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Acta Cryst. (2005). E61, m1-m2 [ doi:10.1107/S160053680403106X ]
Abstract: The reaction of terephthalonitrile and sodium azide catalyzed by manganese chloride tetrahydrate converts one nitrile group to tetrazole and leaves the other nitrile group unchanged. The MnII atom in the title compound, [Mn(H2O)6](C8H4N5)2, is coordinated by six water molecules and lies on a position of 2/m crystallographic symmetry. The plane of the tetrazolate anion is perpendicular to a crystallographic mirror plane.
Online 4 December 2004
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