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Acta Cryst. (2004). E60, m1754-m1756  [ doi:10.1107/S1600536804027709 ]

Aqua(benzene-1,3-dioxyacetato-[kappa]O)tetrakis(1H-imidazole-[kappa]N3)nickel(II) monohydrate

S. Gao, J.-W. Liu, L.-H. Huo, H. Zhao and J.-G. Zhao

Abstract: In the title complex {systematic name: aqua[p-phenylenebis(dioxyacetato)-[kappa]O]tetrakis(1H-imidazole-[kappa]N3)nickel(II) monohydrate}, [Ni(C10H8O6)(C3H4N2)4(H2O)]·H2O, the NiII atom shows a distorted octahedral configuration, defined by one carboxyl O atom of the benzene-1,3-dioxyacetate group, four N atoms from four imidazole ligands and one water molecule. A three-dimensional supramolecular network is constructed by hydrogen-bonding and [pi]-[pi] stacking interactions.

Online 6 November 2004


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