Acta Cryst. (2004). E60, m1185-m1186  [ doi:10.1107/S1600536804018112 ]

Tris[-bis(diphenylphosphino)methane-²P:P']di-₃-chloro-trisilver(I) hexafluoroantimonate dichloromethane disolvate

M.-M. Wu and Y.-H. Qin

Online 31 July 2004

Key indicators

• Single-crystal X-ray study
• T = 293 K
• Mean (C-C) = 0.017 Å
• R factor = 0.072
• wR factor = 0.171
• Data-to-parameter ratio = 16.1

checkCIF/PLATON results

No syntax errors found



Alert level A
PLAT029_ALERT_3_A _diffrn_measured_fraction_theta_full Low .......       0.93       

Alert level B
PLAT232_ALERT_2_B Hirshfeld Test Diff (M-X)  Ag1    -   Cl1     ..      11.14 su    
PLAT232_ALERT_2_B Hirshfeld Test Diff (M-X)  Ag2    -   Cl2     ..      10.23 su    

Alert level C
REFLT03_ALERT_3_C  Reflection count < 95% complete
           From the CIF: _diffrn_reflns_theta_max           25.60
           From the CIF: _diffrn_reflns_theta_full           0.00
           From the CIF: _reflns_number_total              14352
           TEST2: Reflns within _diffrn_reflns_theta_max
           Count of symmetry unique reflns        15504
           Completeness (_total/calc)             92.57%
SHFSU01_ALERT_2_C  The absolute value of parameter shift to su ratio > 0.05
            Absolute value of the parameter shift to su ratio given   0.094
            Additional refinement cycles may be required.
PLAT022_ALERT_3_C Ratio Unique / Expected Reflections too Low ....       0.93       
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT066_ALERT_1_C Predicted and Reported Transmissions Identical .          ?
PLAT080_ALERT_2_C Maximum Shift/Error ............................       0.09       
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.33 Ratio 
PLAT222_ALERT_3_C Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       3.32 Ratio 
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Ag1    -   Cl2     ..       7.03 su    
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Ag1    -   P1      ..       5.12 su    
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Ag2    -   Cl1     ..       9.25 su    
PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors  for       C113     
PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors  for       C415     
PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors  for       C515     
PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors  for       C511     
PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors  for       C514     
PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors  for       C611     
PLAT243_ALERT_4_C High Solvent U(eq) as Compared to Neighbors  for        C04     
PLAT244_ALERT_4_C Low  Solvent U(eq) as Compared to Neighbors  for        Sb1     
PLAT331_ALERT_2_C Small Average Phenyl C-C Dist.   C511   -C516          1.37 Ang.  
PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...         17       
PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........         15       
PLAT731_ALERT_1_C Bond    Calc   1.724(18), Rep    1.725(5) ......       3.60 su-Rat
              CL3  -C04     1.555   1.555                                       
PLAT731_ALERT_1_C Bond    Calc   1.712(17), Rep    1.713(5) ......       3.40 su-Rat
              CL4  -C04     1.555   1.555                                       
PLAT731_ALERT_1_C Bond    Calc     1.72(2), Rep    1.718(5) ......       4.00 su-Rat
              CL6  -C05     1.555   1.555                                       
PLAT731_ALERT_1_C Bond    Calc     1.72(2), Rep    1.721(5) ......       4.00 su-Rat
              CL5  -C05     1.555   1.555                                       
PLAT732_ALERT_1_C Angle   Calc   113.2(12), Rep    113.2(5) ......       2.40 su-Rat
              CL4  -C04  -CL3     1.555   1.555   1.555                         
PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd.  #          4       
              C H2 Cl2                                                          

   1 ALERT level A = In general: serious problem
   2 ALERT level B = Potentially serious problem
  28 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   7 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
  15 ALERT type 2 Indicator that the structure model may be wrong or deficient
   5 ALERT type 3 Indicator that the structure quality may be low
   4 ALERT type 4 Improvement, methodology, query or suggestion

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