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Acta Cryst. (2004). E60, m1444-m1446  [ doi:10.1107/S1600536804022780 ]

Bis(2-aminopyridine-[kappa]N1)silver(I) perchlorate

B. Deng, Z.-D. Liu, X.-Y. Liu, M.-Y. Tan and H.-L. Zhu

Abstract: The title compound, [Ag(C5H6N2)2]ClO4, is a mononuclear silver(I) complex. The Ag atom, lying on a twofold rotation axis, is bicoordinated in a distorted linear configuration by two N atoms from two symmetry-related 2-aminopyridine ligands. The perchlorate ion is disordered across a crystallographic mirror plane. The cations and anions are arranged as alternating layers along the a axis and are interlinked by weak N-H...O interactions in addition to the electrostatic interactions.

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