Acta Cryst. (2004). E60, m1478-m1480  [ doi:10.1107/S1600536804023049 ]

Bis[1,3-bis(diphenylphosphino)propane-²P,P']silver(I) hemi[cyclopentyldiphenylbis(trifluoroacetato-O)stannate(IV)] hemi[triphenylbis(trifluoroacetato-O)stannate(IV)]

Y. Y. Teo, K. M. Lo and S. W. Ng

Online 25 September 2004

Key indicators

• Single-crystal X-ray study
• T = 113 K
• Mean (C-C) = 0.006 Å
• R factor = 0.047
• wR factor = 0.133
• Data-to-parameter ratio = 14.0

checkCIF/PLATON results

No syntax errors found



Alert level A
PLAT220_ALERT_2_A Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       6.52 Ratio 

PLAT222_ALERT_3_A Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       6.54 Ratio 

PLAT241_ALERT_2_A Check High   U(eq) as Compared to Neighbors  for         F2     

PLAT241_ALERT_2_A Check High   U(eq) as Compared to Neighbors  for        C15     

PLAT241_ALERT_2_A Check High   U(eq) as Compared to Neighbors  for        C16     

PLAT241_ALERT_2_A Check High   U(eq) as Compared to Neighbors  for        C17     

PLAT242_ALERT_2_A Check Low    U(eq) as Compared to Neighbors  for       C15'     
PLAT242_ALERT_2_A Check Low    U(eq) as Compared to Neighbors  for       C16'     
PLAT242_ALERT_2_A Check Low    U(eq) as Compared to Neighbors  for       C17'     

Alert level B
PLAT220_ALERT_2_B Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.94 Ratio 

PLAT241_ALERT_2_B Check High   U(eq) as Compared to Neighbors  for        C46     

PLAT241_ALERT_2_B Check High   U(eq) as Compared to Neighbors  for         F3     

PLAT241_ALERT_2_B Check High   U(eq) as Compared to Neighbors  for        F4'     

PLAT241_ALERT_2_B Check High   U(eq) as Compared to Neighbors  for        O2'     

PLAT242_ALERT_2_B Check Low    U(eq) as Compared to Neighbors  for        C44     
PLAT242_ALERT_2_B Check Low    U(eq) as Compared to Neighbors  for        C47     
PLAT242_ALERT_2_B Check Low    U(eq) as Compared to Neighbors  for       C14'     
PLAT242_ALERT_2_B Check Low    U(eq) as Compared to Neighbors  for        C20     
PLAT301_ALERT_3_B Main Residue  Disorder .........................      26.00 Perc. 

Alert level C
PLAT029_ALERT_3_C _diffrn_measured_fraction_theta_full Low .......       0.98       
PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings    Differ ....          ?
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............       0.50 Ratio 
PLAT165_ALERT_3_C Nr. of Status R Flagged Non-Hydrogen Atoms .....         78       
PLAT220_ALERT_2_C Large Non-Solvent    F     Ueq(max)/Ueq(min) ...       2.52 Ratio 

PLAT220_ALERT_2_C Large Non-Solvent    O     Ueq(max)/Ueq(min) ...       3.49 Ratio 

PLAT222_ALERT_3_C Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       3.97 Ratio 

PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors  for        C40     

PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors  for        C45     

PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors  for        C49     

PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors  for        F3'     

PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors  for        F5'     

PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors  for         F6     

PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors  for        F6'     

PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors  for         O4     

PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors  for        C13     

PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors  for       C19'     

PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors  for       C18'     
PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors  for       C20'     
PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors  for        C22     
PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors  for       C22'     
PLAT313_ALERT_2_C Oxygen with three covalent bonds (rare) ........         O4     
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          4     
            O3  -SN1 -O1  -C19   174.00  2.00   1.555   1.555   1.555   1.555   
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          8     
            O1  -SN1 -O3  -C21   178.00  2.00   1.555   1.555   1.555   1.555   
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         59     
            O3' -SN1'-O1' -C19'   42.00  9.00   1.555   1.555   1.555   1.555   
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         63     
            O1' -SN1'-O3' -C21'  152.00  9.00   1.555   1.555   1.555   1.555   
PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........          8       

Alert level G
FORMU01_ALERT_1_G  There is a discrepancy between the atom counts in the
            _chemical_formula_sum and _chemical_formula_moiety. This is
            usually due to the moiety formula being in the wrong format.
            Atom count from _chemical_formula_sum:   C75.5 H69 Ag1 F6 O4 P4 Sn1
            Atom count from _chemical_formula_moiety:C48.5 H43 Ag1 F6 O4 P2 Sn1

   9 ALERT level A = In general: serious problem
  10 ALERT level B = Potentially serious problem
  28 ALERT level C = Check and explain
   1 ALERT level G = General alerts; check

   4 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
  34 ALERT type 2 Indicator that the structure model may be wrong or deficient
   5 ALERT type 3 Indicator that the structure quality may be low
   5 ALERT type 4 Improvement, methodology, query or suggestion

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