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Acta Cryst. (2005). E61, i18-i19  [ doi:10.1107/S1600536805001960 ]

Tetratellurium bis[heptachlorodigallate(III)], Te4[Ga2Cl7]2

M. Lindsjö and L. Kloo

Abstract: Te4[Ga2Cl7]2 has been isolated from GaCl3-benzene media and its structure determined. The structure features a centrosymmetric square-planar Te{}_{4}^{\,\,2+} cation and staggered [Ga2Cl7]- anions, consisting of two corner-sharing GaCl4 tetrahedra. The chlorine bridge between the Ga atoms in the anion is bent. The title compound is isotypic with Te4[Al2Cl7]2.

Online 29 January 2005


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