.4795 (9)	0.2668 (12)	0.876 (1)	0.105 (5)*	0.270 (5)
F51	0.4792 (11)	0.1522 (16)	0.954 (1)	0.126 (6)*	0.270 (5)
F61	0.3700 (8)	0.1009 (11)	0.8896 (9)	0.093 (4)*	0.270 (5)
O1	0.24859 (17)	0.5835 (3)	0.65252 (16)	0.0628
O2	0.2501 (3)	0.4671 (5)	0.7721 (2)	0.0888	0.730 (5)
O3	0.2883 (4)	0.3052 (6)	0.7176 (4)	0.1337	0.730 (5)
O21	0.2959 (9)	0.4097 (13)	0.7673 (8)	0.0886*	0.270 (5)
C1	0.19871 (19)	0.7787 (3)	0.44520 (17)	0.0378
C2	0.12803 (19)	0.8004 (4)	0.43093 (19)	0.0449
C3	0.0848 (2)	0.8404 (4)	0.3666 (2)	0.0496
C4	0.1123 (2)	0.8580 (3)	0.31676 (18)	0.0479
C5	0.1829 (2)	0.8375 (3)	0.3313 (2)	0.0483
C6	0.2265 (2)	0.7987 (3)	0.39515 (19)	0.0453
C7	0.2369 (2)	0.5763 (3)	0.50377 (18)	0.0463
C8	0.1692 (3)	0.5376 (4)	0.4866 (2)	0.0686
C9	0.1561 (4)	0.4293 (6)	0.4762 (3)	0.0904
C10	0.2101 (5)	0.3617 (6)	0.4838 (4)	0.1081
C11	0.2779 (4)	0.3978 (5)	0.5013 (4)	0.0939
C12	0.2916 (3)	0.5048 (4)	0.5102 (3)	0.0647
C13	0.45024 (17)	0.8226 (3)	0.67008 (18)	0.0347
C14	0.48043 (19)	0.8396 (3)	0.74061 (19)	0.0434
C15	0.5397 (2)	0.9048 (4)	0.7693 (2)	0.0593
C16	0.5685 (2)	0.9501 (4)	0.7267 (3)	0.0617
C17	0.5398 (2)	0.9331 (4)	0.6563 (3)	0.0603
C18	0.48029 (19)	0.8696 (3)	0.6279 (2)	0.0437
C19	0.42303 (18)	0.6076 (3)	0.65970 (18)	0.0388
C20	0.4208 (2)	0.5485 (3)	0.7132 (2)	0.0534
C21	0.4606 (3)	0.4531 (4)	0.7309 (3)	0.0713
C22	0.5017 (2)	0.4243 (4)	0.6959 (3)	0.0655
C23	0.5067 (3)	0.4835 (4)	0.6439 (3)	0.0650
C24	0.4676 (2)	0.5767 (3)	0.6261 (2)	0.0508
C25	0.36338 (18)	0.7559 (3)	0.83278 (16)	0.0360
C26	0.3658 (2)	0.6504 (3)	0.84897 (19)	0.0452
C27	0.4174 (2)	0.6125 (4)	0.9103 (2)	0.0548
C28	0.4666 (2)	0.6815 (4)	0.9544 (2)	0.0538
C29	0.46459 (19)	0.7853 (4)	0.93869 (19)	0.0519
C30	0.41343 (19)	0.8240 (3)	0.87792 (19)	0.0429
C31	0.22130 (17)	0.8095 (3)	0.78991 (16)	0.0345
C32	0.17114 (19)	0.7292 (3)	0.77658 (19)	0.0394
C33	0.1229 (2)	0.7288 (3)	0.8082 (2)	0.0499
C34	0.1232 (2)	0.8084 (4)	0.8528 (2)	0.0494
C35	0.1721 (2)	0.8889 (4)	0.8665 (2)	0.0509
C36	0.2211 (2)	0.8891 (3)	0.83526 (19)	0.0460
C37	0.33177 (18)	1.0140 (3)	0.61955 (18)	0.0384
C38	0.3197 (2)	1.0218 (3)	0.5499 (2)	0.0466
C39	0.3605 (3)	1.0885 (4)	0.5277 (2)	0.0599
C40	0.4131 (3)	1.1484 (4)	0.5748 (3)	0.0626
C41	0.4253 (3)	1.1421 (3)	0.6438 (2)	0.0579
C42	0.3848 (2)	1.0757 (3)	0.6662 (2)	0.0451
C43	0.1959 (2)	1.0165 (3)	0.6168 (2)	0.0445
C44	0.1468 (2)	1.0059 (4)	0.5498 (2)	0.0557
C45	0.0936 (2)	1.0812 (4)	0.5217 (3)	0.0647
C46	0.0890 (3)	1.1636 (5)	0.5614 (3)	0.0785
C47	0.1368 (4)	1.1748 (6)	0.6272 (3)	0.1040
C48	0.1908 (3)	1.1018 (5)	0.6546 (3)	0.0806
C49	0.34575 (17)	0.7418 (3)	0.54153 (16)	0.0355
C50	0.3117 (2)	0.9368 (3)	0.74060 (18)	0.0402
C51	0.2482 (4)	0.4568 (7)	0.8418 (3)	0.0761	0.730 (5)
C52	0.2833 (6)	0.3158 (7)	0.6486 (6)	0.1098	0.730 (5)
C511	0.2562 (12)	0.420 (2)	0.8134 (12)	0.0763*	0.270 (5)
H21	0.10797	0.7875	0.46674	0.0528*
H31	0.0339	0.8564	0.3566	0.0565*
H41	0.0811	0.8854	0.27042	0.0540*
H51	0.2028	0.8508	0.2954	0.0592*
H61	0.2777	0.7850	0.40537	0.0556*
H81	0.1293	0.5867	0.4815	0.0775*
H91	0.1068	0.4018	0.4632	0.0990*
H101	0.2003	0.2850	0.4766	0.1245*
H111	0.3174	0.3475	0.5075	0.1093*
H121	0.3409	0.5312	0.5214	0.0777*
H141	0.45968	0.8051	0.77127	0.0510*
H151	0.5608	0.9182	0.8200	0.0652*
H161	0.6111	0.9963	0.7469	0.0714*
H171	0.5617	0.9661	0.6261	0.0735*
H181	0.45896	0.8577	0.5770	0.0527*
H201	0.3917	0.5717	0.7395	0.0604*
H211	0.4582	0.4078	0.7688	0.0760*
H221	0.5291	0.3574	0.7088	0.0707*
H231	0.5375	0.4610	0.6192	0.0721*
H241	0.4714	0.6220	0.5888	0.0593*
H261	0.3305	0.6010	0.81674	0.0517*
H271	0.4188	0.5364	0.9222	0.0650*
H281	0.5038	0.6547	0.9980	0.0629*
H291	0.50012	0.8342	0.97105	0.0601*
H301	0.41252	0.9002	0.86663	0.0512*
H321	0.17011	0.6716	0.74393	0.0476*
H331	0.0877	0.6705	0.7987	0.0604*
H341	0.0880	0.8080	0.8752	0.0625*
H351	0.1723	0.9467	0.8986	0.0636*
H361	0.2566	0.9470	0.84551	0.0550*
H381	0.2813	0.9790	0.5155	0.0565*
H391	0.3516	1.0930	0.4776	0.0753*
H401	0.4423	1.1963	0.5588	0.0794*
H411	0.4635	1.1856	0.6779	0.0726*
H421	0.3938	1.0720	0.7164	0.0561*
H441	0.1494	0.9443	0.5214	0.0632*
H451	0.0591	1.0748	0.4729	0.0760*
H461	0.0501	1.2162	0.5418	0.0963*
H471	0.1331	1.2355	0.6558	0.1242*
H481	0.2265	1.1114	0.7026	0.0943*
H491	0.35338	0.8127	0.52531	0.0417*
H492	0.36756	0.6873	0.52166	0.0417*
H501	0.2878	0.9898	0.75934	0.0479*
H502	0.3639	0.9503	0.75973	0.0479*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ru1	0.0226 (1)	0.04559 (12)	0.0223 (1)	−0.00268 (11)	0.00584 (7)	0.00300 (11)
Cl1	0.0248 (4)	0.0782 (7)	0.0324 (4)	−0.0018 (4)	0.0062 (3)	0.0099 (4)
P1	0.0273 (4)	0.0538 (6)	0.0225 (4)	−0.0040 (4)	0.0066 (3)	0.0011 (4)
P2	0.0227 (4)	0.0413 (5)	0.0267 (4)	−0.0014 (3)	0.0080 (3)	0.0007 (3)
P3	0.0275 (4)	0.0439 (6)	0.0238 (4)	−0.0007 (4)	0.0075 (3)	0.0032 (4)
P4	0.0308 (4)	0.0456 (5)	0.0268 (4)	0.0030 (4)	0.0109 (4)	0.0057 (4)
P5	0.0399 (5)	0.0682 (7)	0.0426 (5)	−0.0110 (5)	0.0173 (4)	−0.0122 (5)
F1	0.092 (2)	0.086 (2)	0.119 (3)	0.0013 (18)	0.056 (2)	−0.029 (2)
F2	0.039 (2)	0.163 (6)	0.143 (5)	−0.039 (3)	0.026 (3)	−0.092 (5)
F3	0.115 (4)	0.134 (5)	0.080 (3)	0.009 (3)	0.049 (3)	0.042 (3)
F4	0.089 (3)	0.094 (3)	0.154 (4)	−0.001 (2)	0.049 (3)	−0.052 (3)
F5	0.040 (2)	0.102 (3)	0.104 (4)	−0.017 (2)	0.014 (2)	−0.036 (3)
F6	0.217 (8)	0.163 (6)	0.078 (4)	0.005 (6)	0.098 (5)	0.034 (4)
O1	0.0572 (18)	0.070 (2)	0.0505 (18)	−0.0158 (15)	0.0088 (14)	0.0081 (15)
O2	0.109 (5)	0.106 (5)	0.049 (3)	−0.036 (4)	0.028 (3)	0.012 (3)
O3	0.152 (7)	0.123 (6)	0.090 (5)	0.032 (5)	0.006 (5)	−0.021 (4)
C1	0.0309 (17)	0.056 (2)	0.0260 (15)	−0.0039 (16)	0.0103 (13)	−0.0020 (14)
C2	0.0301 (17)	0.068 (3)	0.0340 (18)	−0.0032 (18)	0.0093 (14)	0.0002 (18)
C3	0.0334 (19)	0.071 (3)	0.036 (2)	0.0026 (18)	0.0050 (16)	0.0057 (18)
C4	0.046 (2)	0.058 (2)	0.0311 (18)	0.0023 (17)	0.0052 (16)	0.0095 (15)
C5	0.055 (2)	0.060 (2)	0.0336 (18)	−0.0012 (19)	0.0204 (17)	0.0059 (17)
C6	0.0383 (18)	0.063 (2)	0.0375 (19)	0.0009 (18)	0.0180 (16)	0.0061 (17)
C7	0.044 (2)	0.060 (2)	0.0296 (17)	−0.0112 (18)	0.0084 (15)	−0.0047 (16)
C8	0.058 (3)	0.080 (3)	0.056 (3)	−0.028 (2)	0.009 (2)	−0.008 (2)
C9	0.082 (4)	0.093 (5)	0.072 (3)	−0.048 (4)	0.003 (3)	−0.015 (3)
C10	0.142 (7)	0.069 (4)	0.100 (5)	−0.043 (5)	0.032 (5)	−0.042 (4)
C11	0.113 (5)	0.057 (3)	0.103 (4)	−0.012 (3)	0.032 (4)	−0.036 (3)
C12	0.070 (3)	0.064 (3)	0.061 (3)	−0.002 (2)	0.025 (2)	−0.019 (2)
C13	0.0238 (14)	0.0403 (19)	0.0381 (17)	0.0012 (13)	0.0099 (13)	−0.0003 (14)
C14	0.0358 (18)	0.052 (2)	0.0401 (19)	−0.0015 (16)	0.0116 (15)	−0.0016 (16)
C15	0.041 (2)	0.063 (3)	0.059 (3)	−0.0078 (19)	0.0028 (19)	−0.013 (2)
C16	0.040 (2)	0.056 (3)	0.083 (3)	−0.0187 (19)	0.016 (2)	−0.011 (2)
C17	0.045 (2)	0.060 (3)	0.079 (3)	−0.013 (2)	0.027 (2)	−0.002 (2)
C18	0.0331 (17)	0.051 (2)	0.048 (2)	−0.0042 (16)	0.0164 (16)	0.0003 (17)
C19	0.0324 (17)	0.0411 (19)	0.0345 (17)	−0.0025 (15)	0.0034 (14)	−0.0003 (14)
C20	0.038 (2)	0.059 (3)	0.054 (2)	−0.0011 (18)	0.0075 (17)	0.016 (2)
C21	0.053 (3)	0.067 (3)	0.070 (3)	−0.009 (2)	−0.003 (2)	0.032 (3)
C22	0.050 (3)	0.048 (3)	0.078 (3)	0.002 (2)	0.003 (2)	−0.003 (2)
C23	0.064 (3)	0.063 (3)	0.053 (2)	0.017 (2)	0.006 (2)	−0.006 (2)
C24	0.048 (2)	0.056 (3)	0.044 (2)	0.0161 (18)	0.0133 (17)	0.0022 (18)
C25	0.0262 (15)	0.061 (2)	0.0208 (13)	0.0000 (15)	0.0086 (12)	−0.0006 (15)
C26	0.0386 (19)	0.055 (2)	0.0352 (18)	−0.0001 (17)	0.0072 (15)	0.0093 (16)
C27	0.044 (2)	0.075 (3)	0.043 (2)	0.013 (2)	0.0145 (18)	0.023 (2)
C28	0.0347 (19)	0.094 (4)	0.0284 (18)	0.010 (2)	0.0077 (15)	0.010 (2)
C29	0.0286 (17)	0.093 (3)	0.0284 (17)	0.0003 (19)	0.0049 (14)	−0.0012 (19)
C30	0.0317 (18)	0.063 (3)	0.0337 (18)	0.0015 (16)	0.0118 (15)	0.0001 (16)
C31	0.0291 (15)	0.045 (2)	0.0274 (15)	0.0040 (14)	0.0082 (13)	0.0051 (14)
C32	0.0353 (17)	0.047 (2)	0.0363 (18)	0.0004 (14)	0.0149 (14)	0.0022 (15)
C33	0.043 (2)	0.065 (3)	0.043 (2)	−0.0060 (18)	0.0182 (17)	0.0069 (18)
C34	0.043 (2)	0.075 (3)	0.038 (2)	0.012 (2)	0.0243 (17)	0.0125 (19)
C35	0.056 (2)	0.059 (3)	0.044 (2)	0.010 (2)	0.0263 (19)	0.0017 (18)
C36	0.045 (2)	0.054 (2)	0.0390 (19)	−0.0023 (17)	0.0155 (16)	0.0002 (16)
C37	0.0356 (17)	0.044 (2)	0.0371 (17)	0.0086 (15)	0.0157 (14)	0.0064 (15)
C38	0.045 (2)	0.056 (2)	0.0405 (19)	0.0019 (17)	0.0180 (16)	0.0116 (17)
C39	0.068 (3)	0.070 (3)	0.051 (2)	−0.003 (2)	0.032 (2)	0.016 (2)
C40	0.071 (3)	0.057 (3)	0.070 (3)	−0.011 (2)	0.039 (2)	0.009 (2)
C41	0.067 (3)	0.052 (3)	0.062 (3)	−0.019 (2)	0.034 (2)	−0.006 (2)
C42	0.053 (2)	0.042 (2)	0.045 (2)	−0.0048 (17)	0.0246 (18)	−0.0021 (16)
C43	0.0324 (17)	0.066 (2)	0.0376 (18)	0.0075 (17)	0.0161 (15)	0.0065 (18)
C44	0.043 (2)	0.074 (3)	0.041 (2)	0.010 (2)	0.0062 (17)	0.0096 (19)
C45	0.043 (2)	0.092 (4)	0.055 (3)	0.016 (2)	0.0142 (19)	0.026 (2)
C46	0.061 (3)	0.104 (4)	0.075 (3)	0.044 (3)	0.032 (3)	0.031 (3)
C47	0.102 (5)	0.136 (6)	0.072 (4)	0.070 (4)	0.032 (4)	−0.001 (4)
C48	0.076 (3)	0.111 (4)	0.049 (3)	0.049 (3)	0.017 (2)	−0.005 (3)
C49	0.0268 (15)	0.050 (2)	0.0270 (15)	−0.0019 (14)	0.0078 (12)	0.0053 (15)
C50	0.0394 (18)	0.050 (2)	0.0306 (16)	−0.0049 (16)	0.0125 (14)	0.0036 (15)
C51	0.093 (5)	0.089 (6)	0.050 (4)	−0.011 (4)	0.032 (4)	0.012 (3)
C52	0.129 (9)	0.080 (6)	0.104 (8)	0.026 (5)	0.027 (7)	−0.008 (5)

Geometric parameters (Å, º)

Ru1—Cl1	2.4656 (8)	C17—H171	1.000
Ru1—P1	2.345 (1)	C18—H181	1.000
Ru1—P2	2.3028 (8)	C19—C20	1.369 (5)
Ru1—P3	2.3839 (9)	C19—C24	1.406 (5)
Ru1—P4	2.312 (1)	C20—C21	1.432 (6)
Ru1—O1	2.196 (3)	C20—H201	1.000
P1—C1	1.816 (4)	C21—C22	1.363 (7)
P1—C7	1.827 (4)	C21—H211	1.000
P1—C49	1.830 (3)	C22—C23	1.364 (7)
P2—C13	1.818 (3)	C22—H221	1.000
P2—C19	1.836 (4)	C23—C24	1.402 (7)
P2—C49	1.857 (3)	C23—H231	1.000
P3—C25	1.839 (3)	C24—H241	1.000
P3—C31	1.820 (3)	C25—C26	1.385 (5)
P3—C50	1.830 (4)	C25—C30	1.398 (5)
P4—C37	1.827 (4)	C26—C27	1.401 (5)
P4—C43	1.824 (4)	C26—H261	1.000
P4—C50	1.836 (3)	C27—C28	1.389 (6)
P5—F1	1.578 (3)	C27—H271	1.000
P5—F2	1.567 (4)	C28—C29	1.362 (7)
P5—F3	1.593 (4)	C28—H281	1.000
P5—F4	1.571 (4)	C29—C30	1.394 (5)
P5—F5	1.582 (4)	C29—H291	1.000
P5—F6	1.542 (5)	C30—H301	1.000
P5—F21	1.529 (19)	C31—C32	1.399 (5)
P5—F31	1.537 (16)	C31—C36	1.394 (5)
P5—F51	1.53 (2)	C32—C33	1.385 (5)
P5—F61	1.642 (15)	C32—H321	1.000
O2—C51	1.487 (6)	C33—C34	1.381 (6)
O3—C52	1.422 (13)	C33—H331	1.000
O21—C511	1.49 (1)	C34—C35	1.384 (6)
C1—C2	1.386 (5)	C34—H341	1.000
C1—C6	1.399 (5)	C35—C36	1.392 (5)
C2—C3	1.396 (5)	C35—H351	1.000
C2—H21	1.000	C36—H361	1.000
C3—C4	1.386 (5)	C37—C38	1.392 (5)
C3—H31	1.000	C37—C42	1.392 (5)
C4—C5	1.380 (6)	C38—C39	1.392 (6)
C4—H41	1.000	C38—H381	1.000
C5—C6	1.386 (5)	C39—C40	1.378 (7)
C5—H51	1.000	C39—H391	1.000
C6—H61	1.000	C40—C41	1.377 (7)
C7—C8	1.380 (6)	C40—H401	1.000
C7—C12	1.410 (7)	C41—C42	1.388 (5)
C8—C9	1.410 (8)	C41—H411	1.000
C8—H81	1.000	C42—H421	1.000
C9—C10	1.36 (1)	C43—C44	1.388 (5)
C9—H91	1.000	C43—C48	1.376 (6)
C10—C11	1.37 (1)	C44—C45	1.400 (6)
C10—H101	1.000	C44—H441	1.000
C11—C12	1.392 (7)	C45—C46	1.368 (8)
C11—H111	1.000	C45—H451	1.000
C12—H121	1.000	C46—C47	1.361 (8)
C13—C14	1.387 (5)	C46—H461	1.000
C13—C18	1.394 (5)	C47—C48	1.389 (7)
C14—C15	1.401 (5)	C47—H471	1.000
C14—H141	1.000	C48—H481	1.000
C15—C16	1.375 (7)	C49—H491	1.000
C15—H151	1.000	C49—H492	1.000
C16—C17	1.382 (7)	C50—H501	1.000
C16—H161	1.000	C50—H502	1.000
C17—C18	1.390 (5)	C47—C48	1.389 (7)
F1···C30^i	3.474 (5)	O2···O3	2.623 (11)
F1···C50^i	3.546 (5)	O2···C26	3.277 (7)
F2···O3	3.12 (1)	O2···C16^vi	3.466 (7)
F2···C50^i	3.249 (9)	O3···O21	1.66 (2)
F2···C6^ii	3.292 (8)	O3···C48^i	3.230 (9)
F2···C5^ii	3.396 (7)	O3···C47^i	3.38 (1)
F3···O3	2.962 (9)	O21···C26	3.54 (2)
F3···O21	3.38 (2)	C2···C28^vii	3.527 (6)
F3···C21	3.453 (8)	C2···C29^vii	3.578 (6)
F3···C42^i	3.510 (7)	C3···C14^vii	3.535 (5)
F4···O21	3.28 (2)	C3···C28^vii	3.572 (7)
F4···C511	3.31 (2)	C4···C35^viii	3.469 (6)
F4···C49^ii	3.451 (8)	C4···C14^vii	3.587 (5)
F4···C6^ii	3.575 (6)	C5···C36^viii	3.569 (5)
F5···C46^iii	3.165 (8)	C5···C35^viii	3.593 (6)
F5···C45^iii	3.351 (7)	C6···C511^ix	3.45 (3)
F5···C34^iv	3.383 (8)	C6···C51^ix	3.53 (1)
F5···C9^v	3.385 (9)	C7···C51^ix	3.526 (8)
F6···C49^ii	3.47 (1)	C10···C52	3.26 (1)
F6···C18^ii	3.543 (7)	C10···C34^ix	3.419 (9)
F21···O3	2.37 (2)	C11···C52	3.23 (2)
F21···O21	2.92 (3)	C12···C51^ix	3.339 (9)
F21···C52	3.43 (2)	C16···C51^x	3.539 (7)
F21···C42^i	3.57 (2)	C16···C511^x	3.58 (2)
F31···C34^iv	3.20 (2)	C22···C34^iv	3.597 (6)
F51···C46^iii	3.43 (2)	C24···C46^iv	3.440 (9)
F61···C6^ii	3.24 (2)	C26···C51	3.41 (1)
F61···C50^i	3.57 (2)	C26···C511	3.60 (3)
O1···O2	2.910 (6)	C29···C40^xi	3.512 (8)
O1···O21	3.14 (2)	C47···C52^xii	3.37 (1)
O1···C52	3.50 (1)	C48···C52^xii	3.35 (1)
Cl1—Ru1—P1	92.74 (3)	C16—C15—H151	120.5
Cl1—Ru1—P2	163.69 (3)	C15—C16—C17	121.2 (4)
P1—Ru1—P2	71.08 (3)	C15—C16—H161	119.4
Cl1—Ru1—P3	93.70 (3)	C17—C16—H161	119.4
P1—Ru1—P3	172.00 (4)	C16—C17—C18	119.6 (4)
P2—Ru1—P3	102.60 (3)	C16—C17—H171	120.2
Cl1—Ru1—P4	93.34 (4)	C18—C17—H171	120.2
P1—Ru1—P4	103.56 (4)	C13—C18—C17	120.3 (4)
P2—Ru1—P4	92.54 (3)	C13—C18—H181	119.9
P3—Ru1—P4	71.33 (3)	C17—C18—H181	119.9
Cl1—Ru1—O1	81.41 (9)	P2—C19—C20	121.0 (3)
P1—Ru1—O1	88.92 (9)	P2—C19—C24	119.3 (3)
P2—Ru1—O1	95.83 (9)	C20—C19—C24	119.4 (4)
P3—Ru1—O1	96.74 (9)	C19—C20—C21	119.2 (4)
P4—Ru1—O1	166.73 (9)	C19—C20—H201	120.4
Ru1—P1—C1	130.23 (13)	C21—C20—H201	120.4
Ru1—P1—C7	112.46 (12)	C20—C21—C22	119.6 (4)
C1—P1—C7	102.30 (17)	C20—C21—H211	120.2
Ru1—P1—C49	94.90 (11)	C22—C21—H211	120.2
C1—P1—C49	107.77 (16)	C21—C22—C23	122.4 (5)
C7—P1—C49	107.35 (18)	C21—C22—H221	118.8
Ru1—P2—C13	128.14 (11)	C23—C22—H221	118.8
Ru1—P2—C19	120.47 (12)	C22—C23—C24	118.2 (5)
C13—P2—C19	99.60 (15)	C22—C23—H231	120.9
Ru1—P2—C49	95.6 (1)	C24—C23—H231	120.9
C13—P2—C49	104.88 (16)	C19—C24—C23	121.1 (4)
C19—P2—C49	105.00 (17)	C19—C24—H241	119.5
Ru1—P3—C25	127.30 (11)	C23—C24—H241	119.5
Ru1—P3—C31	121.86 (11)	P3—C25—C26	118.0 (3)
C25—P3—C31	98.65 (15)	P3—C25—C30	122.6 (3)
Ru1—P3—C50	93.38 (11)	C26—C25—C30	119.3 (3)
C25—P3—C50	106.33 (17)	C25—C26—C27	120.3 (4)
C31—P3—C50	106.96 (17)	C25—C26—H261	119.8
Ru1—P4—C37	126.88 (12)	C27—C26—H261	119.8
Ru1—P4—C43	122.09 (14)	C26—C27—C28	119.4 (4)
C37—P4—C43	98.01 (17)	C26—C27—H271	120.3
Ru1—P4—C50	95.60 (12)	C28—C27—H271	120.3
C37—P4—C50	104.78 (16)	C27—C28—C29	120.5 (4)
C43—P4—C50	107.13 (18)	C27—C28—H281	119.7
F1—P5—F2	89.2 (2)	C29—C28—H281	119.8
F1—P5—F3	85.3 (3)	C28—C29—C30	120.6 (4)
F2—P5—F3	88.8 (4)	C28—C29—H291	119.7
F1—P5—F4	178.2 (2)	C30—C29—H291	119.7
F2—P5—F4	89.1 (2)	C25—C30—C29	119.9 (4)
F3—P5—F4	94.9 (3)	C25—C30—H301	120.1
F1—P5—F5	89.2 (2)	C29—C30—H301	120.1
F2—P5—F5	176.6 (3)	P3—C31—C32	120.1 (3)
F3—P5—F5	88.1 (3)	P3—C31—C36	121.3 (3)
F4—P5—F5	92.5 (2)	C32—C31—C36	118.4 (3)
F1—P5—F6	94.6 (3)	C31—C32—C33	120.6 (4)
F2—P5—F6	91.4 (5)	C31—C32—H321	119.7
F3—P5—F6	179.9 (5)	C33—C32—H321	119.7
F4—P5—F6	85.1 (3)	C32—C33—C34	120.3 (4)
F5—P5—F6	91.8 (4)	C32—C33—H331	119.8
F1—P5—F21	96.9 (7)	C34—C33—H331	119.8
F4—P5—F21	82.2 (7)	C33—C34—C35	120.1 (3)
F1—P5—F31	102.0 (6)	C33—C34—H341	120.0
F4—P5—F31	79.5 (6)	C35—C34—H341	120.0
F1—P5—F51	86.3 (8)	C34—C35—C36	119.7 (4)
F4—P5—F51	94.6 (8)	C34—C35—H351	120.1
F1—P5—F61	84.6 (5)	C36—C35—H351	120.1
F4—P5—F61	93.9 (5)	C31—C36—C35	120.9 (4)
F21—P5—F31	88.7 (11)	C31—C36—H361	119.6
F21—P5—F51	176.8 (11)	C35—C36—H361	119.6
F31—P5—F51	91.5 (11)	P4—C37—C38	119.3 (3)
F21—P5—F61	91.0 (10)	P4—C37—C42	122.1 (3)
F31—P5—F61	173.4 (8)	C38—C37—C42	118.4 (3)
F51—P5—F61	88.5 (10)	C37—C38—C39	120.6 (4)
P1—C1—C2	120.1 (3)	C37—C38—H381	119.7
P1—C1—C6	120.2 (3)	C39—C38—H381	119.7
C2—C1—C6	119.5 (3)	C38—C39—C40	120.1 (4)
C1—C2—C3	120.1 (3)	C38—C39—H391	120.0
C1—C2—H21	119.9	C40—C39—H391	120.0
C3—C2—H21	119.9	C39—C40—C41	120.0 (4)
C2—C3—C4	120.1 (4)	C39—C40—H401	120.0
C2—C3—H31	119.9	C41—C40—H401	120.0
C4—C3—H31	119.9	C40—C41—C42	120.1 (4)
C3—C4—C5	119.7 (3)	C40—C41—H411	119.9
C3—C4—H41	120.2	C42—C41—H411	119.9
C5—C4—H41	120.1	C37—C42—C41	120.7 (4)
C4—C5—C6	120.8 (4)	C37—C42—H421	119.6
C4—C5—H51	119.6	C41—C42—H421	119.6
C6—C5—H51	119.6	P4—C43—C44	118.8 (3)
C1—C6—C5	119.8 (4)	P4—C43—C48	121.7 (3)
C1—C6—H61	120.1	C44—C43—C48	118.5 (4)
C5—C6—H61	120.1	C43—C44—C45	120.1 (5)
P1—C7—C8	118.5 (4)	C43—C44—H441	119.9
P1—C7—C12	123.0 (3)	C45—C44—H441	119.9
C8—C7—C12	118.2 (4)	C44—C45—C46	119.7 (4)
C7—C8—C9	120.2 (6)	C44—C45—H451	120.2
C7—C8—H81	119.9	C46—C45—H451	120.1
C9—C8—H81	119.9	C45—C46—C47	120.7 (5)
C8—C9—C10	120.3 (6)	C45—C46—H461	119.6
C8—C9—H91	119.8	C47—C46—H461	119.7
C10—C9—H91	119.8	C46—C47—C48	119.8 (6)
C9—C10—C11	120.7 (6)	C46—C47—H471	120.1
C9—C10—H101	119.6	C48—C47—H471	120.1
C11—C10—H101	119.6	C43—C48—C47	121.1 (5)
C10—C11—C12	119.7 (7)	C43—C48—H481	119.5
C10—C11—H111	120.1	C47—C48—H481	119.4
C12—C11—H111	120.1	P1—C49—P2	94.24 (15)
C7—C12—C11	120.7 (5)	P1—C49—H491	113.13
C7—C12—H121	119.6	P2—C49—H491	113.13
C11—C12—H121	119.6	P1—C49—H492	113.14
P2—C13—C14	118.3 (3)	P2—C49—H492	113.14
P2—C13—C18	122.3 (3)	H491—C49—H492	109.467
C14—C13—C18	119.3 (3)	P3—C50—P4	96.68 (18)
C13—C14—C15	120.6 (4)	P3—C50—H501	112.57
C13—C14—H141	119.7	P4—C50—H501	112.56
C15—C14—H141	119.7	P3—C50—H502	112.57
C14—C15—C16	119.1 (4)	P4—C50—H502	112.57
C14—C15—H151	120.5	H501—C50—H502	109.467
Ru1—P1—C1—C2	−46.7 (4)	O1—Ru1—P2—C13	−145.2 (2)
Ru1—P1—C1—C6	138.2 (3)	O1—Ru1—P2—C19	−10.2 (2)
Ru1—P1—C7—C8	79.6 (3)	O1—Ru1—P2—C49	100.9 (1)
Ru1—P1—C7—C12	−93.9 (4)	O1—Ru1—P3—C25	60.6 (2)
Ru1—P1—C49—P2	16.8 (1)	O1—Ru1—P3—C31	−73.5 (2)
Ru1—P2—C13—C14	65.0 (3)	O1—Ru1—P3—C50	174.1 (2)
Ru1—P2—C13—C18	−118.7 (3)	O1—Ru1—P4—C37	151.7 (4)
Ru1—P2—C19—C20	−39.8 (3)	O1—Ru1—P4—C43	−75.8 (4)
Ru1—P2—C19—C24	146.2 (2)	O1—Ru1—P4—C50	38.5 (4)
Ru1—P2—C49—P1	−17.1 (1)	C1—P1—C7—C8	−64.1 (4)
Ru1—P3—C25—C26	−62.4 (4)	C1—P1—C7—C12	122.4 (4)
Ru1—P3—C25—C30	121.9 (3)	C1—C2—C3—C4	0.3 (7)
Ru1—P3—C31—C32	44.4 (3)	C1—C6—C5—C4	0.8 (6)
Ru1—P3—C31—C36	−141.6 (2)	C2—C1—P1—C7	87.5 (4)
Ru1—P3—C50—P4	14.3 (2)	C2—C1—P1—C49	−159.6 (3)
Ru1—P4—C37—C38	67.3 (3)	C2—C1—C6—C5	−1.6 (6)
Ru1—P4—C37—C42	−117.5 (3)	C2—C3—C4—C5	−1.1 (7)
Ru1—P4—C43—C44	−54.8 (4)	C3—C2—C1—C6	1.0 (7)
Ru1—P4—C43—C48	136.8 (4)	C3—C4—C5—C6	0.5 (6)
Ru1—P4—C50—P3	−14.8 (2)	C6—C1—P1—C7	−87.6 (3)
Cl1—Ru1—P1—C1	49.6 (2)	C6—C1—P1—C49	25.3 (4)
Cl1—Ru1—P1—C7	−81.1 (1)	C7—C8—C9—C10	0.8 (9)
Cl1—Ru1—P1—C49	167.9 (1)	C7—C12—C11—C10	2 (1)
Cl1—Ru1—P2—C13	135.5 (2)	C8—C7—P1—C49	−177.4 (3)
Cl1—Ru1—P2—C19	−89.5 (2)	C8—C7—C12—C11	−1.7 (8)
Cl1—Ru1—P2—C49	21.6 (2)	C8—C9—C10—C11	−0 (1)
Cl1—Ru1—P3—C25	142.4 (2)	C9—C8—C7—C12	0.2 (7)
Cl1—Ru1—P3—C31	8.2 (2)	C9—C10—C11—C12	−1 (1)
Cl1—Ru1—P3—C50	−104.1 (1)	C12—C7—P1—C49	9.1 (5)
Cl1—Ru1—P4—C37	−142.2 (1)	C13—P2—C19—C20	105.9 (3)
Cl1—Ru1—P4—C43	−9.6 (2)	C13—P2—C19—C24	−68.1 (3)
Cl1—Ru1—P4—C50	104.6 (2)	C13—C14—C15—C16	−1.3 (6)
P1—Ru1—P2—C13	127.9 (2)	C13—C18—C17—C16	−0.7 (7)
P1—Ru1—P2—C19	−97.0 (1)	C14—C13—P2—C19	−76.9 (3)
P1—Ru1—P2—C49	14.0 (1)	C14—C13—P2—C49	174.7 (3)
P1—Ru1—P4—C37	−48.5 (1)	C14—C13—C18—C17	−0.2 (6)
P1—Ru1—P4—C43	84.0 (2)	C14—C15—C16—C17	0.5 (7)
P1—Ru1—P4—C50	−161.7 (1)	C15—C14—C13—C18	1.2 (6)
P1—C1—C2—C3	−174.1 (4)	C15—C16—C17—C18	0.5 (7)
P1—C1—C6—C5	173.5 (3)	C18—C13—P2—C19	99.4 (3)
P1—C7—C8—C9	−173.6 (4)	C18—C13—P2—C49	−9.1 (4)
P1—C7—C12—C11	171.8 (5)	C19—C20—C21—C22	2.1 (6)
P1—C49—P2—C13	−149.0 (2)	C19—C24—C23—C22	−1.4 (6)
P1—C49—P2—C19	106.5 (2)	C20—C19—P2—C49	−145.7 (3)
P2—Ru1—P1—C1	−132.5 (2)	C20—C19—C24—C23	3.6 (5)
P2—Ru1—P1—C7	96.8 (1)	C20—C21—C22—C23	0.1 (7)
P2—Ru1—P1—C49	−14.2 (1)	C21—C20—C19—C24	−3.8 (5)
P2—Ru1—P3—C25	−37.0 (2)	C21—C22—C23—C24	−0.4 (7)
P2—Ru1—P3—C31	−171.1 (1)	C24—C19—P2—C49	40.3 (3)
P2—Ru1—P3—C50	76.6 (1)	C25—P3—C31—C32	−100.3 (3)
P2—Ru1—P4—C37	22.6 (1)	C25—P3—C31—C36	73.7 (3)
P2—Ru1—P4—C43	155.1 (2)	C25—C26—C27—C28	−0.7 (7)
P2—Ru1—P4—C50	−90.6 (2)	C25—C30—C29—C28	0.4 (7)
P2—C13—C14—C15	177.6 (3)	C26—C25—P3—C31	79.5 (4)
P2—C13—C18—C17	−176.4 (3)	C26—C25—P3—C50	−169.9 (4)
P2—C19—C20—C21	−177.8 (3)	C26—C25—C30—C29	−0.5 (7)
P2—C19—C24—C23	177.7 (3)	C26—C27—C28—C29	0.5 (7)
P2—C49—P1—C1	151.9 (2)	C27—C26—C25—C30	0.7 (7)
P2—C49—P1—C7	−98.6 (2)	C27—C28—C29—C30	−0.4 (7)
P3—Ru1—P2—C13	−47.0 (2)	C30—C25—P3—C31	−96.2 (4)
P3—Ru1—P2—C19	88.1 (1)	C30—C25—P3—C50	14.4 (4)
P3—Ru1—P2—C49	−160.9 (1)	C31—C32—C33—C34	0.7 (5)
P3—Ru1—P4—C37	125.1 (1)	C31—C36—C35—C34	0.4 (5)
P3—Ru1—P4—C43	−102.4 (2)	C32—C31—P3—C50	149.6 (3)
P3—Ru1—P4—C50	11.8 (1)	C32—C31—C36—C35	−0.1 (5)
P3—C25—C26—C27	−175.2 (4)	C32—C33—C34—C35	−0.4 (6)
P3—C25—C30—C29	175.1 (3)	C33—C32—C31—C36	−0.5 (5)
P3—C31—C32—C33	173.7 (3)	C33—C34—C35—C36	−0.2 (6)
P3—C31—C36—C35	−174.2 (3)	C36—C31—P3—C50	−36.4 (3)
P3—C50—P4—C37	−145.3 (2)	C37—P4—C43—C44	88.7 (4)
P3—C50—P4—C43	111.3 (2)	C37—P4—C43—C48	−79.8 (5)
P4—Ru1—P1—C1	−44.5 (2)	C37—C38—C39—C40	−0.6 (7)
P4—Ru1—P1—C7	−175.2 (1)	C37—C42—C41—C40	0.5 (7)
P4—Ru1—P1—C49	73.8 (1)	C38—C37—P4—C43	−73.6 (3)
P4—Ru1—P2—C13	24.4 (2)	C38—C37—P4—C50	176.3 (3)
P4—Ru1—P2—C19	159.5 (1)	C38—C37—C42—C41	−1.0 (6)
P4—Ru1—P2—C49	−89.4 (1)	C38—C39—C40—C41	0.1 (8)
P4—Ru1—P3—C25	−125.4 (2)	C39—C38—C37—C42	1.0 (6)
P4—Ru1—P3—C31	100.5 (2)	C39—C40—C41—C42	−0.1 (8)
P4—Ru1—P3—C50	−11.8 (1)	C42—C37—P4—C43	101.6 (3)
P4—C37—C38—C39	176.4 (4)	C42—C37—P4—C50	−8.5 (4)
P4—C37—C42—C41	−176.2 (3)	C43—C44—C45—C46	−2.0 (8)
P4—C43—C44—C45	−168.6 (4)	C43—C48—C47—C46	−2 (1)
P4—C43—C48—C47	170.0 (6)	C44—C43—P4—C50	−163.0 (4)
P4—C50—P3—C25	144.8 (2)	C44—C43—C48—C47	1.5 (9)
P4—C50—P3—C31	−110.5 (2)	C44—C45—C46—C47	2 (1)
O1—Ru1—P1—C1	131.0 (2)	C45—C44—C43—C48	0.3 (8)
O1—Ru1—P1—C7	0.3 (2)	C45—C46—C47—C48	−0 (1)
O1—Ru1—P1—C49	−110.8 (2)	C48—C43—P4—C50	28.5 (5)

Symmetry codes: (i) x, y−1, z; (ii) x, −y+1, z+1/2; (iii) x+1/2, −y+3/2, z+1/2; (iv) x+1/2, y−1/2, z; (v) x+1/2, −y+1/2, z+1/2; (vi) x−1/2, y−1/2, z; (vii) x−1/2, −y+3/2, z−1/2; (viii) x, −y+2, z−1/2; (ix) x, −y+1, z−1/2; (x) x+1/2, y+1/2, z; (xi) x, −y+2, z+1/2; (xii) x, y+1, z.