Acta Cryst. (2004). E60, m1453-m1455  [ doi:10.1107/S1600536804022809 ]

Aqua(2,2'-diamino-4,4'-bi-1,3-thiazole)(oxydiacetato-³O,O',O'')cadmium(II) trihydrate

B.-X. Liu, Y.-G. Tian and D.-J. Xu

Abstract: In the title compound, [Cd(C₄H₄O₅)(C₆H₆N₄S₂)(H₂O)]·3H₂O, the Cd^II cation assumes a distorted octahedral CdO₄N₂ coordination formed by a tridentate oxydiacetate (ODA) dianion, a bidentate diaminobithizole (DABT) molecule and a water molecule. ODA chelates to the Cd atom in a meridional configuration, while the two rings of DABT are coplanar. Interplanar distances of 3.438  (4) and 3.382  (10)  Å suggest the presence of - stacking interactions between adjacent thiazole rings.

Online 18 September 2004

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