Acta Cryst. (2005). E61, m279-m281  [ doi:10.1107/S1600536805000504 ]

Poly[[triaquabis(₄-3-carboxy-4-hydroxybenzenesulfonato)disilver(I)] monohydrate]

S. Gao, Z.-B. Zhu, L.-H. Huo and S. W. Ng

Abstract: In the layer structure of the title polymeric complex, {[Ag₂(C₇H₅O₆S)₂(H₂O)₃]·H₂O}_n, both substituted benzenesulfonate anions use two of their sulfonyl O atoms to link to three Ag atoms and their double-bond carbonyl O atom to another Ag atom in a ₄-bonding mode. The two symmetry-independent Ag atoms are coordinated by water molecules, one by one water molecule and the other by two water molecules so that one Ag atom is five- and the other six-coordinate.

Online 15 January 2005

Copyright © International Union of Crystallography
IUCr Webmaster