Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804024407/lh6268sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536804024407/lh6268Isup2.hkl |
CCDC reference: 255869
Key indicators
- Single-crystal X-ray study
- T = 193 K
- Mean (C-C) = 0.005 Å
- R factor = 0.053
- wR factor = 0.100
- Data-to-parameter ratio = 9.7
checkCIF/PLATON results
No syntax errors found
Alert level C PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 2.95 Ratio PLAT220_ALERT_2_C Large Non-Solvent O Ueq(max)/Ueq(min) ... 2.57 Ratio PLAT340_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 5
Alert level G REFLT03_ALERT_4_G Please check that the estimate of the number of Friedel pairs is correct. If it is not, please give the correct count in the _publ_section_exptl_refinement section of the submitted CIF. From the CIF: _diffrn_reflns_theta_max 26.43 From the CIF: _reflns_number_total 2286 Count of symmetry unique reflns 2308 Completeness (_total/calc) 99.05% TEST3: Check Friedels for noncentro structure Estimate of Friedel pairs measured 0 Fraction of Friedel pairs measured 0.000 Are heavy atom types Z>Si present no
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 3 ALERT level C = Check and explain 1 ALERT level G = General alerts; check 0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 2 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 1 ALERT type 4 Improvement, methodology, query or suggestion
Data collection: SMART (Bruker, 1997); cell refinement: SAINT (Bruker, 1997); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1990); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997a); molecular graphics: SHELXTL (Sheldrick, 1997b); software used to prepare material for publication: SHELXTL.
C17H24O9 | Dx = 1.289 Mg m−3 |
Mr = 372.36 | Melting point: 376 K |
Orthorhombic, P212121 | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: P 2ac 2ab | Cell parameters from 1490 reflections |
a = 5.4608 (6) Å | θ = 2.9–25.9° |
b = 14.4068 (17) Å | µ = 0.11 mm−1 |
c = 24.392 (3) Å | T = 193 K |
V = 1919.0 (4) Å3 | Needle, colourless |
Z = 4 | 0.60 × 0.06 × 0.05 mm |
F(000) = 792 |
Bruker PLATFORM diffractometer/SMART 1000 CCD area-detector | 2286 independent reflections |
Radiation source: fine-focus sealed tube | 1581 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.084 |
Detector resolution: 8.192 pixels mm-1 | θmax = 26.4°, θmin = 1.6° |
ω scans | h = −5→6 |
Absorption correction: integration (SHELXTL; Sheldrick, 1997b) | k = −15→17 |
Tmin = 0.964, Tmax = 0.995 | l = −30→30 |
10431 measured reflections |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.053 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.100 | H-atom parameters constrained |
S = 1.02 | w = 1/[σ2(Fo2) + (0.0331P)2 + 0.5928P] where P = (Fo2 + 2Fc2)/3 |
2286 reflections | (Δ/σ)max < 0.001 |
235 parameters | Δρmax = 0.18 e Å−3 |
0 restraints | Δρmin = −0.20 e Å−3 |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. Hydrogen atoms were refined with fixed C—H distances and with isotropic displacement parameters 20% (for C—H) greater than those for their attached atoms. The absolute structure could not be determined from the X-ray data (light atoms only), but was assigned on the basis of the established stereochemistry of the precursor compound. Friedel pairs were merged before the final least-squares refinement. |
x | y | z | Uiso*/Ueq | ||
O5 | 0.3586 (5) | 0.26661 (15) | 0.16644 (10) | 0.0305 (6) | |
O6 | 0.3876 (4) | 0.42836 (18) | 0.23409 (8) | 0.0272 (5) | |
O7 | 0.3567 (4) | 0.59133 (15) | 0.16453 (9) | 0.0282 (6) | |
O8 | 0.7388 (4) | 0.42879 (18) | 0.08715 (9) | 0.0333 (6) | |
O9 | 0.8465 (5) | 0.58918 (18) | 0.02816 (9) | 0.0426 (7) | |
O10 | 0.6694 (5) | 0.16661 (18) | 0.17619 (12) | 0.0472 (8) | |
O12 | −0.0232 (4) | 0.4330 (2) | 0.23480 (10) | 0.0419 (7) | |
O14 | 0.6421 (5) | 0.68568 (18) | 0.20089 (11) | 0.0409 (7) | |
O16 | 1.1120 (7) | 0.7039 (3) | 0.04274 (13) | 0.0698 (10) | |
C1 | 0.2802 (11) | 0.3987 (3) | −0.03443 (19) | 0.0711 (16) | |
H1A | 0.1264 | 0.4214 | −0.0221 | 0.085* | |
H1B | 0.3277 | 0.4070 | −0.0716 | 0.085* | |
C2 | 0.4240 (10) | 0.3569 (3) | −0.00082 (16) | 0.0544 (13) | |
H2 | 0.5763 | 0.3352 | −0.0146 | 0.065* | |
C3 | 0.3692 (9) | 0.3399 (3) | 0.05840 (14) | 0.0425 (11) | |
H3A | 0.2968 | 0.2773 | 0.0624 | 0.051* | |
H3B | 0.2457 | 0.3856 | 0.0708 | 0.051* | |
C4 | 0.5948 (7) | 0.3469 (2) | 0.09554 (14) | 0.0321 (10) | |
H4 | 0.7017 | 0.2923 | 0.0873 | 0.039* | |
C5 | 0.5286 (7) | 0.3425 (2) | 0.15654 (14) | 0.0280 (9) | |
H5 | 0.6802 | 0.3334 | 0.1789 | 0.034* | |
C6 | 0.3975 (6) | 0.4292 (3) | 0.17484 (12) | 0.0259 (8) | |
H6 | 0.2274 | 0.4295 | 0.1597 | 0.031* | |
C7 | 0.5296 (7) | 0.5167 (2) | 0.15750 (13) | 0.0240 (8) | |
H7 | 0.6745 | 0.5271 | 0.1818 | 0.029* | |
C8 | 0.6125 (7) | 0.5132 (2) | 0.09782 (14) | 0.0282 (9) | |
H8 | 0.4671 | 0.5182 | 0.0731 | 0.034* | |
C9 | 0.7888 (7) | 0.5907 (3) | 0.08583 (14) | 0.0366 (10) | |
H9A | 0.7142 | 0.6511 | 0.0957 | 0.044* | |
H9B | 0.9400 | 0.5826 | 0.1077 | 0.044* | |
C10 | 0.4540 (7) | 0.1818 (3) | 0.17389 (15) | 0.0315 (9) | |
C11 | 0.2579 (8) | 0.1101 (3) | 0.17786 (18) | 0.0422 (11) | |
H11A | 0.3104 | 0.0607 | 0.2029 | 0.051* | |
H11B | 0.2269 | 0.0837 | 0.1415 | 0.051* | |
H11C | 0.1075 | 0.1386 | 0.1919 | 0.051* | |
C12 | 0.1676 (6) | 0.4288 (3) | 0.25898 (13) | 0.0258 (8) | |
C13 | 0.1981 (7) | 0.4258 (3) | 0.31954 (13) | 0.0354 (9) | |
H13A | 0.0373 | 0.4195 | 0.3370 | 0.042* | |
H13B | 0.2762 | 0.4833 | 0.3320 | 0.042* | |
H13C | 0.3010 | 0.3727 | 0.3295 | 0.042* | |
C14 | 0.4334 (8) | 0.6725 (3) | 0.18686 (14) | 0.0288 (9) | |
C15 | 0.2287 (7) | 0.7399 (3) | 0.19053 (17) | 0.0377 (10) | |
H15A | 0.2916 | 0.8000 | 0.2030 | 0.045* | |
H15B | 0.1064 | 0.7171 | 0.2167 | 0.045* | |
H15C | 0.1529 | 0.7471 | 0.1544 | 0.045* | |
C16 | 1.0150 (9) | 0.6504 (3) | 0.01198 (18) | 0.0482 (12) | |
C17 | 1.0608 (10) | 0.6452 (3) | −0.04807 (17) | 0.0657 (15) | |
H17A | 0.9741 | 0.6959 | −0.0665 | 0.079* | |
H17B | 1.0017 | 0.5855 | −0.0621 | 0.079* | |
H17C | 1.2369 | 0.6507 | −0.0551 | 0.079* |
U11 | U22 | U33 | U12 | U13 | U23 | |
O5 | 0.0256 (15) | 0.0216 (13) | 0.0444 (15) | −0.0001 (12) | −0.0010 (13) | 0.0049 (12) |
O6 | 0.0203 (13) | 0.0336 (13) | 0.0277 (12) | 0.0004 (13) | 0.0003 (10) | 0.0037 (12) |
O7 | 0.0254 (14) | 0.0219 (14) | 0.0372 (13) | 0.0006 (12) | −0.0049 (12) | −0.0044 (11) |
O8 | 0.0323 (14) | 0.0259 (14) | 0.0417 (14) | 0.0034 (14) | 0.0104 (11) | 0.0003 (12) |
O9 | 0.0588 (18) | 0.0361 (16) | 0.0330 (14) | −0.0077 (16) | 0.0144 (13) | 0.0014 (12) |
O10 | 0.0257 (17) | 0.0293 (16) | 0.087 (2) | 0.0062 (13) | 0.0026 (16) | 0.0083 (15) |
O12 | 0.0236 (14) | 0.0610 (19) | 0.0411 (15) | 0.0025 (16) | −0.0019 (12) | −0.0010 (15) |
O14 | 0.0245 (16) | 0.0399 (16) | 0.0585 (17) | −0.0020 (14) | −0.0034 (14) | −0.0179 (14) |
O16 | 0.081 (3) | 0.069 (2) | 0.060 (2) | −0.036 (2) | 0.016 (2) | 0.0036 (18) |
C1 | 0.102 (4) | 0.069 (4) | 0.042 (3) | 0.005 (3) | −0.002 (3) | 0.001 (3) |
C2 | 0.076 (4) | 0.052 (3) | 0.035 (2) | 0.008 (3) | 0.004 (2) | −0.010 (2) |
C3 | 0.057 (3) | 0.033 (2) | 0.038 (2) | −0.011 (2) | −0.002 (2) | −0.0057 (18) |
C4 | 0.035 (3) | 0.021 (2) | 0.040 (2) | 0.0045 (18) | 0.009 (2) | 0.0001 (17) |
C5 | 0.022 (2) | 0.022 (2) | 0.040 (2) | −0.0023 (17) | 0.0015 (17) | 0.0042 (17) |
C6 | 0.0245 (19) | 0.0298 (19) | 0.0233 (17) | 0.004 (2) | −0.0012 (14) | −0.0013 (17) |
C7 | 0.024 (2) | 0.020 (2) | 0.0283 (19) | 0.0038 (16) | −0.0036 (17) | −0.0009 (15) |
C8 | 0.032 (2) | 0.024 (2) | 0.0282 (19) | 0.0025 (18) | −0.0023 (18) | −0.0005 (16) |
C9 | 0.044 (3) | 0.034 (2) | 0.031 (2) | −0.004 (2) | 0.0095 (18) | 0.0002 (17) |
C10 | 0.031 (2) | 0.028 (2) | 0.036 (2) | 0.0027 (19) | −0.0006 (19) | 0.0012 (17) |
C11 | 0.035 (3) | 0.029 (2) | 0.063 (3) | −0.0013 (18) | −0.002 (2) | 0.005 (2) |
C12 | 0.024 (2) | 0.0229 (18) | 0.0300 (18) | −0.001 (2) | 0.0035 (17) | 0.0014 (17) |
C13 | 0.034 (2) | 0.037 (2) | 0.035 (2) | −0.003 (2) | 0.0028 (17) | 0.0009 (19) |
C14 | 0.032 (2) | 0.026 (2) | 0.0280 (19) | −0.0035 (18) | 0.0039 (18) | −0.0019 (16) |
C15 | 0.026 (2) | 0.031 (2) | 0.056 (3) | 0.0026 (19) | 0.002 (2) | −0.0067 (19) |
C16 | 0.061 (3) | 0.035 (3) | 0.049 (3) | −0.004 (2) | 0.021 (2) | 0.008 (2) |
C17 | 0.089 (4) | 0.055 (3) | 0.053 (3) | 0.000 (3) | 0.032 (3) | 0.009 (2) |
O5—C5 | 1.454 (4) | C5—H5 | 1.0000 |
O5—C10 | 1.341 (4) | C6—C7 | 1.513 (5) |
O6—C6 | 1.446 (4) | C6—H6 | 1.0000 |
O6—C12 | 1.346 (4) | C7—C8 | 1.525 (5) |
O7—C7 | 1.441 (4) | C7—H7 | 1.0000 |
O7—C14 | 1.356 (4) | C8—C9 | 1.504 (5) |
O8—C4 | 1.432 (4) | C8—H8 | 1.0000 |
O8—C8 | 1.422 (4) | C9—H9A | 0.9900 |
O9—C9 | 1.442 (4) | C9—H9B | 0.9900 |
O9—C16 | 1.334 (5) | C10—C11 | 1.491 (5) |
O10—C10 | 1.197 (5) | C11—H11A | 0.9800 |
O12—C12 | 1.199 (4) | C11—H11B | 0.9800 |
O14—C14 | 1.205 (4) | C11—H11C | 0.9800 |
O16—C16 | 1.200 (5) | C12—C13 | 1.487 (4) |
C1—C2 | 1.286 (6) | C13—H13A | 0.9800 |
C1—H1A | 0.9500 | C13—H13B | 0.9800 |
C1—H1B | 0.9500 | C13—H13C | 0.9800 |
C2—C3 | 1.495 (5) | C14—C15 | 1.483 (5) |
C2—H2 | 0.9500 | C15—H15A | 0.9800 |
C3—C4 | 1.533 (6) | C15—H15B | 0.9800 |
C3—H3A | 0.9900 | C15—H15C | 0.9800 |
C3—H3B | 0.9900 | C16—C17 | 1.488 (6) |
C4—C5 | 1.533 (5) | C17—H17A | 0.9800 |
C4—H4 | 1.0000 | C17—H17B | 0.9800 |
C5—C6 | 1.508 (5) | C17—H17C | 0.9800 |
C10—O5—C5 | 117.4 (3) | C9—C8—H8 | 109.7 |
C12—O6—C6 | 119.0 (2) | C7—C8—H8 | 109.7 |
C14—O7—C7 | 119.3 (3) | O9—C9—C8 | 108.5 (3) |
C8—O8—C4 | 114.3 (2) | O9—C9—H9A | 110.0 |
C16—O9—C9 | 115.4 (3) | C8—C9—H9A | 110.0 |
C2—C1—H1A | 120.0 | O9—C9—H9B | 110.0 |
C2—C1—H1B | 120.0 | C8—C9—H9B | 110.0 |
H1A—C1—H1B | 120.0 | H9A—C9—H9B | 108.4 |
C1—C2—C3 | 124.8 (5) | O10—C10—O5 | 123.6 (3) |
C1—C2—H2 | 117.6 | O10—C10—C11 | 125.2 (4) |
C3—C2—H2 | 117.6 | O5—C10—C11 | 111.2 (3) |
C2—C3—C4 | 113.5 (4) | C10—C11—H11A | 109.5 |
C2—C3—H3A | 108.9 | C10—C11—H11B | 109.5 |
C4—C3—H3A | 108.9 | H11A—C11—H11B | 109.5 |
C2—C3—H3B | 108.9 | C10—C11—H11C | 109.5 |
C4—C3—H3B | 108.9 | H11A—C11—H11C | 109.5 |
H3A—C3—H3B | 107.7 | H11B—C11—H11C | 109.5 |
O8—C4—C5 | 107.6 (3) | O12—C12—O6 | 123.6 (3) |
O8—C4—C3 | 114.3 (3) | O12—C12—C13 | 126.0 (3) |
C5—C4—C3 | 112.4 (3) | O6—C12—C13 | 110.4 (3) |
O8—C4—H4 | 107.4 | C12—C13—H13A | 109.5 |
C5—C4—H4 | 107.4 | C12—C13—H13B | 109.5 |
C3—C4—H4 | 107.4 | H13A—C13—H13B | 109.5 |
O5—C5—C6 | 105.7 (3) | C12—C13—H13C | 109.5 |
O5—C5—C4 | 110.1 (3) | H13A—C13—H13C | 109.5 |
C6—C5—C4 | 111.4 (3) | H13B—C13—H13C | 109.5 |
O5—C5—H5 | 109.9 | O14—C14—O7 | 122.8 (4) |
C6—C5—H5 | 109.9 | O14—C14—C15 | 126.3 (3) |
C4—C5—H5 | 109.9 | O7—C14—C15 | 110.9 (3) |
O6—C6—C5 | 107.8 (3) | C14—C15—H15A | 109.5 |
O6—C6—C7 | 107.7 (3) | C14—C15—H15B | 109.5 |
C5—C6—C7 | 112.4 (3) | H15A—C15—H15B | 109.5 |
O6—C6—H6 | 109.6 | C14—C15—H15C | 109.5 |
C5—C6—H6 | 109.6 | H15A—C15—H15C | 109.5 |
C7—C6—H6 | 109.6 | H15B—C15—H15C | 109.5 |
O7—C7—C6 | 106.0 (3) | O16—C16—O9 | 123.0 (4) |
O7—C7—C8 | 109.4 (3) | O16—C16—C17 | 125.0 (4) |
C6—C7—C8 | 112.4 (3) | O9—C16—C17 | 112.0 (4) |
O7—C7—H7 | 109.6 | C16—C17—H17A | 109.5 |
C6—C7—H7 | 109.6 | C16—C17—H17B | 109.5 |
C8—C7—H7 | 109.6 | H17A—C17—H17B | 109.5 |
O8—C8—C9 | 106.8 (3) | C16—C17—H17C | 109.5 |
O8—C8—C7 | 110.3 (3) | H17A—C17—H17C | 109.5 |
C9—C8—C7 | 110.5 (3) | H17B—C17—H17C | 109.5 |
O8—C8—H8 | 109.7 | ||
C1—C2—C3—C4 | −144.1 (5) | C5—C6—C7—O7 | 165.3 (3) |
C8—O8—C4—C5 | −64.0 (3) | O6—C6—C7—C8 | 164.5 (3) |
C8—O8—C4—C3 | 61.6 (4) | C5—C6—C7—C8 | 45.8 (4) |
C2—C3—C4—O8 | 49.2 (5) | C4—O8—C8—C9 | −178.9 (3) |
C2—C3—C4—C5 | 172.2 (3) | C4—O8—C8—C7 | 61.0 (3) |
C10—O5—C5—C6 | −155.1 (3) | O7—C7—C8—O8 | −167.1 (3) |
C10—O5—C5—C4 | 84.5 (4) | C6—C7—C8—O8 | −49.6 (4) |
O8—C4—C5—O5 | 173.4 (3) | O7—C7—C8—C9 | 75.0 (4) |
C3—C4—C5—O5 | 46.7 (4) | C6—C7—C8—C9 | −167.5 (3) |
O8—C4—C5—C6 | 56.5 (4) | C16—O9—C9—C8 | −175.5 (3) |
C3—C4—C5—C6 | −70.2 (4) | O8—C8—C9—O9 | 64.6 (4) |
C12—O6—C6—C5 | −119.7 (3) | C7—C8—C9—O9 | −175.4 (3) |
C12—O6—C6—C7 | 118.7 (3) | C5—O5—C10—O10 | 4.8 (5) |
O5—C5—C6—O6 | 72.3 (3) | C5—O5—C10—C11 | −174.2 (3) |
C4—C5—C6—O6 | −168.2 (3) | C6—O6—C12—O12 | −2.7 (6) |
O5—C5—C6—C7 | −169.1 (3) | C6—O6—C12—C13 | 178.9 (3) |
C4—C5—C6—C7 | −49.6 (4) | C7—O7—C14—O14 | 0.6 (5) |
C14—O7—C7—C6 | 137.5 (3) | C7—O7—C14—C15 | −180.0 (3) |
C14—O7—C7—C8 | −101.1 (3) | C9—O9—C16—O16 | −0.6 (6) |
O6—C6—C7—O7 | −76.0 (3) | C9—O9—C16—C17 | −179.1 (4) |