Acta Cryst. (2004). E60, m1744-m1746  [ doi:10.1107/S1600536804026650 ]

catena-Poly[[aquanitritosilver(I)]--1,4-diazabicyclo[2,2,2]octane-²N:N']

Z.-L. You, H.-L. Zhu and W.-S. Liu

Abstract: The title compound, [Ag(NO₂)(C₆H₁₂N₂)(H₂O)]_n, is a polymeric 1,4-diazabicyclo[2,2,2]octane-Ag^I complex. Each Ag atom is five-coordinated by two N atoms from two different 1,4-diazabicyclo[2,2,2]octane ligands, two O atoms of one nitrite anion and another O atom of a coordinated water molecule, forming a severely distorted square-pyramidal coordination environment. In the crystal structure, molecules are connected by intermolecular O-HO hydrogen bonds, forming a three-dimensional network.

Online 6 November 2004

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