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Acta Cryst. (2004). E60, m1137-m1138  [ doi:10.1107/S1600536804017076 ]

[mu]-1,5-Dicyanamido-bis[chloro(1,4,7-triazacyclononane)copper(II)] perchlorate

Z.-D. Wang, W. Han, S.-P. Yan, D.-Z. Liao, Z.-H. Jiang and P. Cheng

Abstract: In the title compound, [Cu2(C2N3)Cl2(C6H15N3)2]ClO4, two [CuCl2(tacn)] units (tacn = 1,4,7-triazacyclononane) are linked by a single bridging dicyanamide ligand. The geometry about each CuII atom is deformed square-pyramidal or deformed trigonal-bipyramidal, formed by three N atoms of tacn, one of the terminal N atoms of the dicyanamide ligand and a Cl- anion.

Online 17 July 2004


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