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Acta Cryst. (2005). E61, m207-m208  [ doi:10.1107/S1600536804033380 ]

[1-(3-Aminopropyl)-4,7-dithia-1-azacyclononane-[kappa]4N,N',S,S']bis(dimethylformamide-[kappa]O)nickel(II) bis(tetraphenylborate) acetonitrile disolvate

A. J. Blake and V. Lippolis

Abstract: In the title complex, [Ni(C3H7NO)2(C9H20N2S2)](C24H20B)2·2CH3CN, the metal centre has a distorted octahedral environment, with four coordination sites occupied by two N- and two S-donor atoms from a 3-aminopropyl pendant arm derivative of the nine-membered macrocycle 1-aza-4,7-dithiacyclononane, and the remaining two positions by two mutually cis dimethylformamide ligands.

Online 8 January 2005


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