Acta Cryst. (2005). E61, m317-m319  [ doi:10.1107/S1600536805001091 ]

Poly[tetra-₂-azido-di-₂-4,4'-bipyridine-sodium(I)iron(III)]

C. Näther, J. Greve and I. Jeß

Abstract: In the crystal structure of the title compound, [FeNa(N₃)₄(C₁₀H₈N₂)₂]_n, the Fe and Na atoms are coordinated by four N atoms of azide anions and two N atoms of 4,4'-bipyridine ligands within distorted octahedra. The azide anions are located in general positions whereas the Fe and Na atoms, as well as the 4,4'-bipyridine ligands, are located on twofold axes. The iron and the sodium cations are connected via the 4,4'-bipyridine ligands into chains, which are linked by the azide anions into a three-dimensional coordination network.

Online 22 January 2005

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