Acta Cryst. (2004). E60, m1849-m1851  [ doi:10.1107/S1600536804029137 ]

Poly[triaqua(-benzene-1,3-dioxyacetato)manganese(II)]: a two-dimensional manganese(II) coordination polymer

S. Gao, J.-W. Liu, L.-H. Huo, H. Zhao and J.-G. Zhao

Abstract: In the asymmetric unit of the title compound, [Mn(C₁₀H₈O₆)(H₂O)₃]_n, the two half-Mn^II atoms lie on inversion centres. One Mn^II atom is in an octahedral configuration, defined by two O atoms from two monodentate carboxylate groups and four water molecules, and the other Mn^II atom exists in a different octahedral coordination environment, defined by four O atoms from four monodentate carboxylate groups and two water molecules. The Mn^II atoms are bridged by a benzene-1,3-dioxyacetate dianion in monodentate and bridging-bidentate modes, forming a two-dimensional layer structure.

Online 20 November 2004

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