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Acta Cryst. (2004). E60, m1982-m1984  [ doi:10.1107/S1600536804030806 ]

catena-Poly[[[diaquacobalt(II)]-[mu]-tartrato-[kappa]4O,O':O'',O'''] monohydrate]

D.-X. Li, D.-J. Xu and Y.-Z. Xu

Abstract: In the title CoII polymeric complex bridged by tartrate dianions, {[Co(C4H4O6)(H2O)2]·H2O}n, the CoII atom is coordinated by two tartrate dianions and two water molecules to give a distorted octahedral geometry. The hydroxyl O atom and one O atom of each carboxyl group chelate to the CoII atom, but the other O atom of this carboxyl group is uncoordinated. The polymeric chains are linked to each other via hydrogen bonds to form cavities which are filled with solvent water molecules.

Online 30 November 2004


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