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Acta Cryst. (2004). E60, m1465-m1467  [ doi:10.1107/S1600536804022950 ]

Tetrabutylbis[3-(4-methoxyphenyl)-2-phenyl-2-propenoato]distannoxane dimer

M. Parvez, Sadiq-ur-Rehman, K. Shahid, S. Ali and M. Mazhar

Abstract: The crystal structure of the title compound, bis[[mu]2-3-(4-methoxyphenyl)-2-phenyl-2-propenoato]bis[3-(4-methoxyphenyl)-2-phenyl-2-propenoato]di-[mu]3-oxo-tetrakis[dibutyltin(IV)], [Sn4(C4H9)8(C17H15O2)4O2], is composed of centrosymmetric dimers in which dibutylbis{[3-(4-methoxyphenyl)-2-phenyl-2-propenoato]tin} units containing monodentate and bridging bidentate ligands are coordinated to the central Sn2O2 core through its O atoms. Both Sn atoms adopt distorted trigonal bipyramidal geometry, with Sn-C distances lying in a narrow range 2.096  (13)-2.161  (6)  Å, while Sn-O distances range between 2.041  (2) and 2.262  (3)  Å.

Online 25 September 2004


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