Acta Cryst. (2004). E60, m1117-m1119  [ doi:10.1107/S1600536804016435 ]

Tris[bis(trimethylsilyl)amido]samarium tetrahydrofuran solvate

J. Sundermeyer, A. Khvorost and K. Harms

Abstract: The molecular structure of the title complex, [Sm{N(SiMe₃)₂}₃]·C₄H₈O, an important key compound in lanthanide chemistry, has been determined. The crystal structure analysis reveals a trigonal-pyramidal structure, isotype to other structurally characterized lanthanide tris-silylamides. The molecule is disordered due to the D₃ site symmetry.

Online 17 July 2004

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