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Acta Cryst. (2005). E61, m260-m262  [ doi:10.1107/S1600536805000164 ]

catena-Poly[[[bis(1H-imidazole-[kappa]N3)zinc(II)]-[mu]-terephthalato-[kappa]2O:O'] trihydrate]

D.-D. Lin, K.-L. Yin and D.-J. Xu

Abstract: In the title polymeric complex, {[Zn(C8H4O4)(C3H4N2)2]·3H2O}n, the ZnII atom is coordinated by two terephthalate dianions and two imidazole ligands in a distorted tetrahedral geometry. The terephthalate dianions are located on inversion centres and bridge neighbouring ZnII atoms to form zigzag polymeric complex chains. The interplanar distance of 3.212 (17) Å between parallel imidazole rings of adjacent polymeric chains suggests the existence of [pi]-[pi] stacking.

Online 15 January 2005


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