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Acta Cryst. (2004). E60, m1630-m1632  [ doi:10.1107/S1600536804025383 ]

Diaquatris(nicotinato-[kappa]O)bis(1,10-phenanthroline-[kappa]2N,N')neodymium(III) trihydrate

F.-C. Liu and X.-L. Wang

Abstract: The title compound, [Nd(C6H4NO2)3(C12H8N2)2(H2O)2]·3H2O, consists of a mononuclear [Nd(C6H4NO2)3(C12H8N2)2(H2O)2] molecule and three uncoordinated water molecules. The NdIII atom is nine-coordinate through coordination by the O atoms of three nicotinate groups, four N atoms of two phenanthroline molecules and two water molecules in a tricapped trigonal prismatic coordination geometry. The mononuclear molecule and solvent water molecule are linked by hydrogen bonds to form a layer framework.

Online 16 October 2004


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