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Acta Cryst. (2005). E61, m87-m88 [ doi:10.1107/S160053680403209X ]
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2-2-methylpyrazine-2-trifluoroacetato], a reinvestigationAbstract: This work is a reinvestigation of a previously reported structure [Zhu & Ng (2004). Acta Cryst. E60, m939-m940], where the crystal measured was twinned. The title compound, [Ag(C2F3O2)(C5H6N2)]n, is a polymeric silver(I) complex. Each AgI atom is in a tetrahedral configuration and is four-coordinated by two O atoms of two 3-fluoroacetate anions and two N atoms of two 2-methylpyrazine ligands. The 3-fluoroacetate anion and the 2-methylpyrazine ligand both act as bidentate bridging ligands and coordinate to the AgI atoms through the carboxylate O atoms and the pyridine N atoms, respectively, forming a three-dimensional network.
Online 11 December 2004
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