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Acta Cryst. (2004). E60, m1063-m1065  [ doi:10.1107/S1600536804015910 ]

Tris(1H-benzimidazole-[kappa]N3)(iminodiacetato-[kappa]2O,O')manganese(II) dihydrate

J.-R. Su, K.-L. Yin and D.-J. Xu

Abstract: In the title compound, [Mn(C4H5NO4)(C7H6N2)3]·2H2O, the MnII atom is surrounded by one iminodiacetate dianion and three benzimidazole molecules in a distorted octahedral geometry. The tridentate iminodiacetate dianion chelates the MnII atom in the facial mode. Extensive intermolecular, N-H...O and O-H...O hydrogen bonding and C-H...[pi](arene) interactions are present in the crystal structure.

Online 9 July 2004


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