Acta Cryst. (2004). E60, m1539-m1541  [ doi:10.1107/S1600536804023104 ]

Bis(tetraphenylphosphonium) bis(tetraselenomolybdato)palladate(II)

Z. J. Shiffler, S. M. Baldwin, J. M. Keane, B. L. Belz, M. L. Barr, E. R. Slavin, M. E. Kastner and C. H. Mahler

Abstract: In the title compound, (C₂₄H₂₀P)₂[Pd(MoSe₄)₂], the [Pd(MoSe₄)₂]^2- anion has the Pd^II atom on a crystallographic inversion center with distorted square-planar geometry, coordinated by two nearly tetrahedral bidentate MoSe₄^2- ligands. It is the first complex of palladium and tetraselenomolybdate to be structurally characterized.

Online 30 September 2004

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