μ₂-Oxo-bis­[bis(η⁵-1,3-di-tert-butylcyclo­penta­dienyl)­titanium(III)]

The title compound, [Ti₂O(C₁₃H₂₁)₄] or {[(1,3-^tBu₂C₅H₃)₂Ti}₂(μ₂-O)}, crystallizes as a centrosymmetric mol­ecule, in which the two metallocene fragments are bridged by an O atom. The trigonal planar coordination around each metal consists of two 1,3-^tBu₂C₅H₃ ligands and the bridging O atom. The O atom is located on a crystallographic inversion center, resulting in a linear Ti—O—Ti linkage.

Key indicators

• Single-crystal X-ray study
• T = 164 K
• Mean [sigma](C-C) = 0.006 Å
• R factor = 0.065
• wR factor = 0.174
• Data-to-parameter ratio = 14.6

checkCIF/PLATON results

No syntax errors found



Alert level A
PLAT022_ALERT_3_A Ratio Unique / Expected Reflections too Low ....       0.85
PLAT027_ALERT_3_A _diffrn_reflns_theta_full (too) Low ............      23.01 Deg.

Alert level B
PLAT220_ALERT_2_B Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.67 Ratio
PLAT222_ALERT_3_B Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       4.65 Ratio

Alert level C
PLAT094_ALERT_2_C Ratio of Maximum / Minimum Residual Density ....       3.09
PLAT213_ALERT_2_C Atom C31     has ADP max/min Ratio .............       3.10 prolat
PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors  for        C29
PLAT601_ALERT_2_C Structure Contains Solvent Accessible VOIDS of .      34.00 A   3  

   2 ALERT level A = In general: serious problem
   2 ALERT level B = Potentially serious problem
   4 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   5 ALERT type 2 Indicator that the structure model may be wrong or deficient
   3 ALERT type 3 Indicator that the structure quality may be low
   0 ALERT type 4 Improvement, methodology, query or suggestion

---

Computing details

Data collection: SMART (Bruker, 1999); cell refinement: SAINT (Bruker, 2002); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: SHELXL97.

µ₂-Oxo-di[bis(η⁵-1,3-di(tert-butyl)cyclopentadienyl)titanium(III)]

Crystal data

[Ti2O(C13H21)4]	Z = 2
Mr = 820.93	F(000) = 896
Triclinic, P1	Dx = 1.135 Mg m^−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 10.6900 (8) Å	Cell parameters from 2932 reflections
b = 11.7225 (8) Å	θ = 2–25°
c = 20.2272 (13) Å	µ = 0.37 mm^−1
α = 90.196 (2)°	T = 164 K
β = 101.945 (2)°	Needle, red-brown
γ = 103.992 (2)°	0.30 × 0.25 × 0.10 mm
V = 2402.5 (3) Å^3

Data collection

Bruker SMART CCD area-detector diffractometer	7637 independent reflections
Radiation source: fine-focus sealed tube	4690 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.046
ω scans	θmax = 25.6°, θmin = 2.0°
Absorption correction: multi-scan (Blessing, 1995)	h = −12→12
Tmin = 0.898, Tmax = 0.964	k = −14→12
10782 measured reflections	l = −20→24

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.065	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.174	H-atom parameters constrained
S = 0.99	w = 1/[σ^2(Fo^2) + (0.0907P)^2] where P = (Fo^2 + 2Fc^2)/3
7637 reflections	(Δ/σ)max = 0.001
523 parameters	Δρmax = 1.24 e Å^−3
0 restraints	Δρmin = −0.40 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Ti1	0.02541 (7)	0.60861 (7)	0.57296 (4)	0.0191 (2)
Ti2	−0.03979 (8)	0.88961 (7)	0.06426 (4)	0.0209 (2)
O1	0.0000	0.5000	0.5000	0.0225 (10)
O2	0.0000	1.0000	0.0000	0.0247 (10)
C1	0.1907 (4)	0.7800 (4)	0.5472 (2)	0.0212 (10)
C2	0.0777 (4)	0.7627 (4)	0.4939 (2)	0.0196 (10)
H2	0.0744	0.7398	0.4484	0.023*
C3	−0.0302 (4)	0.7843 (4)	0.5185 (2)	0.0204 (10)
C4	0.0178 (4)	0.8113 (4)	0.5883 (2)	0.0230 (10)
H4	−0.0324	0.8288	0.6188	0.028*
C5	0.1506 (4)	0.8086 (4)	0.6061 (2)	0.0248 (11)
H5	0.2046	0.8234	0.6504	0.030*
C6	0.1121 (4)	0.5534 (4)	0.6897 (2)	0.0209 (10)
C7	0.0159 (4)	0.6147 (4)	0.6961 (2)	0.0230 (11)
H7	0.0328	0.6876	0.7211	0.028*
C8	−0.1113 (4)	0.5496 (4)	0.6591 (2)	0.0210 (10)
C9	−0.0898 (4)	0.4500 (4)	0.6290 (2)	0.0222 (10)
H9	−0.1559	0.3906	0.6008	0.027*
C10	0.0443 (4)	0.4520 (4)	0.6470 (2)	0.0226 (10)
H10	0.0837	0.3943	0.6328	0.027*
C11	0.0296 (4)	0.7169 (4)	0.0267 (2)	0.0224 (10)
C12	−0.0668 (4)	0.7408 (4)	−0.0267 (2)	0.0233 (11)
H12	−0.0513	0.7655	−0.0696	0.028*
C13	−0.1902 (4)	0.7227 (4)	−0.0073 (2)	0.0220 (10)
C14	−0.1675 (4)	0.6891 (4)	0.0599 (2)	0.0244 (11)
H14	−0.2322	0.6710	0.0867	0.029*
C15	−0.0345 (4)	0.6863 (4)	0.0814 (2)	0.0248 (11)
H15	0.0055	0.6673	0.1251	0.030*
C16	0.0665 (4)	0.9405 (4)	0.1871 (2)	0.0248 (11)
C17	−0.0641 (4)	0.8776 (4)	0.1857 (2)	0.0239 (11)
H17	−0.0880	0.8031	0.2043	0.029*
C18	−0.1548 (4)	0.9394 (4)	0.1531 (2)	0.0249 (11)
C19	−0.0776 (4)	1.0421 (4)	0.1312 (2)	0.0239 (11)
H19	−0.1108	1.1014	0.1067	0.029*
C20	0.0563 (4)	1.0420 (4)	0.1517 (2)	0.0238 (11)
H20	0.1284	1.1011	0.1431	0.029*
C21	0.3328 (4)	0.7839 (4)	0.5398 (2)	0.0223 (10)
C22	0.3568 (5)	0.6609 (4)	0.5395 (3)	0.0344 (12)
H22A	0.2948	0.6122	0.5015	0.052*
H22B	0.3438	0.6252	0.5820	0.052*
H22C	0.4474	0.6664	0.5347	0.052*
C23	0.4318 (5)	0.8617 (5)	0.5976 (3)	0.0474 (15)
H23A	0.5217	0.8670	0.5917	0.071*
H23B	0.4212	0.8273	0.6409	0.071*
H23C	0.4160	0.9406	0.5975	0.071*
C24	0.3548 (5)	0.8394 (4)	0.4733 (2)	0.0332 (12)
H24A	0.4443	0.8413	0.4681	0.050*
H24B	0.3435	0.9199	0.4741	0.050*
H24C	0.2905	0.7927	0.4353	0.050*
C25	−0.1632 (4)	0.7941 (4)	0.4752 (2)	0.0235 (11)
C26	−0.1441 (5)	0.8395 (4)	0.4060 (2)	0.0332 (12)
H26A	−0.0786	0.9155	0.4125	0.050*
H26B	−0.2282	0.8492	0.3795	0.050*
H26C	−0.1131	0.7828	0.3819	0.050*
C27	−0.2156 (5)	0.8844 (5)	0.5097 (3)	0.0374 (13)
H27A	−0.2316	0.8572	0.5536	0.056*
H27B	−0.2984	0.8932	0.4810	0.056*
H27C	−0.1504	0.9606	0.5163	0.056*
C28	−0.2646 (4)	0.6750 (4)	0.4647 (2)	0.0315 (12)
H28A	−0.2319	0.6183	0.4417	0.047*
H28B	−0.3481	0.6840	0.4371	0.047*
H28C	−0.2788	0.6466	0.5088	0.047*
C29	0.2457 (4)	0.5687 (4)	0.7395 (2)	0.0274 (11)
C30	0.3399 (5)	0.5133 (7)	0.7112 (3)	0.067 (2)
H30A	0.3626	0.5551	0.6717	0.101*
H30B	0.2974	0.4304	0.6976	0.101*
H30C	0.4203	0.5189	0.7459	0.101*
C31	0.3092 (6)	0.6965 (5)	0.7626 (3)	0.072 (2)
H31A	0.3829	0.7010	0.8013	0.107*
H31B	0.2438	0.7325	0.7760	0.107*
H31C	0.3421	0.7388	0.7255	0.107*
C32	0.2148 (5)	0.5018 (5)	0.8014 (2)	0.0382 (13)
H32A	0.2961	0.5119	0.8362	0.057*
H32B	0.1781	0.4179	0.7881	0.057*
H32C	0.1506	0.5327	0.8194	0.057*
C33	−0.2430 (4)	0.5627 (4)	0.6731 (2)	0.0261 (11)
C34	−0.3604 (4)	0.4898 (5)	0.6216 (3)	0.0359 (13)
H34A	−0.4426	0.4989	0.6327	0.054*
H34B	−0.3585	0.4067	0.6228	0.054*
H34C	−0.3555	0.5170	0.5762	0.054*
C35	−0.2512 (5)	0.6908 (4)	0.6765 (3)	0.0390 (13)
H35A	−0.1741	0.7372	0.7089	0.059*
H35B	−0.3319	0.6950	0.6912	0.059*
H35C	−0.2528	0.7225	0.6317	0.059*
C36	−0.2509 (5)	0.5120 (5)	0.7430 (2)	0.0363 (13)
H36A	−0.1786	0.5591	0.7777	0.054*
H36B	−0.2435	0.4303	0.7420	0.054*
H36C	−0.3356	0.5144	0.7537	0.054*
C37	0.1690 (4)	0.7080 (4)	0.0219 (2)	0.0230 (11)
C38	0.2137 (5)	0.6198 (5)	0.0711 (3)	0.0468 (15)
H38A	0.2128	0.6447	0.1172	0.070*
H38B	0.3033	0.6164	0.0686	0.070*
H38C	0.1535	0.5417	0.0589	0.070*
C39	0.2666 (5)	0.8275 (4)	0.0360 (3)	0.0353 (13)
H39A	0.2325	0.8846	0.0069	0.053*
H39B	0.3513	0.8218	0.0266	0.053*
H39C	0.2791	0.8533	0.0835	0.053*
C40	0.1641 (5)	0.6619 (4)	−0.0499 (2)	0.0358 (13)
H40A	0.0961	0.5877	−0.0610	0.054*
H40B	0.2500	0.6485	−0.0524	0.054*
H40C	0.1430	0.7200	−0.0823	0.054*
C41	−0.3234 (4)	0.7196 (4)	−0.0540 (2)	0.0259 (11)
C42	−0.4341 (5)	0.6335 (5)	−0.0290 (3)	0.0494 (15)
H42A	−0.4132	0.5567	−0.0237	0.074*
H42B	−0.5175	0.6249	−0.0620	0.074*
H42C	−0.4425	0.6638	0.0147	0.074*
C43	−0.3514 (5)	0.8412 (4)	−0.0591 (3)	0.0373 (13)
H43A	−0.3620	0.8679	−0.0151	0.056*
H43B	−0.4327	0.8369	−0.0931	0.056*
H43C	−0.2777	0.8968	−0.0725	0.056*
C44	−0.3230 (5)	0.6717 (4)	−0.1248 (2)	0.0344 (12)
H44A	−0.2567	0.7266	−0.1439	0.052*
H44B	−0.4104	0.6630	−0.1542	0.052*
H44C	−0.3017	0.5948	−0.1213	0.052*
C45	0.1884 (4)	0.9231 (4)	0.2373 (2)	0.0270 (11)
C46	0.3162 (5)	1.0015 (5)	0.2214 (3)	0.0440 (14)
H46A	0.3927	0.9896	0.2542	0.066*
H46B	0.3136	1.0844	0.2243	0.066*
H46C	0.3231	0.9803	0.1756	0.066*
C47	0.1987 (6)	0.7965 (5)	0.2399 (3)	0.0508 (16)
H47A	0.1198	0.7473	0.2524	0.076*
H47B	0.2772	0.7916	0.2737	0.076*
H47C	0.2057	0.7686	0.1954	0.076*
C48	0.1778 (5)	0.9668 (5)	0.3072 (2)	0.0415 (14)
H48A	0.1036	0.9134	0.3215	0.062*
H48B	0.1633	1.0462	0.3045	0.062*
H48C	0.2597	0.9685	0.3401	0.062*
C49	−0.2970 (5)	0.9234 (4)	0.1630 (2)	0.0305 (12)
C50	−0.3718 (5)	0.9960 (5)	0.1153 (3)	0.0401 (13)
H50A	−0.3228	1.0789	0.1213	0.060*
H50B	−0.4593	0.9884	0.1253	0.060*
H50C	−0.3817	0.9675	0.0684	0.060*
C51	−0.3760 (5)	0.7964 (5)	0.1557 (3)	0.0533 (17)
H51A	−0.3899	0.7660	0.1089	0.080*
H51B	−0.4616	0.7916	0.1674	0.080*
H51C	−0.3276	0.7493	0.1862	0.080*
C52	−0.2795 (6)	0.9731 (5)	0.2358 (3)	0.0477 (15)
H52A	−0.2328	0.9266	0.2676	0.072*
H52B	−0.3663	0.9689	0.2458	0.072*
H52C	−0.2282	1.0553	0.2404	0.072*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ti1	0.0182 (5)	0.0220 (5)	0.0194 (5)	0.0077 (4)	0.0061 (3)	−0.0002 (3)
Ti2	0.0201 (5)	0.0221 (5)	0.0228 (5)	0.0076 (4)	0.0071 (3)	0.0018 (4)
O1	0.023 (2)	0.025 (2)	0.019 (2)	0.003 (2)	0.0077 (18)	−0.0016 (19)
O2	0.028 (3)	0.022 (2)	0.026 (2)	0.008 (2)	0.0071 (19)	−0.0019 (19)
C1	0.025 (3)	0.017 (2)	0.023 (3)	0.007 (2)	0.005 (2)	0.0027 (19)
C2	0.019 (2)	0.015 (2)	0.025 (2)	0.0044 (19)	0.0047 (19)	−0.0016 (19)
C3	0.020 (2)	0.014 (2)	0.029 (3)	0.0067 (19)	0.006 (2)	−0.002 (2)
C4	0.023 (3)	0.024 (3)	0.028 (3)	0.015 (2)	0.008 (2)	0.001 (2)
C5	0.027 (3)	0.022 (3)	0.022 (3)	0.004 (2)	0.000 (2)	−0.002 (2)
C6	0.015 (2)	0.032 (3)	0.017 (2)	0.007 (2)	0.0049 (18)	0.003 (2)
C7	0.022 (3)	0.030 (3)	0.019 (2)	0.008 (2)	0.008 (2)	−0.003 (2)
C8	0.023 (3)	0.022 (2)	0.019 (2)	0.007 (2)	0.0078 (19)	0.0039 (19)
C9	0.022 (3)	0.019 (2)	0.027 (3)	0.004 (2)	0.010 (2)	0.001 (2)
C10	0.024 (3)	0.026 (3)	0.024 (3)	0.016 (2)	0.007 (2)	0.002 (2)
C11	0.020 (2)	0.019 (2)	0.029 (3)	0.004 (2)	0.008 (2)	−0.001 (2)
C12	0.024 (3)	0.024 (3)	0.023 (3)	0.006 (2)	0.008 (2)	0.003 (2)
C13	0.015 (2)	0.025 (3)	0.029 (3)	0.007 (2)	0.007 (2)	0.000 (2)
C14	0.020 (3)	0.024 (3)	0.032 (3)	0.007 (2)	0.011 (2)	0.004 (2)
C15	0.030 (3)	0.022 (3)	0.021 (2)	0.007 (2)	0.003 (2)	0.001 (2)
C16	0.026 (3)	0.026 (3)	0.023 (3)	0.011 (2)	0.002 (2)	−0.003 (2)
C17	0.029 (3)	0.023 (3)	0.025 (3)	0.010 (2)	0.013 (2)	0.002 (2)
C18	0.033 (3)	0.023 (3)	0.022 (3)	0.010 (2)	0.009 (2)	−0.001 (2)
C19	0.026 (3)	0.024 (3)	0.027 (3)	0.013 (2)	0.009 (2)	0.003 (2)
C20	0.026 (3)	0.021 (3)	0.024 (3)	0.004 (2)	0.010 (2)	0.000 (2)
C21	0.017 (2)	0.027 (3)	0.023 (3)	0.005 (2)	0.0051 (19)	0.003 (2)
C22	0.029 (3)	0.040 (3)	0.041 (3)	0.017 (2)	0.013 (2)	0.011 (2)
C23	0.027 (3)	0.063 (4)	0.049 (4)	0.006 (3)	0.008 (3)	−0.009 (3)
C24	0.025 (3)	0.037 (3)	0.043 (3)	0.013 (2)	0.013 (2)	0.010 (2)
C25	0.022 (3)	0.026 (3)	0.028 (3)	0.014 (2)	0.007 (2)	0.001 (2)
C26	0.028 (3)	0.040 (3)	0.038 (3)	0.020 (2)	0.005 (2)	0.006 (2)
C27	0.031 (3)	0.045 (3)	0.043 (3)	0.027 (3)	0.006 (2)	−0.002 (3)
C28	0.023 (3)	0.035 (3)	0.036 (3)	0.007 (2)	0.003 (2)	0.004 (2)
C29	0.024 (3)	0.035 (3)	0.025 (3)	0.013 (2)	0.003 (2)	0.007 (2)
C30	0.036 (3)	0.150 (7)	0.031 (3)	0.053 (4)	0.005 (3)	0.009 (4)
C31	0.040 (4)	0.048 (4)	0.094 (5)	−0.006 (3)	−0.039 (4)	0.022 (4)
C32	0.037 (3)	0.050 (3)	0.029 (3)	0.017 (3)	0.004 (2)	0.005 (3)
C33	0.026 (3)	0.027 (3)	0.034 (3)	0.015 (2)	0.014 (2)	0.002 (2)
C34	0.025 (3)	0.044 (3)	0.044 (3)	0.012 (2)	0.014 (2)	0.002 (3)
C35	0.031 (3)	0.039 (3)	0.057 (4)	0.017 (3)	0.022 (3)	0.004 (3)
C36	0.036 (3)	0.044 (3)	0.038 (3)	0.016 (3)	0.021 (2)	0.002 (3)
C37	0.017 (2)	0.028 (3)	0.028 (3)	0.012 (2)	0.005 (2)	0.000 (2)
C38	0.043 (3)	0.054 (4)	0.055 (4)	0.028 (3)	0.017 (3)	0.015 (3)
C39	0.026 (3)	0.039 (3)	0.043 (3)	0.010 (2)	0.010 (2)	−0.005 (2)
C40	0.025 (3)	0.042 (3)	0.045 (3)	0.014 (2)	0.010 (2)	−0.007 (3)
C41	0.018 (3)	0.030 (3)	0.029 (3)	0.005 (2)	0.005 (2)	0.001 (2)
C42	0.028 (3)	0.063 (4)	0.053 (4)	0.006 (3)	0.006 (3)	0.008 (3)
C43	0.032 (3)	0.042 (3)	0.042 (3)	0.021 (3)	0.003 (2)	−0.004 (3)
C44	0.024 (3)	0.035 (3)	0.040 (3)	0.008 (2)	−0.003 (2)	−0.007 (2)
C45	0.027 (3)	0.029 (3)	0.025 (3)	0.009 (2)	0.002 (2)	0.000 (2)
C46	0.022 (3)	0.070 (4)	0.036 (3)	0.011 (3)	−0.003 (2)	−0.001 (3)
C47	0.050 (4)	0.046 (4)	0.051 (4)	0.024 (3)	−0.017 (3)	−0.003 (3)
C48	0.045 (3)	0.050 (4)	0.032 (3)	0.020 (3)	0.004 (2)	0.001 (3)
C49	0.030 (3)	0.036 (3)	0.032 (3)	0.016 (2)	0.013 (2)	0.002 (2)
C50	0.029 (3)	0.057 (4)	0.041 (3)	0.019 (3)	0.012 (2)	0.003 (3)
C51	0.034 (3)	0.043 (4)	0.092 (5)	0.008 (3)	0.037 (3)	0.001 (3)
C52	0.052 (4)	0.072 (4)	0.035 (3)	0.033 (3)	0.022 (3)	0.009 (3)

Geometric parameters (Å, º)

Ti1—C1	2.470 (4)	C25—C27	1.539 (6)
Ti1—C2	2.456 (4)	C26—H26A	0.9800
Ti1—C3	2.479 (4)	C26—H26B	0.9800
Ti1—C4	2.418 (4)	C26—H26C	0.9800
Ti1—C5	2.416 (4)	C27—H27A	0.9800
Ti1—C6	2.499 (4)	C27—H27B	0.9800
Ti1—C7	2.516 (4)	C27—H27C	0.9800
Ti1—C8	2.495 (4)	C28—H28A	0.9800
Ti1—C9	2.396 (4)	C28—H28B	0.9800
Ti1—C10	2.393 (4)	C28—H28C	0.9800
Ti1—Cg1	2.134	C29—C31	1.515 (7)
Ti1—Cg2	2.146	C29—C30	1.522 (7)
Ti1—O1	1.8780 (8)	C29—C32	1.531 (6)
Ti2—C11	2.485 (4)	C30—H30A	0.9800
Ti2—C12	2.455 (4)	C30—H30B	0.9800
Ti2—C13	2.450 (4)	C30—H30C	0.9800
Ti2—C14	2.407 (4)	C31—H31A	0.9800
Ti2—C15	2.421 (4)	C31—H31B	0.9800
Ti2—C16	2.514 (4)	C31—H31C	0.9800
Ti2—C17	2.523 (4)	C32—H32A	0.9800
Ti2—C18	2.516 (4)	C32—H32B	0.9800
Ti2—C19	2.398 (4)	C32—H32C	0.9800
Ti2—C20	2.391 (4)	C33—C34	1.525 (6)
Ti2—Cg3	2.159	C33—C35	1.527 (6)
Ti2—Cg4	2.128	C33—C36	1.546 (6)
Ti2—O2	1.8760 (8)	C34—H34A	0.9800
O1—Ti1^i	1.8780 (8)	C34—H34B	0.9800
O2—Ti2^ii	1.8760 (8)	C34—H34C	0.9800
C1—C5	1.412 (6)	C35—H35A	0.9800
C1—C2	1.416 (6)	C35—H35B	0.9800
C1—C21	1.546 (6)	C35—H35C	0.9800
C2—C3	1.420 (6)	C36—H36A	0.9800
C2—H2	0.9500	C36—H36B	0.9800
C3—C4	1.406 (6)	C36—H36C	0.9800
C3—C25	1.538 (6)	C37—C39	1.517 (6)
C4—C5	1.398 (6)	C37—C38	1.529 (6)
C4—H4	0.9500	C37—C40	1.534 (6)
C5—H5	0.9500	C38—H38A	0.9800
C6—C10	1.414 (6)	C38—H38B	0.9800
C6—C7	1.416 (6)	C38—H38C	0.9800
C6—C29	1.538 (6)	C39—H39A	0.9800
C7—C8	1.437 (6)	C39—H39B	0.9800
C7—H7	0.9500	C39—H39C	0.9800
C8—C9	1.403 (6)	C40—H40A	0.9800
C8—C33	1.535 (6)	C40—H40B	0.9800
C9—C10	1.398 (6)	C40—H40C	0.9800
C9—H9	0.9500	C41—C43	1.525 (6)
C10—H10	0.9500	C41—C42	1.533 (7)
C11—C12	1.411 (6)	C41—C44	1.538 (6)
C11—C15	1.421 (6)	C42—H42A	0.9800
C11—C37	1.542 (6)	C42—H42B	0.9800
C12—C13	1.421 (6)	C42—H42C	0.9800
C12—H12	0.9500	C43—H43A	0.9800
C13—C14	1.406 (6)	C43—H43B	0.9800
C13—C41	1.529 (6)	C43—H43C	0.9800
C14—C15	1.406 (6)	C44—H44A	0.9800
C14—H14	0.9500	C44—H44B	0.9800
C15—H15	0.9500	C44—H44C	0.9800
C16—C20	1.407 (6)	C45—C47	1.515 (7)
C16—C17	1.407 (6)	C45—C48	1.538 (6)
C16—C45	1.533 (6)	C45—C46	1.546 (7)
C17—C18	1.406 (6)	C46—H46A	0.9800
C17—H17	0.9500	C46—H46B	0.9800
C18—C19	1.415 (6)	C46—H46C	0.9800
C18—C49	1.542 (6)	C47—H47A	0.9800
C19—C20	1.406 (6)	C47—H47B	0.9800
C19—H19	0.9500	C47—H47C	0.9800
C20—H20	0.9500	C48—H48A	0.9800
C21—C22	1.524 (6)	C48—H48B	0.9800
C21—C23	1.528 (6)	C48—H48C	0.9800
C21—C24	1.533 (6)	C49—C51	1.514 (7)
C22—H22A	0.9800	C49—C50	1.520 (6)
C22—H22B	0.9800	C49—C52	1.539 (7)
C22—H22C	0.9800	C50—H50A	0.9800
C23—H23A	0.9800	C50—H50B	0.9800
C23—H23B	0.9800	C50—H50C	0.9800
C23—H23C	0.9800	C51—H51A	0.9800
C24—H24A	0.9800	C51—H51B	0.9800
C24—H24B	0.9800	C51—H51C	0.9800
C24—H24C	0.9800	C52—H52A	0.9800
C25—C28	1.529 (6)	C52—H52B	0.9800
C25—C26	1.535 (6)	C52—H52C	0.9800
O1—Ti1—C10	87.99 (11)	C18—C17—H17	124.5
O1—Ti1—C9	87.32 (11)	C16—C17—H17	124.5
C10—Ti1—C9	33.96 (14)	Ti2—C17—H17	120.2
O1—Ti1—C5	136.85 (11)	C17—C18—C19	105.5 (4)
C10—Ti1—C5	121.27 (15)	C17—C18—C49	125.5 (4)
C9—Ti1—C5	135.01 (15)	C19—C18—C49	125.4 (4)
O1—Ti1—C4	137.03 (11)	C17—C18—Ti2	74.1 (3)
C10—Ti1—C4	134.64 (15)	C19—C18—Ti2	68.8 (2)
C9—Ti1—C4	123.58 (15)	C49—C18—Ti2	138.3 (3)
C5—Ti1—C4	33.63 (14)	C20—C19—C18	108.7 (4)
O1—Ti1—C2	86.49 (10)	C20—C19—Ti2	72.7 (2)
C10—Ti1—C2	161.17 (14)	C18—C19—Ti2	77.9 (3)
C9—Ti1—C2	162.88 (15)	C20—C19—H19	125.7
C5—Ti1—C2	55.24 (14)	C18—C19—H19	125.7
C4—Ti1—C2	54.90 (15)	Ti2—C19—H19	115.8
O1—Ti1—C1	103.39 (10)	C19—C20—C16	109.1 (4)
C10—Ti1—C1	132.11 (15)	C19—C20—Ti2	73.2 (2)
C9—Ti1—C1	163.22 (15)	C16—C20—Ti2	78.2 (3)
C5—Ti1—C1	33.57 (14)	C19—C20—H20	125.5
C4—Ti1—C1	55.62 (15)	C16—C20—H20	125.5
C2—Ti1—C1	33.41 (13)	Ti2—C20—H20	115.2
O1—Ti1—C3	103.91 (10)	C22—C21—C23	109.9 (4)
C10—Ti1—C3	164.03 (15)	C22—C21—C24	109.0 (4)
C9—Ti1—C3	134.41 (15)	C23—C21—C24	107.7 (4)
C5—Ti1—C3	55.92 (14)	C22—C21—C1	111.4 (4)
C4—Ti1—C3	33.33 (14)	C23—C21—C1	109.6 (4)
C2—Ti1—C3	33.44 (13)	C24—C21—C1	109.2 (3)
C1—Ti1—C3	56.05 (14)	C21—C22—H22A	109.5
O1—Ti1—C8	117.09 (11)	C21—C22—H22B	109.5
C10—Ti1—C8	55.72 (14)	H22A—C22—H22B	109.5
C9—Ti1—C8	33.27 (14)	C21—C22—H22C	109.5
C5—Ti1—C8	105.89 (15)	H22A—C22—H22C	109.5
C4—Ti1—C8	90.48 (15)	H22B—C22—H22C	109.5
C2—Ti1—C8	141.86 (14)	C21—C23—H23A	109.5
C1—Ti1—C8	139.46 (14)	C21—C23—H23B	109.5
C3—Ti1—C8	108.69 (14)	H23A—C23—H23B	109.5
O1—Ti1—C6	118.59 (11)	C21—C23—H23C	109.5
C10—Ti1—C6	33.52 (14)	H23A—C23—H23C	109.5
C9—Ti1—C6	55.83 (14)	H23B—C23—H23C	109.5
C5—Ti1—C6	88.20 (15)	C21—C24—H24A	109.5
C4—Ti1—C6	104.04 (15)	C21—C24—H24B	109.5
C2—Ti1—C6	140.37 (14)	H24A—C24—H24B	109.5
C1—Ti1—C6	107.40 (14)	C21—C24—H24C	109.5
C3—Ti1—C6	137.37 (14)	H24A—C24—H24C	109.5
C8—Ti1—C6	55.62 (14)	H24B—C24—H24C	109.5
O1—Ti1—C7	140.52 (11)	C28—C25—C26	109.2 (4)
C10—Ti1—C7	54.78 (15)	C28—C25—C27	109.7 (4)
C9—Ti1—C7	54.90 (15)	C26—C25—C27	107.1 (4)
C5—Ti1—C7	80.15 (15)	C28—C25—C3	111.3 (4)
C4—Ti1—C7	80.19 (15)	C26—C25—C3	109.8 (4)
C2—Ti1—C7	132.99 (15)	C27—C25—C3	109.6 (4)
C1—Ti1—C7	111.28 (14)	C25—C26—H26A	109.5
C3—Ti1—C7	110.77 (15)	C25—C26—H26B	109.5
C8—Ti1—C7	33.33 (14)	H26A—C26—H26B	109.5
C6—Ti1—C7	32.80 (13)	C25—C26—H26C	109.5
O2—Ti2—C20	89.17 (11)	H26A—C26—H26C	109.5
O2—Ti2—C19	88.74 (11)	H26B—C26—H26C	109.5
C20—Ti2—C19	34.14 (15)	C25—C27—H27A	109.5
O2—Ti2—C14	135.27 (11)	C25—C27—H27B	109.5
C20—Ti2—C14	134.75 (16)	H27A—C27—H27B	109.5
C19—Ti2—C14	121.58 (16)	C25—C27—H27C	109.5
O2—Ti2—C15	136.80 (11)	H27A—C27—H27C	109.5
C20—Ti2—C15	122.37 (15)	H27B—C27—H27C	109.5
C19—Ti2—C15	134.18 (16)	C25—C28—H28A	109.5
C14—Ti2—C15	33.86 (14)	C25—C28—H28B	109.5
O2—Ti2—C13	101.75 (11)	H28A—C28—H28B	109.5
C20—Ti2—C13	163.29 (15)	C25—C28—H28C	109.5
C19—Ti2—C13	132.33 (15)	H28A—C28—H28C	109.5
C14—Ti2—C13	33.63 (14)	H28B—C28—H28C	109.5
C15—Ti2—C13	56.31 (15)	C31—C29—C30	111.1 (5)
O2—Ti2—C12	85.44 (11)	C31—C29—C32	107.9 (4)
C20—Ti2—C12	162.30 (15)	C30—C29—C32	107.5 (4)
C19—Ti2—C12	161.78 (15)	C31—C29—C6	112.1 (4)
C14—Ti2—C12	55.16 (15)	C30—C29—C6	112.2 (4)
C15—Ti2—C12	55.26 (15)	C32—C29—C6	105.7 (4)
C13—Ti2—C12	33.67 (14)	C29—C30—H30A	109.5
O2—Ti2—C11	103.42 (11)	C29—C30—H30B	109.5
C20—Ti2—C11	133.76 (15)	H30A—C30—H30B	109.5
C19—Ti2—C11	163.81 (15)	C29—C30—H30C	109.5
C14—Ti2—C11	55.83 (15)	H30A—C30—H30C	109.5
C15—Ti2—C11	33.64 (15)	H30B—C30—H30C	109.5
C13—Ti2—C11	56.21 (14)	C29—C31—H31A	109.5
C12—Ti2—C11	33.17 (14)	C29—C31—H31B	109.5
O2—Ti2—C16	119.39 (11)	H31A—C31—H31B	109.5
C20—Ti2—C16	33.21 (14)	C29—C31—H31C	109.5
C19—Ti2—C16	55.55 (15)	H31A—C31—H31C	109.5
C14—Ti2—C16	105.20 (15)	H31B—C31—H31C	109.5
C15—Ti2—C16	89.42 (15)	C29—C32—H32A	109.5
C13—Ti2—C16	138.82 (15)	C29—C32—H32B	109.5
C12—Ti2—C16	141.38 (15)	H32A—C32—H32B	109.5
C11—Ti2—C16	108.54 (14)	C29—C32—H32C	109.5
O2—Ti2—C18	118.77 (11)	H32A—C32—H32C	109.5
C20—Ti2—C18	55.62 (15)	H32B—C32—H32C	109.5
C19—Ti2—C18	33.35 (15)	C34—C33—C35	110.2 (4)
C14—Ti2—C18	88.66 (15)	C34—C33—C8	111.7 (4)
C15—Ti2—C18	103.96 (15)	C35—C33—C8	112.9 (4)
C13—Ti2—C18	107.73 (15)	C34—C33—C36	107.4 (4)
C12—Ti2—C18	140.89 (15)	C35—C33—C36	108.5 (4)
C11—Ti2—C18	137.60 (15)	C8—C33—C36	105.8 (4)
C16—Ti2—C18	54.93 (14)	C33—C34—H34A	109.5
O2—Ti2—C17	141.16 (11)	C33—C34—H34B	109.5
C20—Ti2—C17	54.17 (15)	H34A—C34—H34B	109.5
C19—Ti2—C17	54.21 (15)	C33—C34—H34C	109.5
C14—Ti2—C17	80.67 (15)	H34A—C34—H34C	109.5
C15—Ti2—C17	80.22 (15)	H34B—C34—H34C	109.5
C13—Ti2—C17	111.68 (15)	C33—C35—H35A	109.5
C12—Ti2—C17	133.39 (15)	C33—C35—H35B	109.5
C11—Ti2—C17	111.26 (15)	H35A—C35—H35B	109.5
C16—Ti2—C17	32.44 (14)	C33—C35—H35C	109.5
C18—Ti2—C17	32.41 (14)	H35A—C35—H35C	109.5
Ti1—O1—Ti1^i	180.0	H35B—C35—H35C	109.5
Ti2—O2—Ti2^ii	180.0	C33—C36—H36A	109.5
Cg1—Ti1—Cg2	132.43	C33—C36—H36B	109.5
Cg3—Ti2—Cg4	132.23	H36A—C36—H36B	109.5
C5—C1—C2	106.0 (4)	C33—C36—H36C	109.5
C5—C1—C21	127.2 (4)	H36A—C36—H36C	109.5
C2—C1—C21	126.2 (4)	H36B—C36—H36C	109.5
C5—C1—Ti1	71.1 (2)	C39—C37—C38	110.6 (4)
C2—C1—Ti1	72.7 (2)	C39—C37—C40	108.8 (4)
C21—C1—Ti1	127.3 (3)	C38—C37—C40	107.7 (4)
C1—C2—C3	110.2 (4)	C39—C37—C11	110.9 (4)
C1—C2—Ti1	73.9 (3)	C38—C37—C11	110.0 (4)
C3—C2—Ti1	74.2 (2)	C40—C37—C11	108.8 (3)
C1—C2—H2	124.9	C37—C38—H38A	109.5
C3—C2—H2	124.9	C37—C38—H38B	109.5
Ti1—C2—H2	118.7	H38A—C38—H38B	109.5
C4—C3—C2	105.3 (4)	C37—C38—H38C	109.5
C4—C3—C25	127.8 (4)	H38A—C38—H38C	109.5
C2—C3—C25	126.2 (4)	H38B—C38—H38C	109.5
C4—C3—Ti1	70.9 (2)	C37—C39—H39A	109.5
C2—C3—Ti1	72.4 (2)	C37—C39—H39B	109.5
C25—C3—Ti1	128.0 (3)	H39A—C39—H39B	109.5
C5—C4—C3	109.9 (4)	C37—C39—H39C	109.5
C5—C4—Ti1	73.1 (2)	H39A—C39—H39C	109.5
C3—C4—Ti1	75.7 (2)	H39B—C39—H39C	109.5
C5—C4—H4	125.0	C37—C40—H40A	109.5
C3—C4—H4	125.0	C37—C40—H40B	109.5
Ti1—C4—H4	117.9	H40A—C40—H40B	109.5
C4—C5—C1	108.5 (4)	C37—C40—H40C	109.5
C4—C5—Ti1	73.3 (2)	H40A—C40—H40C	109.5
C1—C5—Ti1	75.3 (2)	H40B—C40—H40C	109.5
C4—C5—H5	125.7	C43—C41—C13	112.1 (4)
C1—C5—H5	125.7	C43—C41—C42	110.0 (4)
Ti1—C5—H5	117.6	C13—C41—C42	110.0 (4)
C10—C6—C7	106.0 (4)	C43—C41—C44	109.4 (4)
C10—C6—C29	125.6 (4)	C13—C41—C44	108.6 (4)
C7—C6—C29	124.6 (4)	C42—C41—C44	106.6 (4)
C10—C6—Ti1	69.1 (2)	C41—C42—H42A	109.5
C7—C6—Ti1	74.3 (2)	C41—C42—H42B	109.5
C29—C6—Ti1	138.5 (3)	H42A—C42—H42B	109.5
C6—C7—C8	109.5 (4)	C41—C42—H42C	109.5
C6—C7—Ti1	72.9 (2)	H42A—C42—H42C	109.5
C8—C7—Ti1	72.5 (2)	H42B—C42—H42C	109.5
C6—C7—H7	125.3	C41—C43—H43A	109.5
C8—C7—H7	125.3	C41—C43—H43B	109.5
Ti1—C7—H7	120.9	H43A—C43—H43B	109.5
C9—C8—C7	105.9 (4)	C41—C43—H43C	109.5
C9—C8—C33	126.2 (4)	H43A—C43—H43C	109.5
C7—C8—C33	124.1 (4)	H43B—C43—H43C	109.5
C9—C8—Ti1	69.5 (2)	C41—C44—H44A	109.5
C7—C8—Ti1	74.1 (2)	C41—C44—H44B	109.5
C33—C8—Ti1	138.3 (3)	H44A—C44—H44B	109.5
C10—C9—C8	109.4 (4)	C41—C44—H44C	109.5
C10—C9—Ti1	72.9 (3)	H44A—C44—H44C	109.5
C8—C9—Ti1	77.2 (3)	H44B—C44—H44C	109.5
C10—C9—H9	125.3	C47—C45—C16	113.9 (4)
C8—C9—H9	125.3	C47—C45—C48	109.4 (4)
Ti1—C9—H9	116.4	C16—C45—C48	106.2 (4)
C9—C10—C6	109.2 (4)	C47—C45—C46	109.3 (4)
C9—C10—Ti1	73.1 (2)	C16—C45—C46	110.8 (4)
C6—C10—Ti1	77.4 (3)	C48—C45—C46	107.0 (4)
C9—C10—H10	125.4	C45—C46—H46A	109.5
C6—C10—H10	125.4	C45—C46—H46B	109.5
Ti1—C10—H10	116.1	H46A—C46—H46B	109.5
C12—C11—C15	106.0 (4)	C45—C46—H46C	109.5
C12—C11—C37	125.8 (4)	H46A—C46—H46C	109.5
C15—C11—C37	127.6 (4)	H46B—C46—H46C	109.5
C12—C11—Ti2	72.3 (2)	C45—C47—H47A	109.5
C15—C11—Ti2	70.7 (2)	C45—C47—H47B	109.5
C37—C11—Ti2	128.5 (3)	H47A—C47—H47B	109.5
C11—C12—C13	110.4 (4)	C45—C47—H47C	109.5
C11—C12—Ti2	74.6 (3)	H47A—C47—H47C	109.5
C13—C12—Ti2	73.0 (3)	H47B—C47—H47C	109.5
C11—C12—H12	124.8	C45—C48—H48A	109.5
C13—C12—H12	124.8	C45—C48—H48B	109.5
Ti2—C12—H12	119.3	H48A—C48—H48B	109.5
C14—C13—C12	105.6 (4)	C45—C48—H48C	109.5
C14—C13—C41	127.2 (4)	H48A—C48—H48C	109.5
C12—C13—C41	126.4 (4)	H48B—C48—H48C	109.5
C14—C13—Ti2	71.5 (2)	C51—C49—C50	109.3 (4)
C12—C13—Ti2	73.4 (2)	C51—C49—C52	109.7 (5)
C41—C13—Ti2	127.7 (3)	C50—C49—C52	108.0 (4)
C15—C14—C13	109.7 (4)	C51—C49—C18	113.6 (4)
C15—C14—Ti2	73.6 (3)	C50—C49—C18	111.7 (4)
C13—C14—Ti2	74.9 (3)	C52—C49—C18	104.2 (4)
C15—C14—H14	125.2	C49—C50—H50A	109.5
C13—C14—H14	125.2	C49—C50—H50B	109.5
Ti2—C14—H14	118.1	H50A—C50—H50B	109.5
C14—C15—C11	108.2 (4)	C49—C50—H50C	109.5
C14—C15—Ti2	72.5 (3)	H50A—C50—H50C	109.5
C11—C15—Ti2	75.6 (3)	H50B—C50—H50C	109.5
C14—C15—H15	125.9	C49—C51—H51A	109.5
C11—C15—H15	125.9	C49—C51—H51B	109.5
Ti2—C15—H15	117.9	H51A—C51—H51B	109.5
C20—C16—C17	105.6 (4)	C49—C51—H51C	109.5
C20—C16—C45	126.4 (4)	H51A—C51—H51C	109.5
C17—C16—C45	124.9 (4)	H51B—C51—H51C	109.5
C20—C16—Ti2	68.6 (2)	C49—C52—H52A	109.5
C17—C16—Ti2	74.2 (2)	C49—C52—H52B	109.5
C45—C16—Ti2	137.4 (3)	H52A—C52—H52B	109.5
C18—C17—C16	111.1 (4)	C49—C52—H52C	109.5
C18—C17—Ti2	73.5 (2)	H52A—C52—H52C	109.5
C16—C17—Ti2	73.4 (3)	H52B—C52—H52C	109.5
O1—Ti1—C1—C5	175.9 (2)	C14—Ti2—C12—C11	−79.3 (3)
C10—Ti1—C1—C5	−84.5 (3)	C15—Ti2—C12—C11	−37.7 (3)
C9—Ti1—C1—C5	−55.5 (6)	C13—Ti2—C12—C11	−117.6 (4)
C4—Ti1—C1—C5	37.5 (2)	C16—Ti2—C12—C11	−10.3 (4)
C2—Ti1—C1—C5	114.3 (4)	C18—Ti2—C12—C11	−104.9 (3)
C3—Ti1—C1—C5	78.0 (3)	C17—Ti2—C12—C11	−57.7 (3)
C8—Ti1—C1—C5	−0.8 (4)	O2—Ti2—C12—C13	−119.2 (2)
C6—Ti1—C1—C5	−57.9 (3)	C20—Ti2—C12—C13	168.1 (4)
C7—Ti1—C1—C5	−23.3 (3)	C19—Ti2—C12—C13	−47.5 (6)
O1—Ti1—C1—C2	61.6 (2)	C14—Ti2—C12—C13	38.3 (2)
C10—Ti1—C1—C2	161.2 (2)	C15—Ti2—C12—C13	79.8 (3)
C9—Ti1—C1—C2	−169.8 (5)	C11—Ti2—C12—C13	117.6 (4)
C5—Ti1—C1—C2	−114.3 (4)	C16—Ti2—C12—C13	107.2 (3)
C4—Ti1—C1—C2	−76.8 (3)	C18—Ti2—C12—C13	12.6 (4)
C3—Ti1—C1—C2	−36.3 (2)	C17—Ti2—C12—C13	59.9 (3)
C8—Ti1—C1—C2	−115.2 (3)	C11—C12—C13—C14	1.0 (5)
C6—Ti1—C1—C2	−172.2 (2)	Ti2—C12—C13—C14	−64.7 (3)
C7—Ti1—C1—C2	−137.6 (2)	C11—C12—C13—C41	−169.3 (4)
O1—Ti1—C1—C21	−61.1 (3)	Ti2—C12—C13—C41	125.0 (4)
C10—Ti1—C1—C21	38.4 (4)	C11—C12—C13—Ti2	65.7 (3)
C9—Ti1—C1—C21	67.4 (7)	O2—Ti2—C13—C14	176.0 (2)
C5—Ti1—C1—C21	122.9 (5)	C20—Ti2—C13—C14	−54.1 (6)
C4—Ti1—C1—C21	160.4 (4)	C19—Ti2—C13—C14	−84.8 (3)
C2—Ti1—C1—C21	−122.8 (5)	C15—Ti2—C13—C14	36.9 (2)
C3—Ti1—C1—C21	−159.1 (4)	C12—Ti2—C13—C14	113.3 (4)
C8—Ti1—C1—C21	122.1 (3)	C11—Ti2—C13—C14	77.6 (3)
C6—Ti1—C1—C21	65.0 (4)	C16—Ti2—C13—C14	−1.8 (4)
C7—Ti1—C1—C21	99.6 (3)	C18—Ti2—C13—C14	−58.3 (3)
C5—C1—C2—C3	2.1 (5)	C17—Ti2—C13—C14	−24.1 (3)
C21—C1—C2—C3	−170.1 (4)	O2—Ti2—C13—C12	62.7 (3)
Ti1—C1—C2—C3	65.9 (3)	C20—Ti2—C13—C12	−167.4 (5)
C5—C1—C2—Ti1	−63.8 (3)	C19—Ti2—C13—C12	161.8 (3)
C21—C1—C2—Ti1	124.0 (4)	C14—Ti2—C13—C12	−113.3 (4)
O1—Ti1—C2—C1	−120.9 (2)	C15—Ti2—C13—C12	−76.4 (3)
C10—Ti1—C2—C1	−47.7 (6)	C11—Ti2—C13—C12	−35.7 (2)
C9—Ti1—C2—C1	170.0 (4)	C16—Ti2—C13—C12	−115.1 (3)
C5—Ti1—C2—C1	37.8 (2)	C18—Ti2—C13—C12	−171.7 (2)
C4—Ti1—C2—C1	79.2 (3)	C17—Ti2—C13—C12	−137.4 (3)
C3—Ti1—C2—C1	117.1 (4)	O2—Ti2—C13—C41	−60.8 (4)
C8—Ti1—C2—C1	107.7 (3)	C20—Ti2—C13—C41	69.1 (7)
C6—Ti1—C2—C1	11.7 (4)	C19—Ti2—C13—C41	38.4 (5)
C7—Ti1—C2—C1	59.2 (3)	C14—Ti2—C13—C41	123.2 (5)
O1—Ti1—C2—C3	122.0 (2)	C15—Ti2—C13—C41	160.1 (4)
C10—Ti1—C2—C3	−164.8 (4)	C12—Ti2—C13—C41	−123.5 (5)
C9—Ti1—C2—C3	53.0 (6)	C11—Ti2—C13—C41	−159.2 (4)
C5—Ti1—C2—C3	−79.2 (3)	C16—Ti2—C13—C41	121.4 (4)
C4—Ti1—C2—C3	−37.9 (2)	C18—Ti2—C13—C41	64.8 (4)
C1—Ti1—C2—C3	−117.1 (4)	C17—Ti2—C13—C41	99.1 (4)
C8—Ti1—C2—C3	−9.4 (4)	C12—C13—C14—C15	0.0 (5)
C6—Ti1—C2—C3	−105.3 (3)	C41—C13—C14—C15	170.2 (4)
C7—Ti1—C2—C3	−57.9 (3)	Ti2—C13—C14—C15	−66.0 (3)
C1—C2—C3—C4	−1.9 (5)	C12—C13—C14—Ti2	66.0 (3)
Ti1—C2—C3—C4	63.7 (3)	C41—C13—C14—Ti2	−123.8 (4)
C1—C2—C3—C25	169.8 (4)	O2—Ti2—C14—C15	110.8 (2)
Ti1—C2—C3—C25	−124.5 (4)	C20—Ti2—C14—C15	−82.8 (3)
C1—C2—C3—Ti1	−65.7 (3)	C19—Ti2—C14—C15	−123.5 (3)
O1—Ti1—C3—C4	−174.5 (2)	C13—Ti2—C14—C15	116.3 (4)
C10—Ti1—C3—C4	48.3 (6)	C12—Ti2—C14—C15	78.0 (3)
C9—Ti1—C3—C4	85.4 (3)	C11—Ti2—C14—C15	37.4 (2)
C5—Ti1—C3—C4	−36.8 (3)	C16—Ti2—C14—C15	−64.9 (3)
C2—Ti1—C3—C4	−113.8 (4)	C18—Ti2—C14—C15	−117.9 (3)
C1—Ti1—C3—C4	−77.6 (3)	C17—Ti2—C14—C15	−86.3 (3)
C8—Ti1—C3—C4	60.1 (3)	O2—Ti2—C14—C13	−5.5 (3)
C6—Ti1—C3—C4	1.0 (3)	C20—Ti2—C14—C13	160.9 (2)
C7—Ti1—C3—C4	24.7 (3)	C19—Ti2—C14—C13	120.2 (3)
O1—Ti1—C3—C2	−60.7 (2)	C15—Ti2—C14—C13	−116.3 (4)
C10—Ti1—C3—C2	162.1 (5)	C12—Ti2—C14—C13	−38.3 (2)
C9—Ti1—C3—C2	−160.8 (2)	C11—Ti2—C14—C13	−78.9 (3)
C5—Ti1—C3—C2	77.0 (3)	C16—Ti2—C14—C13	178.8 (2)
C4—Ti1—C3—C2	113.8 (4)	C18—Ti2—C14—C13	125.8 (3)
C1—Ti1—C3—C2	36.2 (2)	C17—Ti2—C14—C13	157.4 (3)
C8—Ti1—C3—C2	173.9 (2)	C13—C14—C15—C11	−1.0 (5)
C6—Ti1—C3—C2	114.8 (3)	Ti2—C14—C15—C11	−67.8 (3)
C7—Ti1—C3—C2	138.5 (2)	C13—C14—C15—Ti2	66.8 (3)
O1—Ti1—C3—C25	61.9 (4)	C12—C11—C15—C14	1.6 (5)
C10—Ti1—C3—C25	−75.3 (7)	C37—C11—C15—C14	−170.0 (4)
C9—Ti1—C3—C25	−38.2 (4)	Ti2—C11—C15—C14	65.7 (3)
C5—Ti1—C3—C25	−160.4 (4)	C12—C11—C15—Ti2	−64.1 (3)
C4—Ti1—C3—C25	−123.6 (5)	C37—C11—C15—Ti2	124.3 (4)
C2—Ti1—C3—C25	122.6 (5)	O2—Ti2—C15—C14	−106.0 (3)
C1—Ti1—C3—C25	158.8 (4)	C20—Ti2—C15—C14	123.5 (3)
C8—Ti1—C3—C25	−63.5 (4)	C19—Ti2—C15—C14	82.1 (3)
C6—Ti1—C3—C25	−122.6 (3)	C13—Ti2—C15—C14	−36.6 (2)
C7—Ti1—C3—C25	−98.9 (4)	C12—Ti2—C15—C14	−77.6 (3)
C2—C3—C4—C5	1.0 (5)	C11—Ti2—C15—C14	−114.8 (4)
C25—C3—C4—C5	−170.5 (4)	C16—Ti2—C15—C14	119.1 (3)
Ti1—C3—C4—C5	65.7 (3)	C18—Ti2—C15—C14	65.6 (3)
C2—C3—C4—Ti1	−64.7 (3)	C17—Ti2—C15—C14	87.8 (3)
C25—C3—C4—Ti1	123.8 (4)	O2—Ti2—C15—C11	8.8 (3)
O1—Ti1—C4—C5	−108.6 (3)	C20—Ti2—C15—C11	−121.7 (3)
C10—Ti1—C4—C5	80.4 (3)	C19—Ti2—C15—C11	−163.1 (2)
C9—Ti1—C4—C5	122.3 (3)	C14—Ti2—C15—C11	114.8 (4)
C2—Ti1—C4—C5	−78.4 (3)	C13—Ti2—C15—C11	78.2 (3)
C1—Ti1—C4—C5	−37.4 (2)	C12—Ti2—C15—C11	37.2 (2)
C3—Ti1—C4—C5	−116.4 (4)	C16—Ti2—C15—C11	−126.1 (3)
C8—Ti1—C4—C5	118.8 (3)	C18—Ti2—C15—C11	−179.6 (3)
C6—Ti1—C4—C5	64.3 (3)	C17—Ti2—C15—C11	−157.4 (3)
C7—Ti1—C4—C5	86.9 (3)	O2—Ti2—C16—C20	27.0 (3)
O1—Ti1—C4—C3	7.8 (3)	C19—Ti2—C16—C20	−38.3 (3)
C10—Ti1—C4—C3	−163.2 (2)	C14—Ti2—C16—C20	−156.5 (3)
C9—Ti1—C4—C3	−121.3 (3)	C15—Ti2—C16—C20	173.2 (3)
C5—Ti1—C4—C3	116.4 (4)	C13—Ti2—C16—C20	−155.5 (3)
C2—Ti1—C4—C3	38.0 (2)	C12—Ti2—C16—C20	151.0 (3)
C1—Ti1—C4—C3	79.0 (3)	C11—Ti2—C16—C20	145.0 (3)
C8—Ti1—C4—C3	−124.8 (3)	C18—Ti2—C16—C20	−79.2 (3)
C6—Ti1—C4—C3	−179.3 (2)	C17—Ti2—C16—C20	−114.3 (4)
C7—Ti1—C4—C3	−156.6 (3)	O2—Ti2—C16—C17	141.3 (2)
C3—C4—C5—C1	0.3 (5)	C20—Ti2—C16—C17	114.3 (4)
Ti1—C4—C5—C1	67.7 (3)	C19—Ti2—C16—C17	75.9 (3)
C3—C4—C5—Ti1	−67.4 (3)	C14—Ti2—C16—C17	−42.2 (3)
C2—C1—C5—C4	−1.5 (5)	C15—Ti2—C16—C17	−72.5 (3)
C21—C1—C5—C4	170.6 (4)	C13—Ti2—C16—C17	−41.2 (3)
Ti1—C1—C5—C4	−66.3 (3)	C12—Ti2—C16—C17	−94.7 (3)
C2—C1—C5—Ti1	64.9 (3)	C11—Ti2—C16—C17	−100.7 (3)
C21—C1—C5—Ti1	−123.0 (4)	C18—Ti2—C16—C17	35.1 (2)
O1—Ti1—C5—C4	109.1 (3)	O2—Ti2—C16—C45	−94.0 (5)
C10—Ti1—C5—C4	−124.8 (3)	C20—Ti2—C16—C45	−121.0 (6)
C9—Ti1—C5—C4	−84.8 (3)	C19—Ti2—C16—C45	−159.3 (5)
C2—Ti1—C5—C4	77.3 (3)	C14—Ti2—C16—C45	82.5 (5)
C1—Ti1—C5—C4	114.9 (4)	C15—Ti2—C16—C45	52.2 (5)
C3—Ti1—C5—C4	36.4 (2)	C13—Ti2—C16—C45	83.5 (5)
C8—Ti1—C5—C4	−65.7 (3)	C12—Ti2—C16—C45	30.0 (6)
C6—Ti1—C5—C4	−119.0 (3)	C11—Ti2—C16—C45	24.0 (5)
C7—Ti1—C5—C4	−87.1 (3)	C18—Ti2—C16—C45	159.8 (5)
O1—Ti1—C5—C1	−5.8 (3)	C17—Ti2—C16—C45	124.7 (6)
C10—Ti1—C5—C1	120.2 (3)	C20—C16—C17—C18	−2.6 (5)
C9—Ti1—C5—C1	160.3 (2)	C45—C16—C17—C18	158.3 (4)
C4—Ti1—C5—C1	−114.9 (4)	Ti2—C16—C17—C18	−64.4 (3)
C2—Ti1—C5—C1	−37.6 (2)	C20—C16—C17—Ti2	61.8 (3)
C3—Ti1—C5—C1	−78.5 (3)	C45—C16—C17—Ti2	−137.3 (4)
C8—Ti1—C5—C1	179.4 (2)	O2—Ti2—C17—C18	58.4 (3)
C6—Ti1—C5—C1	126.0 (3)	C20—Ti2—C17—C18	80.7 (3)
C7—Ti1—C5—C1	158.0 (3)	C19—Ti2—C17—C18	38.2 (3)
O1—Ti1—C6—C10	−26.5 (3)	C14—Ti2—C17—C18	−102.4 (3)
C9—Ti1—C6—C10	37.8 (2)	C15—Ti2—C17—C18	−136.7 (3)
C5—Ti1—C6—C10	−171.0 (3)	C13—Ti2—C17—C18	−89.1 (3)
C4—Ti1—C6—C10	159.1 (2)	C12—Ti2—C17—C18	−120.2 (3)
C2—Ti1—C6—C10	−149.8 (3)	C11—Ti2—C17—C18	−150.0 (3)
C1—Ti1—C6—C10	−143.1 (2)	C16—Ti2—C17—C18	118.7 (4)
C3—Ti1—C6—C10	158.5 (2)	O2—Ti2—C17—C16	−60.3 (3)
C8—Ti1—C6—C10	78.3 (3)	C20—Ti2—C17—C16	−38.0 (2)
C7—Ti1—C6—C10	114.5 (4)	C19—Ti2—C17—C16	−80.5 (3)
O1—Ti1—C6—C7	−141.0 (2)	C14—Ti2—C17—C16	138.9 (3)
C10—Ti1—C6—C7	−114.5 (4)	C15—Ti2—C17—C16	104.6 (3)
C9—Ti1—C6—C7	−76.7 (3)	C13—Ti2—C17—C16	152.2 (2)
C5—Ti1—C6—C7	74.5 (3)	C12—Ti2—C17—C16	121.1 (3)
C4—Ti1—C6—C7	44.6 (3)	C11—Ti2—C17—C16	91.4 (3)
C2—Ti1—C6—C7	95.7 (3)	C18—Ti2—C17—C16	−118.7 (4)
C1—Ti1—C6—C7	102.4 (3)	C16—C17—C18—C19	2.3 (5)
C3—Ti1—C6—C7	44.0 (3)	Ti2—C17—C18—C19	−62.0 (3)
C8—Ti1—C6—C7	−36.2 (3)	C16—C17—C18—C49	−157.0 (4)
O1—Ti1—C6—C29	94.1 (5)	Ti2—C17—C18—C49	138.6 (4)
C10—Ti1—C6—C29	120.6 (6)	C16—C17—C18—Ti2	64.3 (3)
C9—Ti1—C6—C29	158.3 (5)	O2—Ti2—C18—C17	−142.5 (2)
C5—Ti1—C6—C29	−50.4 (5)	C20—Ti2—C18—C17	−75.8 (3)
C4—Ti1—C6—C29	−80.4 (5)	C19—Ti2—C18—C17	−114.1 (4)
C2—Ti1—C6—C29	−29.2 (6)	C14—Ti2—C18—C17	74.6 (3)
C1—Ti1—C6—C29	−22.5 (5)	C15—Ti2—C18—C17	44.1 (3)
C3—Ti1—C6—C29	−80.9 (5)	C13—Ti2—C18—C17	102.7 (3)
C8—Ti1—C6—C29	−161.1 (5)	C12—Ti2—C18—C17	95.4 (3)
C7—Ti1—C6—C29	−124.9 (6)	C11—Ti2—C18—C17	43.8 (4)
C10—C6—C7—C8	1.6 (5)	C16—Ti2—C18—C17	−35.1 (2)
C29—C6—C7—C8	−157.5 (4)	O2—Ti2—C18—C19	−28.4 (3)
Ti1—C6—C7—C8	63.8 (3)	C20—Ti2—C18—C19	38.3 (3)
C10—C6—C7—Ti1	−62.2 (3)	C14—Ti2—C18—C19	−171.3 (3)
C29—C6—C7—Ti1	138.7 (4)	C15—Ti2—C18—C19	158.2 (3)
O1—Ti1—C7—C6	60.4 (3)	C13—Ti2—C18—C19	−143.2 (3)
C10—Ti1—C7—C6	38.0 (3)	C12—Ti2—C18—C19	−150.5 (3)
C9—Ti1—C7—C6	79.8 (3)	C11—Ti2—C18—C19	157.9 (3)
C5—Ti1—C7—C6	−102.2 (3)	C16—Ti2—C18—C19	79.0 (3)
C4—Ti1—C7—C6	−136.3 (3)	C17—Ti2—C18—C19	114.1 (4)
C2—Ti1—C7—C6	−119.8 (3)	O2—Ti2—C18—C49	91.5 (5)
C1—Ti1—C7—C6	−89.3 (3)	C20—Ti2—C18—C49	158.2 (5)
C3—Ti1—C7—C6	−149.8 (3)	C19—Ti2—C18—C49	119.9 (6)
C8—Ti1—C7—C6	117.5 (4)	C14—Ti2—C18—C49	−51.4 (5)
O1—Ti1—C7—C8	−57.2 (3)	C15—Ti2—C18—C49	−81.9 (5)
C10—Ti1—C7—C8	−79.6 (3)	C13—Ti2—C18—C49	−23.3 (5)
C9—Ti1—C7—C8	−37.7 (2)	C12—Ti2—C18—C49	−30.6 (6)
C5—Ti1—C7—C8	140.3 (3)	C11—Ti2—C18—C49	−82.2 (5)
C4—Ti1—C7—C8	106.2 (3)	C16—Ti2—C18—C49	−161.1 (5)
C2—Ti1—C7—C8	122.6 (3)	C17—Ti2—C18—C49	−126.0 (6)
C1—Ti1—C7—C8	153.1 (2)	C17—C18—C19—C20	−1.2 (5)
C3—Ti1—C7—C8	92.7 (3)	C49—C18—C19—C20	158.3 (4)
C6—Ti1—C7—C8	−117.5 (4)	Ti2—C18—C19—C20	−66.8 (3)
C6—C7—C8—C9	−1.4 (5)	C17—C18—C19—Ti2	65.6 (3)
Ti1—C7—C8—C9	62.7 (3)	C49—C18—C19—Ti2	−135.0 (4)
C6—C7—C8—C33	157.8 (4)	O2—Ti2—C19—C20	−90.4 (3)
Ti1—C7—C8—C33	−138.1 (4)	C14—Ti2—C19—C20	124.5 (3)
C6—C7—C8—Ti1	−64.1 (3)	C15—Ti2—C19—C20	84.1 (3)
O1—Ti1—C8—C9	28.9 (3)	C13—Ti2—C19—C20	164.8 (3)
C10—Ti1—C8—C9	−37.7 (3)	C12—Ti2—C19—C20	−161.6 (4)
C5—Ti1—C8—C9	−155.1 (3)	C11—Ti2—C19—C20	48.8 (6)
C4—Ti1—C8—C9	174.6 (3)	C16—Ti2—C19—C20	37.2 (3)
C2—Ti1—C8—C9	151.6 (3)	C18—Ti2—C19—C20	114.2 (4)
C1—Ti1—C8—C9	−154.6 (3)	C17—Ti2—C19—C20	77.1 (3)
C3—Ti1—C8—C9	146.2 (3)	O2—Ti2—C19—C18	155.4 (3)
C6—Ti1—C8—C9	−78.6 (3)	C20—Ti2—C19—C18	−114.2 (4)
C7—Ti1—C8—C9	−114.2 (4)	C14—Ti2—C19—C18	10.2 (3)
O1—Ti1—C8—C7	143.1 (2)	C15—Ti2—C19—C18	−30.1 (4)
C10—Ti1—C8—C7	76.5 (3)	C13—Ti2—C19—C18	50.6 (3)
C9—Ti1—C8—C7	114.2 (4)	C12—Ti2—C19—C18	84.1 (6)
C5—Ti1—C8—C7	−40.9 (3)	C11—Ti2—C19—C18	−65.5 (6)
C4—Ti1—C8—C7	−71.2 (3)	C16—Ti2—C19—C18	−77.0 (3)
C2—Ti1—C8—C7	−94.2 (3)	C17—Ti2—C19—C18	−37.1 (3)
C1—Ti1—C8—C7	−40.4 (3)	C18—C19—C20—C16	−0.4 (5)
C3—Ti1—C8—C7	−99.6 (3)	Ti2—C19—C20—C16	−70.7 (3)
C6—Ti1—C8—C7	35.6 (2)	C18—C19—C20—Ti2	70.3 (3)
O1—Ti1—C8—C33	−93.0 (4)	C17—C16—C20—C19	1.8 (5)
C10—Ti1—C8—C33	−159.6 (5)	C45—C16—C20—C19	−158.7 (4)
C9—Ti1—C8—C33	−121.9 (6)	Ti2—C16—C20—C19	67.4 (3)
C5—Ti1—C8—C33	83.1 (4)	C17—C16—C20—Ti2	−65.6 (3)
C4—Ti1—C8—C33	52.7 (4)	C45—C16—C20—Ti2	133.9 (4)
C2—Ti1—C8—C33	29.7 (6)	O2—Ti2—C20—C19	89.0 (3)
C1—Ti1—C8—C33	83.5 (5)	C14—Ti2—C20—C19	−81.5 (3)
C3—Ti1—C8—C33	24.3 (5)	C15—Ti2—C20—C19	−122.4 (3)
C6—Ti1—C8—C33	159.5 (5)	C13—Ti2—C20—C19	−42.3 (6)
C7—Ti1—C8—C33	123.9 (6)	C12—Ti2—C20—C19	161.1 (5)
C7—C8—C9—C10	0.7 (5)	C11—Ti2—C20—C19	−163.1 (3)
C33—C8—C9—C10	−158.0 (4)	C16—Ti2—C20—C19	−114.3 (4)
Ti1—C8—C9—C10	66.5 (3)	C18—Ti2—C20—C19	−37.4 (3)
C7—C8—C9—Ti1	−65.8 (3)	C17—Ti2—C20—C19	−77.3 (3)
C33—C8—C9—Ti1	135.5 (4)	O2—Ti2—C20—C16	−156.7 (3)
O1—Ti1—C9—C10	90.4 (2)	C19—Ti2—C20—C16	114.3 (4)
C5—Ti1—C9—C10	−80.1 (3)	C14—Ti2—C20—C16	32.9 (4)
C4—Ti1—C9—C10	−121.6 (3)	C15—Ti2—C20—C16	−8.0 (3)
C2—Ti1—C9—C10	159.3 (4)	C13—Ti2—C20—C16	72.0 (6)
C1—Ti1—C9—C10	−40.0 (6)	C12—Ti2—C20—C16	−84.6 (6)
C3—Ti1—C9—C10	−162.7 (2)	C11—Ti2—C20—C16	−48.8 (3)
C8—Ti1—C9—C10	−115.2 (4)	C18—Ti2—C20—C16	76.9 (3)
C6—Ti1—C9—C10	−37.3 (2)	C17—Ti2—C20—C16	37.1 (2)
C7—Ti1—C9—C10	−77.4 (3)	C5—C1—C21—C22	102.8 (5)
O1—Ti1—C9—C8	−154.5 (2)	C2—C1—C21—C22	−86.6 (5)
C10—Ti1—C9—C8	115.2 (4)	Ti1—C1—C21—C22	8.9 (5)
C5—Ti1—C9—C8	35.0 (3)	C5—C1—C21—C23	−19.0 (6)
C4—Ti1—C9—C8	−6.4 (3)	C2—C1—C21—C23	151.6 (4)
C2—Ti1—C9—C8	−85.5 (6)	Ti1—C1—C21—C23	−112.9 (4)
C1—Ti1—C9—C8	75.2 (6)	C5—C1—C21—C24	−136.7 (4)
C3—Ti1—C9—C8	−47.5 (3)	C2—C1—C21—C24	33.9 (6)
C6—Ti1—C9—C8	77.9 (3)	Ti1—C1—C21—C24	129.4 (3)
C7—Ti1—C9—C8	37.8 (2)	C4—C3—C25—C28	−97.9 (5)
C8—C9—C10—C6	0.3 (5)	C2—C3—C25—C28	92.3 (5)
Ti1—C9—C10—C6	69.6 (3)	Ti1—C3—C25—C28	−3.2 (5)
C8—C9—C10—Ti1	−69.3 (3)	C4—C3—C25—C26	141.1 (5)
C7—C6—C10—C9	−1.2 (5)	C2—C3—C25—C26	−28.7 (6)
C29—C6—C10—C9	157.7 (4)	Ti1—C3—C25—C26	−124.2 (4)
Ti1—C6—C10—C9	−66.9 (3)	C4—C3—C25—C27	23.7 (6)
C7—C6—C10—Ti1	65.7 (3)	C2—C3—C25—C27	−146.2 (4)
C29—C6—C10—Ti1	−135.5 (4)	Ti1—C3—C25—C27	118.4 (4)
O1—Ti1—C10—C9	−88.2 (2)	C10—C6—C29—C31	163.9 (5)
C5—Ti1—C10—C9	125.4 (3)	C7—C6—C29—C31	−41.0 (7)
C4—Ti1—C10—C9	85.7 (3)	Ti1—C6—C29—C31	65.4 (6)
C2—Ti1—C10—C9	−161.2 (4)	C10—C6—C29—C30	38.1 (7)
C1—Ti1—C10—C9	165.5 (2)	C7—C6—C29—C30	−166.9 (5)
C3—Ti1—C10—C9	50.5 (6)	Ti1—C6—C29—C30	−60.4 (6)
C8—Ti1—C10—C9	36.9 (2)	C10—C6—C29—C32	−78.8 (5)
C6—Ti1—C10—C9	114.9 (4)	C7—C6—C29—C32	76.3 (5)
C7—Ti1—C10—C9	77.8 (3)	Ti1—C6—C29—C32	−177.2 (4)
O1—Ti1—C10—C6	156.9 (2)	C9—C8—C33—C34	−30.0 (6)
C9—Ti1—C10—C6	−114.9 (4)	C7—C8—C33—C34	175.1 (4)
C5—Ti1—C10—C6	10.5 (3)	Ti1—C8—C33—C34	69.8 (6)
C4—Ti1—C10—C6	−29.2 (3)	C9—C8—C33—C35	−154.8 (5)
C2—Ti1—C10—C6	83.9 (5)	C7—C8—C33—C35	50.3 (6)
C1—Ti1—C10—C6	50.6 (3)	Ti1—C8—C33—C35	−55.1 (6)
C3—Ti1—C10—C6	−64.4 (6)	C9—C8—C33—C36	86.6 (5)
C8—Ti1—C10—C6	−78.0 (3)	C7—C8—C33—C36	−68.3 (5)
C7—Ti1—C10—C6	−37.1 (2)	Ti1—C8—C33—C36	−173.6 (3)
O2—Ti2—C11—C12	−59.0 (3)	C12—C11—C37—C39	88.8 (5)
C20—Ti2—C11—C12	−161.0 (3)	C15—C11—C37—C39	−101.3 (5)
C19—Ti2—C11—C12	163.2 (5)	Ti2—C11—C37—C39	−6.6 (5)
C14—Ti2—C11—C12	77.1 (3)	C12—C11—C37—C38	−148.5 (4)
C15—Ti2—C11—C12	114.8 (4)	C15—C11—C37—C38	21.4 (6)
C13—Ti2—C11—C12	36.3 (3)	Ti2—C11—C37—C38	116.1 (4)
C16—Ti2—C11—C12	173.2 (3)	C12—C11—C37—C40	−30.8 (6)
C18—Ti2—C11—C12	115.3 (3)	C15—C11—C37—C40	139.2 (5)
C17—Ti2—C11—C12	138.8 (3)	Ti2—C11—C37—C40	−126.2 (4)
O2—Ti2—C11—C15	−173.8 (2)	C14—C13—C41—C43	101.6 (5)
C20—Ti2—C11—C15	84.2 (3)	C12—C13—C41—C43	−90.1 (5)
C19—Ti2—C11—C15	48.4 (6)	Ti2—C13—C41—C43	6.8 (6)
C14—Ti2—C11—C15	−37.7 (2)	C14—C13—C41—C42	−21.1 (6)
C13—Ti2—C11—C15	−78.5 (3)	C12—C13—C41—C42	147.2 (5)
C12—Ti2—C11—C15	−114.8 (4)	Ti2—C13—C41—C42	−115.9 (4)
C16—Ti2—C11—C15	58.4 (3)	C14—C13—C41—C44	−137.5 (5)
C18—Ti2—C11—C15	0.6 (4)	C12—C13—C41—C44	30.8 (6)
C17—Ti2—C11—C15	24.0 (3)	Ti2—C13—C41—C44	127.7 (4)
O2—Ti2—C11—C37	63.0 (4)	C20—C16—C45—C47	−150.3 (5)
C20—Ti2—C11—C37	−39.0 (5)	C17—C16—C45—C47	52.8 (6)
C19—Ti2—C11—C37	−74.8 (7)	Ti2—C16—C45—C47	−52.7 (7)
C14—Ti2—C11—C37	−160.9 (4)	C20—C16—C45—C48	89.2 (5)
C15—Ti2—C11—C37	−123.2 (5)	C17—C16—C45—C48	−67.7 (5)
C13—Ti2—C11—C37	158.3 (4)	Ti2—C16—C45—C48	−173.2 (4)
C12—Ti2—C11—C37	122.0 (5)	C20—C16—C45—C46	−26.6 (6)
C16—Ti2—C11—C37	−64.8 (4)	C17—C16—C45—C46	176.5 (4)
C18—Ti2—C11—C37	−122.7 (4)	Ti2—C16—C45—C46	71.1 (6)
C17—Ti2—C11—C37	−99.2 (4)	C17—C18—C49—C51	−50.5 (6)
C15—C11—C12—C13	−1.6 (5)	C19—C18—C49—C51	154.1 (5)
C37—C11—C12—C13	170.1 (4)	Ti2—C18—C49—C51	56.7 (6)
Ti2—C11—C12—C13	−64.7 (3)	C17—C18—C49—C50	−174.8 (4)
C15—C11—C12—Ti2	63.1 (3)	C19—C18—C49—C50	29.8 (6)
C37—C11—C12—Ti2	−125.2 (4)	Ti2—C18—C49—C50	−67.6 (6)
O2—Ti2—C12—C11	123.2 (3)	C17—C18—C49—C52	68.8 (5)
C20—Ti2—C12—C11	50.5 (6)	C19—C18—C49—C52	−86.6 (5)
C19—Ti2—C12—C11	−165.0 (4)	Ti2—C18—C49—C52	176.0 (4)

Symmetry codes: (i) −x, −y+1, −z+1; (ii) −x, −y+2, −z.