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Acta Cryst. (2005). E61, o678-o680  [ doi:10.1107/S1600536805004472 ]

1,1,2,2-Tetrachloro-1,2-diphenylethane

A. Garcia-Sanchez, I. I. Padilla-Martínez, F. J. Martínez-Martínez, H. Höpfl and E. V. García-Báez

Abstract: The title compound, C14H10Cl4, possesses Ci symmetry and crystallizes with one half-molecule in the asymmetric unit. The two phenyl rings are antiperiplanar and inclined to one another by 180° by symmetry. The central C-C bond distance and the Cl-C-Cl bond angle [1.5887  (18)  Å and 106.02  (7)°, respectively] are significantly different from ideal sp3 values. In the crystal, a supramolecular structure is achieved by soft parallel-displaced [pi]-[pi] stacking and C-H...[pi] intermolecular interactions.

Online 19 February 2005


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