Acta Cryst. (2005). E61, m519-m521  [ doi:10.1107/S1600536805004174 ]

A trigonal prismatic coordination geometry for vanadium in bis(2-oxidonaphthalene-1-carbaldehyde benzoylhydrazonato)vanadium(IV) dichloromethane hexane hemisolvate

S. Gao, L.-H. Huo, H. Zhao and S. W. Ng

Abstract: The V^IV atom in the title compound, [V(C₁₈H₁₂N₂O₄)₂]·CH₂Cl₂·0.5C₆H₁₄, which crystallizes as a dichloromethane hexane hemisolvate, exists in a trigonal prismatic geometry. The hexane molecule lies across an inversion center and both solvent molecules are disordered.

Online 12 February 2005

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