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Acta Cryst. (2004). E60, o1419-o1420 [ doi:10.1107/S1600536804017490 ]
Abstract: The title compound, C10H10N6, was crystallized from a methylene dichloride solution. Tpm has gained much attention of late as a neutral scorpionate ligand analogue of hydrotris(pyrazol-1-yl)borate. We report here the structure of the free Tpm ligand, which shows a structure typical of a tripodal neutral ligand. The compound crystallizes in a chiral space group despite the fact that it is achiral, ideally C3v.
Online 31 July 2004
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