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Acta Cryst. (2005). E61, m27-m29  [ doi:10.1107/S1600536804031277 ]

cis-Bis(8-hydroxyquinolinato-[kappa]2N,O)diphenyltin(IV)

A. Linden, T. S. Basu Baul and A. Mizar

Abstract: The coordination geometry at the Sn atom in the title compound, [Sn(C6H5)2(C9H6NO)2], is distorted cis-octahedral, in which the two phenyl ligands are cis to one another and trans to the N atoms of the oxinate ligands. This arrangement brings the oxinate O atoms into a trans relationship and is the geometry adopted most frequently by diorganotin(IV) oxinates. The O...O vector in the molecule is almost parallel to the plane of every ligand.

Online 4 December 2004


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