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Acta Cryst. (2004). E60, m1281-m1283  [ doi:10.1107/S1600536804019725 ]

(Acetato-[kappa]O)[benzoylacetone (4-methoxybenzoyl)hydrazonato-[kappa]3O,N,O'](pyridine-[kappa]N)zinc(II)

L.-H. Huo, S. Gao, J.-W. Liu and H. Zhao

Abstract: The asymmetric unit of title complex, [Zn(C18H17N2O3)(C2H3O2)(C5H5N)], consists of two independent ZnII complex molecules, which are held together by N-H...O hydrogen bonds, forming a dimer. Each ZnII atom has a distorted trigonal-bipyramidal O3N2 configuration, defined by two O atoms and one N atom from the tridentate hydrazone ligand, one O atom from the acetate group and one N atom from pyridine molecule. The O atoms of the deprotonated hydrazone ligand occupy the axial sites.

Online 21 August 2004


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