μ-3,4,5,6-Tetra­fluoro­phthalato-bis­[tris(2-methyl-2-phenyl­propyl)­tin(IV)]

The mol­ecule of the title compound, [Sn₂(C₁₀H₁₃)₆(C₈F₄O₄)], has crystallographic twofold symmetry. The Sn atoms are four-coordinate in a tetrahedral geometry.

Key indicators

• Single-crystal X-ray study
• T = 295 K
• Mean [sigma](C-C) = 0.006 Å
• R factor = 0.028
• wR factor = 0.068
• Data-to-parameter ratio = 19.9

checkCIF/PLATON results

No syntax errors found



Alert level C
ABSTM02_ALERT_3_C  The ratio of expected to reported Tmax/Tmin(RR') is < 0.90
            Tmin and Tmax reported:      0.759     0.935
            Tmin' and Tmax expected:      0.855     0.934
            RR' =      0.887
            Please check that your absorption correction is appropriate.
PLAT061_ALERT_3_C Tmax/Tmin Range Test RR' too Large .............       0.88
PLAT094_ALERT_2_C Ratio of Maximum / Minimum Residual Density ....       2.52
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       2.60 Ratio
PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors  for        C15

Alert level G
REFLT03_ALERT_4_G Please check that the estimate of the number of Friedel pairs is
            correct. If it is not, please give the correct count in the
            _publ_section_exptl_refinement section of the submitted CIF.
           From the CIF: _diffrn_reflns_theta_max           27.50
           From the CIF: _reflns_number_total               7137
           Count of symmetry unique reflns         3795
           Completeness (_total/calc)            188.06%
           TEST3: Check Friedels for noncentro structure
           Estimate of Friedel pairs measured      3342
           Fraction of Friedel pairs measured     0.881
           Are heavy atom types Z>Si present          yes

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   5 ALERT level C = Check and explain
   1 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   3 ALERT type 2 Indicator that the structure model may be wrong or deficient
   2 ALERT type 3 Indicator that the structure quality may be low
   1 ALERT type 4 Improvement, methodology, query or suggestion

---

Computing details

Data collection: SMART (Bruker, 2002); cell refinement: SAINT (Bruker, 2002); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.

µ-3,4,5,6-Tetrafluorophthalato-bis[tris(2-methyl-2-phenylpropyl)tin(IV)]

Crystal data

[Sn2(C10H13)6(C8F4O4)]	F(000) = 1308
Mr = 1272.68	Dx = 1.344 Mg m^−3
Monoclinic, C2	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: C 2y	Cell parameters from 8235 reflections
a = 14.4124 (6) Å	θ = 2.2–24.4°
b = 12.5830 (6) Å	µ = 0.85 mm^−1
c = 17.9361 (8) Å	T = 295 K
β = 104.833 (1)°	Plate, colorless
V = 3144.3 (2) Å^3	0.18 × 0.15 × 0.08 mm
Z = 2

Data collection

Bruker APEX area-detector diffractometer	7137 independent reflections
Radiation source: fine-focus sealed tube	6453 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.030
φ and ω scans	θmax = 27.5°, θmin = 2.2°
Absorption correction: multi-scan (SADABS; Bruker, 2002)	h = −18→18
Tmin = 0.759, Tmax = 0.935	k = −16→16
18250 measured reflections	l = −23→23

Refinement

Refinement on F^2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.028	H-atom parameters constrained
wR(F^2) = 0.068	w = 1/[σ^2(Fo^2) + (0.0386P)^2] where P = (Fo^2 + 2Fc^2)/3
S = 0.99	(Δ/σ)max = 0.003
7137 reflections	Δρmax = 0.58 e Å^−3
358 parameters	Δρmin = −0.23 e Å^−3
1 restraint	Absolute structure: Flack (1983), 3565 Friedel pairs
Primary atom site location: structure-invariant direct methods	Absolute structure parameter: −0.03 (2)

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Sn1	0.60500 (1)	0.50000 (2)	0.20203 (1)	0.04589 (6)
F1	0.6248 (2)	0.1450 (2)	0.1409 (1)	0.0758 (5)
F2	0.5631 (2)	−0.0389 (2)	0.0701 (2)	0.1042 (9)
O1	0.5539 (2)	0.3608 (2)	0.1426 (1)	0.0543 (6)
O2	0.6108 (2)	0.4091 (2)	0.0443 (1)	0.0823 (8)
C1	0.7581 (2)	0.4881 (4)	0.2206 (2)	0.0637 (8)
C2	0.8128 (2)	0.5823 (3)	0.1985 (2)	0.0706 (9)
C3	0.7897 (3)	0.5892 (4)	0.1103 (2)	0.0941 (13)
C4	0.9211 (3)	0.5613 (4)	0.2296 (3)	0.1007 (14)
C5	0.7874 (3)	0.6854 (3)	0.2353 (2)	0.0719 (9)
C6	0.7643 (4)	0.7786 (4)	0.1947 (3)	0.1013 (15)
C7	0.7429 (4)	0.8707 (4)	0.2292 (4)	0.1185 (19)
C8	0.7466 (4)	0.8704 (4)	0.3050 (4)	0.1193 (19)
C9	0.7679 (3)	0.7800 (5)	0.3477 (3)	0.1016 (15)
C10	0.7880 (3)	0.6875 (4)	0.3127 (2)	0.0801 (10)
C11	0.5459 (2)	0.4571 (3)	0.2964 (2)	0.0582 (8)
C12	0.6020 (2)	0.3816 (3)	0.3593 (2)	0.0588 (8)
C13	0.5341 (3)	0.3456 (4)	0.4085 (2)	0.0902 (13)
C14	0.6316 (3)	0.2824 (3)	0.3220 (2)	0.0690 (9)
C15	0.6871 (2)	0.4391 (3)	0.4122 (2)	0.0574 (7)
C16	0.6732 (3)	0.5325 (3)	0.4484 (2)	0.0869 (14)
C17	0.7484 (4)	0.5852 (4)	0.4984 (3)	0.1084 (17)
C18	0.8380 (4)	0.5442 (5)	0.5141 (3)	0.1041 (17)
C19	0.8537 (4)	0.4536 (4)	0.4788 (3)	0.1022 (17)
C20	0.7787 (3)	0.4007 (3)	0.4287 (2)	0.0757 (10)
C21	0.5315 (3)	0.6251 (3)	0.1280 (2)	0.0616 (10)
C22	0.4305 (2)	0.6559 (3)	0.1348 (2)	0.0605 (8)
C23	0.3955 (3)	0.7543 (4)	0.0839 (3)	0.0926 (13)
C24	0.3624 (2)	0.5630 (3)	0.1051 (2)	0.0694 (9)
C25	0.4337 (2)	0.6843 (3)	0.2186 (2)	0.0588 (7)
C26	0.5043 (3)	0.7499 (3)	0.2611 (2)	0.0817 (11)
C27	0.5120 (3)	0.7693 (4)	0.3388 (3)	0.1037 (16)
C28	0.4479 (4)	0.7278 (5)	0.3731 (3)	0.1106 (19)
C29	0.3750 (3)	0.6656 (5)	0.3319 (3)	0.0997 (15)
C30	0.3675 (3)	0.6453 (3)	0.2551 (2)	0.0755 (10)
C31	0.5696 (2)	0.3478 (2)	0.0756 (2)	0.0503 (6)
C32	0.5319 (2)	0.2441 (2)	0.0370 (2)	0.0461 (6)
C33	0.5621 (2)	0.1483 (2)	0.0712 (2)	0.0545 (7)
C34	0.5319 (3)	0.0532 (3)	0.0355 (2)	0.0657 (9)
H1a	0.7852	0.4736	0.2749	0.076*
H1b	0.7710	0.4265	0.1923	0.076*
H3a	0.7226	0.6034	0.0899	0.141*
H3b	0.8057	0.5231	0.0899	0.141*
H3c	0.8265	0.6455	0.0957	0.141*
H4a	0.9382	0.4983	0.2060	0.151*
H4b	0.9360	0.5517	0.2845	0.151*
H4c	0.9565	0.6207	0.2176	0.151*
H6	0.7630	0.7798	0.1426	0.122*
H7	0.7260	0.9323	0.2002	0.142*
H8	0.7345	0.9329	0.3285	0.143*
H9	0.7689	0.7803	0.3997	0.122*
H10	0.8022	0.6257	0.3418	0.096*
H11a	0.5349	0.5224	0.3216	0.070*
H11b	0.4835	0.4253	0.2747	0.070*
H13a	0.5696	0.3047	0.4516	0.135*
H13b	0.4835	0.3029	0.3776	0.135*
H13c	0.5071	0.4069	0.4269	0.135*
H14a	0.6812	0.3005	0.2972	0.104*
H14b	0.5771	0.2547	0.2844	0.104*
H14c	0.6553	0.2297	0.3609	0.104*
H16	0.6117	0.5609	0.4389	0.104*
H17	0.7373	0.6487	0.5211	0.130*
H18	0.8884	0.5781	0.5488	0.125*
H19	0.9156	0.4263	0.4882	0.123*
H20	0.7911	0.3378	0.4058	0.091*
H21a	0.5715	0.6881	0.1380	0.074*
H21b	0.5263	0.6042	0.0750	0.074*
H23a	0.3964	0.7391	0.0317	0.139*
H23b	0.4372	0.8133	0.1027	0.139*
H23c	0.3313	0.7717	0.0859	0.139*
H24a	0.3810	0.5029	0.1385	0.104*
H24b	0.3657	0.5446	0.0539	0.104*
H24c	0.2980	0.5833	0.1043	0.104*
H26	0.5475	0.7818	0.2373	0.098*
H27	0.5619	0.8113	0.3671	0.124*
H28	0.4531	0.7413	0.4250	0.133*
H29	0.3304	0.6370	0.3557	0.120*
H30	0.3167	0.6042	0.2273	0.091*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Sn1	0.04490 (9)	0.05209 (9)	0.04063 (8)	−0.0029 (1)	0.0109 (1)	−0.0029 (1)
F1	0.080 (1)	0.076 (1)	0.060 (1)	0.013 (1)	−0.003 (1)	0.016 (1)
F2	0.135 (2)	0.054 (1)	0.115 (2)	0.017 (1)	0.017 (2)	0.022 (1)
O1	0.065 (1)	0.056 (1)	0.042 (1)	−0.010 (1)	0.014 (1)	−0.006 (1)
O2	0.118 (2)	0.076 (2)	0.059 (1)	−0.042 (2)	0.034 (2)	−0.011 (1)
C1	0.047 (1)	0.077 (2)	0.066 (2)	−0.002 (2)	0.012 (1)	0.000 (2)
C2	0.056 (2)	0.090 (2)	0.069 (2)	−0.020 (2)	0.022 (2)	−0.008 (2)
C3	0.095 (3)	0.123 (4)	0.074 (2)	−0.035 (3)	0.039 (2)	−0.010 (2)
C4	0.055 (2)	0.130 (4)	0.120 (3)	−0.024 (2)	0.026 (2)	−0.024 (3)
C5	0.057 (2)	0.077 (2)	0.083 (2)	−0.024 (2)	0.019 (2)	−0.005 (2)
C6	0.106 (3)	0.083 (3)	0.111 (4)	−0.035 (3)	0.020 (3)	0.005 (3)
C7	0.126 (5)	0.069 (3)	0.155 (6)	−0.027 (3)	0.025 (4)	0.000 (3)
C8	0.105 (4)	0.082 (3)	0.170 (6)	−0.024 (3)	0.032 (4)	−0.036 (4)
C9	0.087 (3)	0.112 (4)	0.109 (4)	−0.018 (3)	0.030 (3)	−0.032 (3)
C10	0.072 (2)	0.088 (3)	0.081 (3)	−0.011 (2)	0.021 (2)	−0.014 (2)
C11	0.048 (2)	0.084 (2)	0.043 (1)	0.011 (1)	0.012 (1)	0.004 (1)
C12	0.054 (2)	0.079 (2)	0.042 (2)	−0.001 (2)	0.011 (1)	0.005 (1)
C13	0.076 (2)	0.134 (4)	0.064 (2)	−0.010 (2)	0.024 (2)	0.026 (2)
C14	0.074 (2)	0.063 (2)	0.063 (2)	−0.005 (2)	0.005 (2)	0.005 (2)
C15	0.061 (2)	0.072 (2)	0.038 (1)	0.006 (2)	0.009 (1)	−0.001 (1)
C16	0.081 (2)	0.109 (4)	0.067 (2)	0.021 (2)	0.012 (2)	−0.025 (2)
C17	0.126 (4)	0.116 (4)	0.072 (3)	0.011 (3)	0.004 (3)	−0.045 (3)
C18	0.107 (4)	0.107 (3)	0.080 (3)	−0.015 (3)	−0.010 (3)	−0.029 (3)
C19	0.068 (3)	0.109 (3)	0.107 (4)	0.010 (2)	−0.019 (3)	−0.011 (3)
C20	0.065 (2)	0.072 (2)	0.078 (2)	0.009 (2)	−0.003 (2)	−0.010 (2)
C21	0.074 (2)	0.058 (2)	0.054 (2)	0.000 (2)	0.018 (2)	0.005 (2)
C22	0.061 (2)	0.056 (2)	0.063 (2)	0.010 (1)	0.011 (2)	0.001 (1)
C23	0.101 (3)	0.082 (3)	0.088 (3)	0.023 (2)	0.012 (2)	0.017 (2)
C24	0.061 (2)	0.081 (2)	0.061 (2)	0.001 (2)	0.006 (2)	−0.018 (2)
C25	0.056 (2)	0.054 (2)	0.064 (2)	0.012 (1)	0.010 (2)	−0.010 (1)
C26	0.072 (2)	0.084 (2)	0.086 (3)	−0.005 (2)	0.014 (2)	−0.026 (2)
C27	0.085 (3)	0.123 (4)	0.092 (3)	0.012 (3)	0.003 (3)	−0.051 (3)
C28	0.097 (3)	0.158 (5)	0.071 (3)	0.040 (3)	0.010 (3)	−0.050 (3)
C29	0.085 (3)	0.138 (4)	0.086 (3)	0.028 (3)	0.039 (2)	−0.025 (3)
C30	0.060 (2)	0.086 (2)	0.080 (2)	0.013 (2)	0.017 (2)	−0.020 (2)
C31	0.058 (2)	0.050 (2)	0.040 (1)	−0.005 (1)	0.007 (1)	0.002 (1)
C32	0.046 (1)	0.051 (1)	0.043 (1)	−0.001 (1)	0.014 (1)	0.001 (1)
C33	0.055 (2)	0.057 (2)	0.050 (2)	0.003 (1)	0.012 (1)	0.008 (1)
C34	0.076 (2)	0.047 (2)	0.076 (2)	0.009 (2)	0.023 (2)	0.010 (2)

Geometric parameters (Å, º)

Sn1—O1	2.085 (2)	C33—C34	1.375 (5)
Sn1—C1	2.151 (3)	C34—C34^i	1.366 (8)
Sn1—C11	2.149 (3)	C1—H1a	0.97
Sn1—C21	2.155 (4)	C1—H1b	0.97
F1—C33	1.342 (3)	C3—H3a	0.96
F2—C34	1.338 (4)	C3—H3b	0.96
O1—C31	1.287 (4)	C3—H3c	0.96
O2—C31	1.198 (4)	C4—H4a	0.96
C1—C2	1.531 (5)	C4—H4b	0.96
C2—C3	1.535 (5)	C4—H4c	0.96
C2—C4	1.539 (5)	C6—H6	0.93
C2—C5	1.542 (5)	C7—H7	0.93
C5—C6	1.375 (6)	C8—H8	0.93
C5—C10	1.387 (5)	C9—H9	0.93
C6—C7	1.385 (8)	C10—H10	0.93
C7—C8	1.347 (8)	C11—H11a	0.97
C8—C9	1.362 (8)	C11—H11b	0.97
C9—C10	1.387 (7)	C13—H13a	0.96
C11—C12	1.536 (4)	C13—H13b	0.96
C12—C15	1.527 (5)	C13—H13c	0.96
C12—C14	1.527 (5)	C14—H14a	0.96
C12—C13	1.544 (5)	C14—H14b	0.96
C15—C20	1.366 (5)	C14—H14c	0.96
C15—C16	1.381 (5)	C16—H16	0.93
C16—C17	1.386 (6)	C17—H17	0.93
C17—C18	1.351 (7)	C18—H18	0.93
C18—C19	1.351 (7)	C19—H19	0.93
C19—C20	1.386 (6)	C20—H20	0.93
C21—C22	1.541 (5)	C21—H21a	0.97
C22—C24	1.531 (5)	C21—H21b	0.97
C22—C25	1.533 (4)	C23—H23a	0.96
C22—C23	1.544 (5)	C23—H23b	0.96
C25—C30	1.378 (5)	C23—H23c	0.96
C25—C26	1.379 (5)	C24—H24a	0.96
C26—C27	1.392 (6)	C24—H24b	0.96
C27—C28	1.341 (7)	C24—H24c	0.96
C28—C29	1.365 (7)	C26—H26	0.93
C29—C30	1.378 (6)	C27—H27	0.93
C31—C32	1.511 (4)	C28—H28	0.93
C32—C33	1.372 (4)	C29—H29	0.93
C32—C32^i	1.409 (5)	C30—H30	0.93
O1—Sn1—C1	103.5 (2)	H3a—C3—H3c	109.5
O1—Sn1—C11	91.9 (1)	H3b—C3—H3c	109.5
O1—Sn1—C21	104.2 (1)	C2—C4—H4a	109.5
C1—Sn1—C11	117.3 (1)	C2—C4—H4b	109.5
C1—Sn1—C21	118.0 (2)	H4a—C4—H4b	109.5
C11—Sn1—C21	116.0 (1)	C2—C4—H4c	109.5
C31—O1—Sn1	117.4 (2)	H4a—C4—H4c	109.5
C2—C1—Sn1	118.8 (3)	H4b—C4—H4c	109.5
C1—C2—C3	108.7 (3)	C5—C6—H6	119.1
C1—C2—C4	108.4 (3)	C7—C6—H6	119.1
C3—C2—C4	108.3 (3)	C8—C7—H7	120.2
C1—C2—C5	110.3 (3)	C6—C7—H7	120.2
C3—C2—C5	112.4 (4)	C7—C8—H8	119.5
C4—C2—C5	108.6 (3)	C9—C8—H8	119.5
C6—C5—C10	116.9 (4)	C8—C9—H9	120.4
C6—C5—C2	122.9 (4)	C10—C9—H9	120.4
C10—C5—C2	120.2 (4)	C5—C10—H10	119.3
C5—C6—C7	121.9 (5)	C9—C10—H10	119.3
C8—C7—C6	119.5 (5)	C12—C11—H11a	107.4
C7—C8—C9	121.0 (5)	Sn1—C11—H11a	107.4
C8—C9—C10	119.3 (5)	C12—C11—H11b	107.4
C5—C10—C9	121.4 (5)	Sn1—C11—H11b	107.4
C12—C11—Sn1	119.5 (2)	H11a—C11—H11b	107.0
C15—C12—C14	112.9 (3)	C12—C13—H13a	109.5
C15—C12—C11	110.6 (3)	C12—C13—H13b	109.5
C14—C12—C11	109.7 (3)	H13a—C13—H13b	109.5
C15—C12—C13	108.0 (3)	C12—C13—H13c	109.5
C14—C12—C13	107.4 (3)	H13a—C13—H13c	109.5
C11—C12—C13	108.0 (3)	H13b—C13—H13c	109.5
C20—C15—C16	116.6 (3)	C12—C14—H14a	109.5
C20—C15—C12	123.0 (3)	C12—C14—H14b	109.5
C16—C15—C12	120.4 (3)	H14a—C14—H14b	109.5
C15—C16—C17	121.8 (4)	C12—C14—H14c	109.5
C18—C17—C16	120.0 (4)	H14a—C14—H14c	109.5
C17—C18—C19	119.3 (5)	H14b—C14—H14c	109.5
C18—C19—C20	120.8 (5)	C15—C16—H16	119.1
C15—C20—C19	121.4 (4)	C17—C16—H16	119.1
C22—C21—Sn1	117.4 (3)	C18—C17—H17	120.0
C24—C22—C25	112.0 (3)	C16—C17—H17	120.0
C24—C22—C21	108.3 (3)	C17—C18—H18	120.3
C25—C22—C21	110.1 (3)	C19—C18—H18	120.3
C24—C22—C23	108.9 (3)	C18—C19—H19	119.6
C25—C22—C23	108.4 (3)	C20—C19—H19	119.6
C21—C22—C23	109.1 (3)	C15—C20—H20	119.3
C30—C25—C26	116.9 (3)	C19—C20—H20	119.3
C30—C25—C22	122.1 (3)	C22—C21—H21a	108.0
C26—C25—C22	120.9 (3)	Sn1—C21—H21a	108.0
C25—C26—C27	121.2 (4)	C22—C21—H21b	108.0
C28—C27—C26	120.2 (4)	Sn1—C21—H21b	108.0
C27—C28—C29	120.0 (4)	H21a—C21—H21b	107.2
C28—C29—C30	120.0 (5)	C22—C23—H23a	109.5
C25—C30—C29	121.5 (4)	C22—C23—H23b	109.5
O2—C31—O1	125.6 (3)	H23a—C23—H23b	109.5
O2—C31—C32	120.2 (3)	C22—C23—H23c	109.5
O1—C31—C32	114.2 (3)	H23a—C23—H23c	109.5
C33—C32—C32^i	118.5 (2)	H23b—C23—H23c	109.5
C33—C32—C31	121.2 (2)	C22—C24—H24a	109.5
C32^i—C32—C31	120.2 (2)	C22—C24—H24b	109.5
F1—C33—C32	120.3 (3)	H24a—C24—H24b	109.5
F1—C33—C34	117.7 (3)	C22—C24—H24c	109.5
C32—C33—C34	122.0 (3)	H24a—C24—H24c	109.5
F2—C34—C34^i	120.0 (2)	H24b—C24—H24c	109.5
F2—C34—C33	120.6 (3)	C25—C26—H26	119.4
C34^i—C34—C33	119.5 (2)	C27—C26—H26	119.4
C2—C1—H1a	107.6	C28—C27—H27	119.9
Sn1—C1—H1a	107.6	C26—C27—H27	119.9
C2—C1—H1b	107.6	C27—C28—H28	120.0
Sn1—C1—H1b	107.6	C29—C28—H28	120.0
H1a—C1—H1b	107.0	C28—C29—H29	120.0
C2—C3—H3a	109.5	C30—C29—H29	120.0
C2—C3—H3b	109.5	C25—C30—H30	119.2
H3a—C3—H3b	109.5	C29—C30—H30	119.2
C2—C3—H3c	109.5
C11—Sn1—O1—C31	178.2 (2)	C17—C18—C19—C20	−2.0 (8)
C1—Sn1—O1—C31	−63.1 (3)	C16—C15—C20—C19	−0.3 (6)
C21—Sn1—O1—C31	60.9 (3)	C12—C15—C20—C19	−178.1 (4)
O1—Sn1—C1—C2	129.6 (3)	C18—C19—C20—C15	1.1 (8)
C11—Sn1—C1—C2	−131.0 (2)	O1—Sn1—C21—C22	84.8 (3)
C21—Sn1—C1—C2	15.2 (3)	C11—Sn1—C21—C22	−14.4 (3)
Sn1—C1—C2—C3	−71.7 (4)	C1—Sn1—C21—C22	−161.1 (3)
Sn1—C1—C2—C4	170.8 (3)	Sn1—C21—C22—C24	−67.9 (3)
Sn1—C1—C2—C5	51.9 (4)	Sn1—C21—C22—C25	54.9 (4)
C1—C2—C5—C6	−133.0 (4)	Sn1—C21—C22—C23	173.8 (3)
C3—C2—C5—C6	−11.6 (5)	C24—C22—C25—C30	−12.9 (4)
C4—C2—C5—C6	108.3 (4)	C21—C22—C25—C30	−133.5 (4)
C1—C2—C5—C10	47.6 (4)	C23—C22—C25—C30	107.3 (4)
C3—C2—C5—C10	169.1 (3)	C24—C22—C25—C26	166.5 (3)
C4—C2—C5—C10	−71.0 (4)	C21—C22—C25—C26	45.9 (4)
C10—C5—C6—C7	0.2 (7)	C23—C22—C25—C26	−73.4 (4)
C2—C5—C6—C7	−179.2 (4)	C30—C25—C26—C27	4.5 (6)
C5—C6—C7—C8	1.5 (8)	C22—C25—C26—C27	−174.9 (4)
C6—C7—C8—C9	−2.3 (9)	C25—C26—C27—C28	−2.9 (7)
C7—C8—C9—C10	1.4 (8)	C26—C27—C28—C29	0.4 (8)
C6—C5—C10—C9	−1.1 (6)	C27—C28—C29—C30	0.2 (7)
C2—C5—C10—C9	178.3 (4)	C26—C25—C30—C29	−3.8 (6)
C8—C9—C10—C5	0.3 (7)	C22—C25—C30—C29	175.5 (4)
O1—Sn1—C11—C12	82.7 (3)	C28—C29—C30—C25	1.5 (7)
C1—Sn1—C11—C12	−23.6 (3)	Sn1—O1—C31—O2	−0.3 (5)
C21—Sn1—C11—C12	−170.5 (2)	Sn1—O1—C31—C32	179.0 (2)
Sn1—C11—C12—C15	74.4 (3)	O2—C31—C32—C33	120.6 (4)
Sn1—C11—C12—C14	−50.8 (3)	O1—C31—C32—C33	−58.7 (4)
Sn1—C11—C12—C13	−167.6 (3)	O2—C31—C32—C32^i	−56.4 (5)
C14—C12—C15—C20	−4.6 (5)	O1—C31—C32—C32^i	124.3 (4)
C11—C12—C15—C20	−128.0 (4)	C32^i—C32—C33—F1	178.4 (3)
C13—C12—C15—C20	114.0 (4)	C31—C32—C33—F1	1.3 (4)
C14—C12—C15—C16	177.7 (3)	C32^i—C32—C33—C34	−0.1 (5)
C11—C12—C15—C16	54.3 (4)	C31—C32—C33—C34	−177.1 (3)
C13—C12—C15—C16	−63.7 (4)	F1—C33—C34—F2	1.0 (5)
C20—C15—C16—C17	0.4 (6)	C32—C33—C34—F2	179.6 (4)
C12—C15—C16—C17	178.3 (4)	F1—C33—C34—C34^i	180.0 (4)
C15—C16—C17—C18	−1.3 (8)	C32—C33—C34—C34^i	−1.5 (7)
C16—C17—C18—C19	2.0 (8)

Symmetry code: (i) −x+1, y, −z.