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Acta Cryst. (2004). E60, o2201-o2203  [ doi:10.1107/S1600536804027266 ]

p-Tolyl 2,3-anhydro-5,6-O-isopropylidene-1-thio-[beta]-D-gulofuranoside

Y. Bai, T. L. Lowary and M. J. Ferguson

Abstract: In the title compound, C16H20O4S, the epoxide ring is trans to the p-tolyl group and cis to the dioxolane moiety. The furanose ring adopts a conformation in which the furanose and epoxide O atoms are on the same face of the molecule (EO) and the p-tolyl group adopts the conformation favored by the exo-anomeric effect, gauche to the ring O atom and anti to the ring C atom.

Online 6 November 2004


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