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Acta Cryst. (2005). E61, m596-m597 [ doi:10.1107/S1600536805005350 ]
![[mu]](/logos/entities/mu_rmgif.gif)
-hydroxo-![[kappa]](/logos/entities/kappa_rmgif.gif)
2O:O-di--sulfato-4O:O'] monohydrate]Abstract: Ferric sulfate reacts with 1,6-diaminohexane in the presence of acid under hydrothermal conditions to form the title compound, (C6H18N2)[Fe(OH)(SO4)2]·H2O. The six-coordinate ferrate trianion exists as a 2-hydroxodi-2-sulfate-bridged chain that propagates along the b axis of the monoclinic unit cell. The dication and uncoordinated water molecule connect the polyanionic chain into a three-dimensional network structure. The asymmetric unit contains two Fe ions, each on a center of symmetry.
Online 26 February 2005
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