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Acta Cryst. (2005). E61, m548-m550  [ doi:10.1107/S160053680500468X ]

Poly[[bis(triphenylphosphine)mercury(II)]-[mu]-thiocyanato-cadmium(II)-tri-[mu]-thiocyanato]

X. Q. Wang, W. T. Yu, D. Xu and H. Q. Sun

Abstract: The title complex, [CdHg(NCS)4(C18H15P)2]n, contains slightly distorted trigonal bipyramidal CdN4S and tetrahedral HgP2S2. The CdII atom is coordinated by the N atoms of four thiocyanate ions and the S atom of one thiocyanate ion. The HgII atom is coordinated by two triphenylphosphine P atoms and two thiocyanate S atoms. The two metal atoms, viz. CdII and HgII, are connected by an -S=C=N- bridge, forming an infinite three-dimensional network.

Online 19 February 2005


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