Acta Cryst. (2004). E60, m1185-m1186  [ doi:10.1107/S1600536804018112 ]

Tris[-bis(diphenylphosphino)methane-²P:P']di-₃-chloro-trisilver(I) hexafluoroantimonate dichloromethane disolvate

M.-M. Wu and Y.-H. Qin

Abstract: The title ₃-Cl dicapped trisilver compound, [Ag₃Cl₂(C₂₅H₂₂P₂)₃][SbF₆]·2CH₂Cl₂, exhibits distorted trigonal bipyramidal coordination with two ₃-Cl atoms at the apices. The Ag^I atoms are four-coordinated and exhibit a tetrahedral geometry.

Online 31 July 2004

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