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Acta Cryst. (2005). E61, m299-m301  [ doi:10.1107/S1600536805000711 ]

catena-Poly[bis[aqua(1,10-phenanthroline)zinc(II)]-[mu]4-benzene-1,2,4,5-tetracarboxylato]

X.-L. Wang, F.-C. Liu, J.-R. Li and S. W. Ng

Abstract: The pyromellitate tetraanion in the title polymeric complex, [Zn2(C10H2O8)(C12H8N2)2(H2O)2]n, uses only one O atom from each carboxylate group to bind to one Zn atom, which is also chelated by the heterocycle; the fifth coordination site of the trigonal bipyramid around the Zn atom is occupied by a water molecule. The ribbons are linked by hydrogen bonds into sheets. The pyromellitate tetranion lies on an inversion center.

Online 15 January 2005


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