Acta Cryst. (2004). E60, m1183-m1184  [ doi:10.1107/S1600536804018069 ]

Tribromo(⁵-1,2,3-trimethylcyclopentadienyl)titanium(IV)

M. Erben, I. Císarová, J. Vinklárek and M. Pavlista

Abstract: The crystal structure of the title compound, [TiBr₃(Me₃Cp)], where Me₃Cp is 1,2,3-trimethylcyclopentadienyl (C₈H₁₁), has been determined. The molecule has a typical piano-stool structure in which one ⁵-bonded trimethylcyclopentadienyl ring and three bromide ligands occupy the pseudo-tetrahedral coordination sites around the titanium(IV) centre. The Ti-ring distance is 2.0162  (16)  Å.

Online 24 July 2004

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