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Acta Cryst. (2004). E60, m1716-m1718  [ doi:10.1107/S1600536804026765 ]

catena-Poly[bis[aqua(1,10-phenanthroline)cobalt(II)]-[mu]4-1,2,4,5-benzenetetracarboxylato]

Y.-L. Fu, J.-L. Ren and S. W. Ng

Abstract: The title compound, [Co2(C10H2O8)(C12H8N2)2(H2O)2]n, adopts a linear chain structure in which the tetra-anionic ligand, which lies on a special position of \overline 1 site symmetry, uses two O atoms of one carboxylate group to bind to one Co atom and the O atom of the carboxyl group at the ortho position to bind to another Co atom. Each Co atom is also chelated by the N-heterocycle, and its sixth coordination site is occupied by a water molecule.

Online 30 October 2004


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