Acta Cryst. (2004). E60, m1043-m1045  [ doi:10.1107/S1600536804015533 ]

A mononuclear Rh^III tetraphosphine complex, [RhCl₂(C₂₅H₄₀P₄)]BF₄·C₃D₆O, crystallized as a perdeuteroacetone solvate

P. G. Gueorguieva, G. G. Stanley and F. R. Fronczek

Online 9 July 2004

Key indicators

• Single-crystal X-ray study
• T = 105 K
• Mean (C-C) = 0.004 Å
• R factor = 0.031
• wR factor = 0.071
• Data-to-parameter ratio = 23.4

checkCIF/PLATON results

No syntax errors found




Alert level C
PLAT031_ALERT_4_C Refined Extinction Parameter within Range ......       3.00 Sigma 
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Rh1    -   Cl2     ..       8.60 su    
PLAT244_ALERT_4_C Low Solvent  U(eq) as Compared to Neighbors ....        C1S     
PLAT244_ALERT_4_C Low Solvent  U(eq) as Compared to Neighbors ....         B1     

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   5 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   1 ALERT type 2 Indicator that the structure model may be wrong or deficient
   0 ALERT type 3 Indicator that the structure quality may be low
   3 ALERT type 4 Improvement, methodology, query or suggestion

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