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Acta Cryst. (2004). E60, m1223-m1224  [ doi:10.1107/S1600536804018987 ]

Di-[mu]-methoxo-bis[dipyridinecopper(II)] diperchlorate

J. Wang and M.-L. Tong

Abstract: The title compound, [Cu2(CH3O)2(C5H5N)4](ClO4)2, consists of a centrosymmetric dinuclear unit with bridging methoxo groups, and each CuII atom forms a square-planar CuN2O2 unit with pyridine ligands. The Cu...Cu distance is 2.9336 (11) Å and the Cu-O-Cu bond angle is 99.51 (7)°. The perchlorate anions are at semi-coordination distances, the Cu-O(perchlorate) distances being in the range 2.649 (2)-2.741 (2) Å.

Online 7 August 2004


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