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Acta Cryst. (2005). E61, m3-m5  [ doi:10.1107/S1600536804030983 ]

(2,2'-Bipyridine-[kappa]2N,N')(3-oxidonaphthalene-2-carboxylato-[kappa]2O:O')palladium(II) hemihydrate

Y. Wang and N. Okabe

Abstract: The title compound, [Pd(C11H6O3)(C10H8N2)]·0.5H2O, contains two monoclear PdII complexes and one water molecule in the asymmetric unit. The Pd atom of each complex has a similar distorted cis-square-planar coordination geometry and is bonded to two N atoms from 2,2'-bipyridine ligand, and one carboxylate O and one naphthol O atom from the 3-oxidonaphthalene-2-carboxylate ligand. There are intermolecular [pi]-[pi] interactions, together with hydrogen bonds involving the solvent water molecule.

Online 4 December 2004


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