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In the title compound, the centrosymmetric polyanion consists of ten VO6 edge-sharing distorted octahedra. Each of the two Li+ cations is surrounded by six water molecules in a distorted octahedral arrangement. The V...V distances are in the range 3.078 (5)–3.101 (5) Å and the four types of V—O bond lengths are in the range 1.601 (2)–2.361 (2) Å. The title compound is isostructural with (NH4)4Na2[V10O28]·10H2O and K4Na2[V10O28]·10H2O. It provides the first example of a decavanadate salt of a lithium cation.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804017416/dn6142sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536804017416/dn6142Isup2.hkl
Contains datablock I

Key indicators

  • Single-crystal X-ray study
  • T = 293 K
  • Mean [sigma](V-O) = 0.002 Å
  • R factor = 0.030
  • wR factor = 0.093
  • Data-to-parameter ratio = 12.2

checkCIF/PLATON results

No syntax errors found



Alert level C PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT480_ALERT_4_C Long H...A H-Bond Reported H6 .. O14 .. 2.62 Ang. PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........ 5 PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 2 H4 N PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 4 H2 O PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 5 H2 O PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 6 H2 O PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 7 H2 O PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 8 H2 O PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 9 Li
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 10 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 0 ALERT type 2 Indicator that the structure model may be wrong or deficient 0 ALERT type 3 Indicator that the structure quality may be low 9 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: CAD-4 EXPRESS (Duisenberg, 1992; Macíček & Yordanov, 1992); cell refinement: CAD-4 EXPRESS; data reduction: MolEN (Fair, 1990); program(s) used to solve structure: SHELXS97 (Sheldrick, 1990); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: DIAMOND (Brandenburg, 1998); software used to prepare material for publication: SHELXL97.

(I) top
Crystal data top
(NH4)4Li2[V10O28]·10H2OZ = 1
Mr = 1223.61F(000) = 604
Triclinic, P1Dx = 2.439 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 8.523 (2) ÅCell parameters from 25 reflections
b = 10.272 (2) Åθ = 2–27°
c = 11.110 (2) ŵ = 2.80 mm1
α = 68.42 (2)°T = 293 K
β = 87.05 (2)°Hexagonal, orange
γ = 67.80 (2)°0.58 × 0.29 × 0.14 mm
V = 833.1 (3) Å3
Data collection top
Diffractomètre CAD-43387 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tubeRint = 0.002
Graphite monochromatorθmax = 27.0°, θmin = 2.0°
ω/2θ scansh = 100
Absorption correction: ψ scan
(North et al., 1968)
k = 1312
Tmin = 0.392, Tmax = 0.676l = 1414
7758 measured reflections2 standard reflections every 120 min
3628 independent reflections intensity decay: 1%
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.030Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.093H atoms treated by a mixture of independent and constrained refinement
S = 1.16 w = 1/[σ2(Fo2) + (0.0537P)2 + 0.7843P]
where P = (Fo2 + 2Fc2)/3
3628 reflections(Δ/σ)max = 0.004
298 parametersΔρmax = 0.73 e Å3
27 restraintsΔρmin = 0.66 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
V30.03155 (5)0.20246 (4)0.76577 (4)0.01855 (12)
V50.19029 (4)0.49582 (4)0.51993 (3)0.01428 (11)
V10.02585 (5)0.50699 (4)0.25496 (4)0.01668 (11)
V20.12201 (5)0.21415 (4)0.50094 (4)0.01760 (11)
V40.32561 (5)0.21174 (4)0.72571 (4)0.01966 (12)
O140.1543 (2)0.11711 (19)0.40905 (18)0.0265 (4)
O130.0062 (2)0.4034 (2)0.16808 (17)0.0255 (4)
O110.1150 (2)0.0954 (2)0.86590 (18)0.0283 (4)
O120.5177 (2)0.1143 (2)0.79525 (19)0.0307 (4)
O70.0146 (2)0.12448 (18)0.63355 (16)0.0196 (3)
O90.2405 (2)0.36342 (18)0.64300 (15)0.0181 (3)
O60.2477 (2)0.63680 (18)0.20142 (16)0.0200 (3)
O80.3274 (2)0.13104 (18)0.59840 (16)0.0214 (3)
O100.3738 (2)0.62103 (18)0.42493 (16)0.0196 (3)
O50.0629 (2)0.35420 (18)0.83419 (15)0.0195 (3)
O40.1983 (2)0.11273 (18)0.82694 (16)0.0211 (3)
O20.1040 (2)0.37831 (17)0.41414 (15)0.0161 (3)
O30.1837 (2)0.61531 (17)0.61806 (15)0.0160 (3)
O10.06631 (18)0.37359 (17)0.60696 (15)0.0151 (3)
OW10.3151 (3)0.4887 (3)0.9863 (2)0.0353 (5)
H10.252 (4)0.438 (4)0.947 (3)0.042*
H20.261 (4)0.507 (4)1.031 (3)0.042*
OW20.4780 (3)0.4875 (3)0.2343 (2)0.0390 (5)
H30.559 (3)0.532 (4)0.268 (3)0.047*
H40.407 (4)0.527 (4)0.222 (4)0.047*
OW30.1814 (3)0.1963 (2)0.7628 (3)0.0423 (5)
H50.121 (4)0.103 (2)0.735 (4)0.051*
H60.114 (4)0.237 (3)0.760 (4)0.051*
OW40.4618 (3)0.8005 (3)0.7201 (2)0.0408 (5)
H70.503 (4)0.890 (2)0.681 (3)0.049*
H80.386 (4)0.752 (3)0.688 (3)0.049*
OW50.4213 (3)0.1985 (3)0.9710 (2)0.0405 (5)
H90.338 (4)0.118 (3)0.943 (3)0.049*
H100.408 (4)0.255 (3)1.040 (2)0.049*
N10.3241 (3)0.2048 (3)0.5094 (2)0.0289 (5)
H110.265 (4)0.113 (2)0.468 (3)0.035*
H120.389 (4)0.252 (3)0.467 (3)0.035*
H130.367 (4)0.201 (4)0.573 (2)0.035*
H140.245 (3)0.232 (4)0.537 (3)0.035*
N20.2246 (4)0.1773 (3)0.0729 (2)0.0344 (5)
H150.225 (5)0.095 (3)0.116 (3)0.041*
H160.164 (4)0.233 (4)0.106 (3)0.041*
H170.174 (4)0.221 (4)0.003 (2)0.041*
H180.318 (3)0.178 (4)0.073 (4)0.041*
Li10.4379 (6)0.3405 (5)0.8726 (4)0.0273 (9)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
V30.0207 (2)0.0161 (2)0.0179 (2)0.00739 (15)0.00407 (15)0.00536 (15)
V50.01371 (19)0.01311 (19)0.0165 (2)0.00430 (15)0.00384 (14)0.00729 (15)
V10.0209 (2)0.01531 (19)0.0149 (2)0.00545 (15)0.00336 (15)0.00870 (15)
V20.0222 (2)0.01204 (19)0.0186 (2)0.00405 (15)0.00439 (15)0.00874 (15)
V40.0169 (2)0.0162 (2)0.0210 (2)0.00284 (15)0.00000 (15)0.00517 (16)
O140.0346 (10)0.0180 (8)0.0287 (9)0.0069 (7)0.0063 (8)0.0146 (7)
O130.0344 (10)0.0255 (9)0.0224 (8)0.0111 (8)0.0063 (7)0.0161 (7)
O110.0333 (10)0.0253 (9)0.0259 (9)0.0162 (8)0.0075 (7)0.0049 (7)
O120.0218 (9)0.0259 (9)0.0354 (10)0.0016 (7)0.0042 (7)0.0086 (8)
O70.0239 (8)0.0137 (7)0.0214 (8)0.0072 (6)0.0037 (6)0.0070 (6)
O90.0183 (8)0.0173 (8)0.0194 (8)0.0072 (6)0.0048 (6)0.0076 (6)
O60.0215 (8)0.0184 (8)0.0194 (8)0.0063 (6)0.0005 (6)0.0074 (6)
O80.0204 (8)0.0145 (7)0.0250 (8)0.0011 (6)0.0029 (6)0.0087 (6)
O100.0154 (7)0.0189 (8)0.0226 (8)0.0041 (6)0.0020 (6)0.0085 (7)
O50.0240 (8)0.0186 (8)0.0159 (7)0.0078 (6)0.0057 (6)0.0073 (6)
O40.0230 (8)0.0162 (8)0.0190 (8)0.0048 (6)0.0008 (6)0.0037 (6)
O20.0175 (7)0.0144 (7)0.0181 (7)0.0061 (6)0.0031 (6)0.0082 (6)
O30.0171 (7)0.0140 (7)0.0168 (7)0.0038 (6)0.0047 (6)0.0081 (6)
O10.0169 (8)0.0128 (7)0.0161 (7)0.0047 (6)0.0040 (6)0.0076 (6)
OW10.0331 (11)0.0443 (12)0.0338 (11)0.0132 (10)0.0087 (9)0.0230 (10)
OW20.0328 (11)0.0545 (14)0.0522 (13)0.0233 (10)0.0210 (10)0.0401 (12)
OW30.0409 (12)0.0234 (10)0.0587 (15)0.0102 (9)0.0017 (11)0.0129 (10)
OW40.0397 (12)0.0358 (11)0.0462 (13)0.0139 (10)0.0227 (10)0.0178 (10)
OW50.0469 (13)0.0354 (12)0.0274 (10)0.0041 (10)0.0036 (9)0.0112 (9)
N10.0274 (12)0.0274 (11)0.0360 (13)0.0082 (9)0.0039 (10)0.0188 (10)
N20.0430 (14)0.0252 (12)0.0261 (12)0.0018 (11)0.0006 (11)0.0115 (10)
Li10.032 (2)0.024 (2)0.032 (2)0.0138 (18)0.0086 (18)0.0145 (18)
Geometric parameters (Å, º) top
V3—O111.6009 (18)O10—V4i2.0659 (18)
V3—O41.8601 (18)O5—V1i1.8127 (17)
V3—O71.8768 (17)O3—V2i2.0036 (17)
V3—O51.9012 (17)O3—V1i2.0048 (18)
V3—O92.0328 (18)O1—V5i2.1048 (16)
V3—O12.3609 (17)O1—V1i2.2333 (15)
V3—V43.0858 (9)OW1—Li1ii2.227 (5)
V3—V53.1010 (12)OW1—Li1iii2.270 (5)
V5—O101.6929 (17)OW1—H10.83 (4)
V5—O91.7072 (17)OW1—H20.81 (4)
V5—O21.9139 (16)OW2—Li1iv2.167 (5)
V5—O31.9341 (16)OW2—H30.83 (4)
V5—O1i2.1048 (16)OW2—H40.83 (4)
V5—O12.1317 (17)OW3—Li12.227 (5)
V5—V4i3.0785 (12)OW3—H50.838 (18)
V1—O131.6273 (17)OW3—H60.84 (4)
V1—O5i1.8127 (17)OW4—Li1ii2.163 (5)
V1—O61.8262 (18)OW4—H70.797 (17)
V1—O3i2.0048 (18)OW4—H80.809 (17)
V1—O22.0355 (17)OW5—Li12.084 (5)
V1—O1i2.2333 (15)OW5—H90.825 (17)
V1—V23.0899 (12)OW5—H100.805 (17)
V2—O141.6198 (17)N1—H110.834 (18)
V2—O81.8303 (18)N1—H120.843 (18)
V2—O71.8323 (17)N1—H130.826 (18)
V2—O3i2.0036 (17)N1—H140.828 (18)
V2—O22.0062 (18)N2—H150.801 (18)
V2—O12.2514 (15)N2—H160.80 (4)
V2—V43.1010 (9)N2—H170.791 (19)
V4—O121.6131 (19)N2—H180.799 (18)
V4—O41.8288 (18)Li1—OW4v2.163 (5)
V4—O81.8813 (17)Li1—OW2iv2.167 (5)
V4—O6i1.8992 (17)Li1—OW1v2.227 (5)
V4—O10i2.0659 (18)Li1—OW1iii2.270 (5)
V4—O12.3019 (18)Li1—Li1vi3.277 (9)
V4—V5i3.0785 (12)Li1—H102.30 (4)
O6—V4i1.8992 (17)
O11—V3—O4104.68 (9)O6i—V4—O10i82.92 (7)
O11—V3—O7102.27 (9)O12—V4—O1172.12 (8)
O4—V3—O790.92 (8)O4—V4—O182.93 (7)
O11—V3—O5103.28 (9)O8—V4—O178.63 (7)
O4—V3—O589.97 (8)O6i—V4—O177.29 (7)
O7—V3—O5153.32 (7)O10i—V4—O174.32 (6)
O11—V3—O9100.56 (9)O12—V4—V5i129.02 (8)
O4—V3—O9154.75 (7)O4—V4—V5i126.04 (6)
O7—V3—O984.30 (7)O8—V4—V5i79.23 (5)
O5—V3—O983.61 (7)O6i—V4—V5i78.39 (5)
O11—V3—O1174.67 (8)O10i—V4—V5i31.21 (5)
O4—V3—O180.65 (7)O1—V4—V5i43.12 (4)
O7—V3—O177.06 (6)O12—V4—V3138.48 (8)
O5—V3—O176.78 (6)O4—V4—V333.55 (5)
O9—V3—O174.11 (6)O8—V4—V385.13 (6)
O11—V3—V4137.57 (7)O6i—V4—V384.60 (5)
O4—V3—V432.91 (5)O10i—V4—V3123.71 (5)
O7—V3—V482.98 (6)O1—V4—V349.39 (4)
O5—V3—V483.38 (5)V5i—V4—V392.50 (3)
O9—V3—V4121.86 (5)O12—V4—V2134.03 (8)
O1—V3—V447.75 (4)O4—V4—V283.01 (6)
O11—V3—V5131.32 (7)O8—V4—V232.82 (5)
O4—V3—V5124.01 (6)O6i—V4—V2123.68 (6)
O7—V3—V578.63 (5)O10i—V4—V282.01 (5)
O5—V3—V578.83 (5)O1—V4—V246.40 (4)
O9—V3—V530.76 (5)V5i—V4—V261.75 (2)
O1—V3—V543.36 (4)V3—V4—V260.95 (2)
V4—V3—V591.10 (3)V2—O7—V3115.56 (8)
O10—V5—O9106.88 (9)V5—O9—V3111.73 (9)
O10—V5—O297.52 (8)V1—O6—V4i113.81 (9)
O9—V5—O297.11 (8)V2—O8—V4113.33 (8)
O10—V5—O397.18 (8)V5—O10—V4i109.57 (9)
O9—V5—O396.58 (7)V1i—O5—V3114.75 (8)
O2—V5—O3156.05 (7)V4—O4—V3113.55 (9)
O10—V5—O1i87.59 (8)V5—O2—V2108.09 (8)
O9—V5—O1i165.53 (7)V5—O2—V1107.06 (7)
O2—V5—O1i80.94 (6)V2—O2—V199.73 (7)
O3—V5—O1i80.90 (6)V5—O3—V2i107.27 (7)
O10—V5—O1166.11 (7)V5—O3—V1i107.03 (7)
O9—V5—O187.01 (7)V2i—O3—V1i100.86 (8)
O2—V5—O180.71 (7)V5i—O1—V5101.48 (7)
O3—V5—O180.48 (7)V5i—O1—V1i94.11 (6)
O1i—V5—O178.52 (7)V5—O1—V1i93.00 (6)
O10—V5—V4i39.22 (6)V5i—O1—V293.37 (6)
O9—V5—V4i146.09 (6)V5—O1—V292.74 (6)
O2—V5—V4i90.26 (5)V1i—O1—V2169.48 (8)
O3—V5—V4i89.27 (5)V5i—O1—V488.51 (6)
O1i—V5—V4i48.37 (5)V5—O1—V4169.98 (8)
O1—V5—V4i126.89 (5)V1i—O1—V486.97 (6)
O10—V5—V3144.39 (6)V2—O1—V485.84 (5)
O9—V5—V337.52 (6)V5i—O1—V3171.37 (8)
O2—V5—V389.23 (5)V5—O1—V387.14 (6)
O3—V5—V389.74 (5)V1i—O1—V385.78 (5)
O1i—V5—V3128.02 (5)V2—O1—V385.71 (5)
O1—V5—V349.50 (5)V4—O1—V382.86 (6)
V4i—V5—V3176.381 (15)Li1ii—OW1—Li1iii93.56 (17)
O13—V1—O5i103.37 (9)Li1ii—OW1—H1114 (2)
O13—V1—O6102.01 (9)Li1iii—OW1—H1107 (3)
O5i—V1—O695.24 (8)Li1ii—OW1—H2122 (2)
O13—V1—O3i99.89 (8)Li1iii—OW1—H2105 (3)
O5i—V1—O3i91.14 (8)H1—OW1—H2111 (3)
O6—V1—O3i155.07 (7)Li1iv—OW2—H3135 (2)
O13—V1—O298.96 (8)Li1iv—OW2—H4112 (2)
O5i—V1—O2155.80 (7)H3—OW2—H4111 (3)
O6—V1—O289.09 (8)Li1—OW3—H5135 (2)
O3i—V1—O275.80 (7)Li1—OW3—H6119 (2)
O13—V1—O1i173.77 (8)H5—OW3—H6104 (2)
O5i—V1—O1i81.93 (7)Li1ii—OW4—H7129 (3)
O6—V1—O1i80.54 (7)Li1ii—OW4—H8113 (2)
O3i—V1—O1i76.53 (6)H7—OW4—H8117 (3)
O2—V1—O1i75.31 (6)Li1—OW5—H9113 (3)
O13—V1—V289.27 (7)Li1—OW5—H1095 (3)
O5i—V1—V2130.69 (6)H9—OW5—H10111 (3)
O6—V1—V2128.88 (6)H11—N1—H12116 (3)
O3i—V1—V239.55 (5)H11—N1—H13102 (3)
O2—V1—V239.79 (5)H12—N1—H13118 (3)
O1i—V1—V284.76 (5)H11—N1—H1497 (3)
O14—V2—O8103.13 (9)H12—N1—H14115 (3)
O14—V2—O7103.93 (9)H13—N1—H14105 (3)
O8—V2—O794.83 (8)H15—N2—H16105 (4)
O14—V2—O3i98.63 (8)H15—N2—H17119 (4)
O8—V2—O3i89.92 (8)H16—N2—H1797 (4)
O7—V2—O3i155.20 (7)H15—N2—H18112 (4)
O14—V2—O299.17 (8)H16—N2—H18110 (4)
O8—V2—O2155.40 (7)H17—N2—H18112 (4)
O7—V2—O289.74 (8)OW5—Li1—OW4v86.62 (18)
O3i—V2—O276.49 (7)OW5—Li1—OW2iv174.7 (2)
O14—V2—O1173.25 (8)OW4v—Li1—OW2iv89.48 (18)
O8—V2—O181.00 (7)OW5—Li1—OW1v91.73 (19)
O7—V2—O180.84 (7)OW4v—Li1—OW1v97.86 (19)
O3i—V2—O175.88 (6)OW2iv—Li1—OW1v85.26 (17)
O2—V2—O175.88 (6)OW5—Li1—OW393.95 (18)
O14—V2—V188.49 (7)OW4v—Li1—OW387.76 (18)
O8—V2—V1129.50 (6)OW2iv—Li1—OW389.46 (18)
O7—V2—V1130.22 (6)OW1v—Li1—OW3172.2 (2)
O3i—V2—V139.58 (5)OW5—Li1—OW1iii98.44 (19)
O2—V2—V140.49 (5)OW4v—Li1—OW1iii173.3 (2)
O1—V2—V184.77 (5)OW2iv—Li1—OW1iii85.73 (17)
O14—V2—V4136.86 (7)OW1v—Li1—OW1iii86.44 (17)
O8—V2—V433.85 (5)OW3—Li1—OW1iii87.50 (17)
O7—V2—V483.20 (6)OW5—Li1—Li1vi97.0 (2)
O3i—V2—V487.40 (5)OW4v—Li1—Li1vi141.3 (3)
O2—V2—V4123.63 (5)OW2iv—Li1—Li1vi83.82 (18)
O1—V2—V447.76 (4)OW1v—Li1—Li1vi43.74 (12)
V1—V2—V4119.51 (2)OW3—Li1—Li1vi130.0 (2)
O12—V4—O4104.94 (9)OW1iii—Li1—Li1vi42.70 (11)
O12—V4—O8101.23 (9)OW5—Li1—H1020.4 (5)
O4—V4—O892.72 (8)OW4v—Li1—H10106.4 (6)
O12—V4—O6i101.66 (9)OW2iv—Li1—H10161.9 (6)
O4—V4—O6i91.28 (8)OW1v—Li1—H1084.1 (8)
O8—V4—O6i154.89 (7)OW3—Li1—H1099.5 (8)
O12—V4—O10i97.81 (9)OW1iii—Li1—H1079.1 (7)
O4—V4—O10i157.23 (7)Li1vi—Li1—H1078.4 (6)
O8—V4—O10i83.86 (7)
Symmetry codes: (i) x, y+1, z+1; (ii) x1, y+1, z; (iii) x, y, z+2; (iv) x, y, z+1; (v) x+1, y1, z; (vi) x+1, y1, z+2.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
OW1—H1···O50.83 (4)2.11 (2)2.912 (3)164 (3)
OW1—H2···O13vii0.81 (4)2.44 (3)3.130 (3)144 (3)
OW2—H3···O9viii0.83 (4)2.07 (2)2.895 (3)178 (4)
OW2—H4···O60.83 (4)2.03 (4)2.851 (3)174 (3)
OW3—H5···O70.84 (3)2.03 (2)2.851 (3)166 (4)
OW3—H6···O13iv0.84 (4)2.20 (2)2.985 (3)156 (3)
OW3—H6···O14iv0.84 (4)2.62 (3)3.187 (3)126 (3)
OW4—H7···O8ii0.80 (2)2.20 (2)2.975 (3)166 (3)
OW4—H8···O30.81 (2)2.10 (2)2.902 (3)176 (4)
OW5—H9···O40.83 (2)2.11 (2)2.890 (3)157 (3)
OW5—H10···OW2ix0.81 (2)2.59 (2)3.305 (4)150 (3)
N1—H11···O140.83 (2)2.04 (2)2.848 (3)163 (3)
N1—H12···O10v0.84 (2)2.08 (2)2.866 (3)154 (3)
N1—H12···O9iv0.84 (2)2.58 (3)3.009 (3)113 (3)
N1—H13···OW4v0.83 (2)2.26 (2)3.070 (3)167 (3)
N1—H13···OW30.83 (2)2.58 (3)3.028 (4)116 (3)
N1—H14···O2iv0.83 (2)2.17 (2)2.943 (3)156 (3)
N1—H14···O7iv0.83 (2)2.59 (3)3.040 (3)115 (3)
N2—H15···O12x0.80 (2)2.34 (3)2.841 (3)121 (3)
N2—H15···O11iv0.80 (2)2.41 (3)3.113 (3)146 (3)
N2—H16···O130.80 (3)2.09 (2)2.884 (3)172 (4)
N2—H17···O6xi0.79 (2)2.40 (3)2.986 (3)131 (3)
N2—H17···O5xii0.79 (2)2.42 (2)3.178 (3)160 (3)
N2—H17···O4xii0.79 (2)2.54 (3)3.076 (3)126 (3)
N2—H18···OW5x0.80 (2)2.32 (2)3.108 (4)169 (4)
Symmetry codes: (ii) x1, y+1, z; (iv) x, y, z+1; (v) x+1, y1, z; (vii) x, y, z+1; (viii) x1, y+1, z+1; (ix) x+1, y1, z+1; (x) x+1, y, z+1; (xi) x, y+1, z; (xii) x, y, z1.
 

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