Acta Cryst. (2005). E61, m50-m51  [ doi:10.1107/S1600536804031332 ]

{(⁵,N)-[(tert-Butylamido)dimethylsilyl]cyclopentadienyl}dichlorotitanium(IV)

M. Erben, I. Císarová, J. Vinklárek and M. Dusek

Abstract: The crystal structure of the title compound, [Ti(C₁₁H₁₉NSi)Cl₂], has been determined as part of a broad investigation of half-sandwich titanium complexes. Titanium has a pseudo-tetrahedral coordination formed by two Cl atoms [Ti-Cl = 2.2719  (4) and 2.2730  (4)  Å], the N atom of the N-tert-butyl group [Ti-N = 1.9094  (12)  Å] and the silyl-substituted Cp ligand [metal-Cp ring centroid distance = 2.0185  (9)  Å]. The tert-butyl group was found to be disordered.

Online 11 December 2004

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